IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v102y2016icp669-681.html
   My bibliography  Save this article

Chemical-looping combustion in a reverse-flow fixed bed reactor

Author

Listed:
  • Han, Lu
  • Bollas, George M.

Abstract

A reverse-flow fixed bed reactor concept for CLC (chemical-looping combustion) is explored. The limitations of conventional fixed bed reactors, as applied to CLC, are overcome by reversing the gas flow direction periodically to enhance the mixing characteristics of the bed, thus improving oxygen carrier utilization and energy efficiency with respect to power generation. The reverse-flow reactor is simulated by a dusty-gas model and compared with an equivalent fixed bed reactor without flow reversal. Dynamic optimization is used to calculate conditions at which each reactor operates at maximum energy efficiency. Several cases studies illustrate the benefits of reverse-flow operation for the CLC with CuO and NiO oxygen carriers and methane and syngas fuels. The results show that periodic reversal of the flow during reduction improves the contact between the fuel and unconverted oxygen carrier, enabling the system to suppress unwanted catalytic reactions and axial temperature and conversion gradients. The operational scheme presented reduces the fluctuations of temperature during oxidation and increases the high-temperature heat produced by the process. CLC in a reverse-flow reactor has the potential to achieve higher energy efficiency than conventional fixed bed CLC reactors, when integrated with a downstream gas turbine of a combined cycle power plant.

Suggested Citation

  • Han, Lu & Bollas, George M., 2016. "Chemical-looping combustion in a reverse-flow fixed bed reactor," Energy, Elsevier, vol. 102(C), pages 669-681.
  • Handle: RePEc:eee:energy:v:102:y:2016:i:c:p:669-681
    DOI: 10.1016/j.energy.2016.02.057
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544216301086
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2016.02.057?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Ishida, M. & Zheng, D. & Akehata, T., 1987. "Evaluation of a chemical-looping-combustion power-generation system by graphic exergy analysis," Energy, Elsevier, vol. 12(2), pages 147-154.
    2. Erlach, B. & Schmidt, M. & Tsatsaronis, G., 2011. "Comparison of carbon capture IGCC with pre-combustion decarbonisation and with chemical-looping combustion," Energy, Elsevier, vol. 36(6), pages 3804-3815.
    3. Fernandez, Jose Ramon & Abanades, Juan Carlos & Murillo, Ramon, 2014. "Modeling of Cu oxidation in an adiabatic fixed-bed reactor with N2 recycling," Applied Energy, Elsevier, vol. 113(C), pages 1945-1951.
    4. Fernández, J.R. & Abanades, J.C., 2014. "Conceptual design of a Ni-based chemical looping combustion process using fixed-beds," Applied Energy, Elsevier, vol. 135(C), pages 309-319.
    5. Naqvi, Rehan & Wolf, Jens & Bolland, Olav, 2007. "Part-load analysis of a chemical looping combustion (CLC) combined cycle with CO2 capture," Energy, Elsevier, vol. 32(4), pages 360-370.
    6. Kvamsdal, Hanne M. & Jordal, Kristin & Bolland, Olav, 2007. "A quantitative comparison of gas turbine cycles with CO2 capture," Energy, Elsevier, vol. 32(1), pages 10-24.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Gao, Zixiang & Wu, Di & Yin, Fan & Sun, Liyan & Zeng, Dewang & Xiao, Rui, 2024. "Thermodynamic and kinetic analysis on the biomass syngas fueled chemical looping hydrogen generation process in fixed bed reactor," Energy, Elsevier, vol. 298(C).
    2. Tomasz Czakiert & Jaroslaw Krzywanski & Anna Zylka & Wojciech Nowak, 2022. "Chemical Looping Combustion: A Brief Overview," Energies, MDPI, vol. 15(4), pages 1-19, February.
    3. Güleç, Fatih & Meredith, Will & Sun, Cheng-Gong & Snape, Colin E., 2019. "Selective low temperature chemical looping combustion of higher alkanes with Cu- and Mn- oxides," Energy, Elsevier, vol. 173(C), pages 658-666.
    4. Qiang Tian & Lixin Che & Bin Ding & Qianwei Wang & Qingquan Su, 2017. "Performance of Cu‐Fe‐based oxygen carrier in a CLC process based on fixed bed reactors," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 7(4), pages 731-744, August.
    5. Zhang, Hao & Liu, Xiangyu & Hong, Hui & Jin, Hongguang, 2018. "Characteristics of a 10 kW honeycomb reactor for natural gas fueled chemical-looping combustion," Applied Energy, Elsevier, vol. 213(C), pages 285-292.
    6. Zhang, Hao & Hong, Hui & Jiang, Qiongqiong & Deng, Ya'nan & Jin, Hongguang & Kang, Qilan, 2018. "Development of a chemical-looping combustion reactor having porous honeycomb chamber and experimental validation by using NiO/NiAl2O4," Applied Energy, Elsevier, vol. 211(C), pages 259-268.
    7. Han, Lu & Bollas, George M., 2016. "Dynamic optimization of fixed bed chemical-looping combustion processes," Energy, Elsevier, vol. 112(C), pages 1107-1119.
    8. Qiang Tian & Lixin Che & Bin Ding & Qianwei Wang & Qingquan Su, 2018. "Performance of a Cu–Fe‐based oxygen carrier combined with a Ni‐based oxygen carrier in a chemical‐looping combustion process based on fixed‐bed reactors," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 8(3), pages 542-556, June.
    9. Lucia Blas & Patrick Dutournié & Mejdi Jeguirim & Ludovic Josien & David Chiche & Stephane Bertholin & Arnold Lambert, 2017. "Numerical Modeling of Oxygen Carrier Performances (NiO/NiAl 2 O 4 ) for Chemical-Looping Combustion," Energies, MDPI, vol. 10(7), pages 1-16, June.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Han, Lu & Bollas, George M., 2016. "Dynamic optimization of fixed bed chemical-looping combustion processes," Energy, Elsevier, vol. 112(C), pages 1107-1119.
    2. Fernández, J.R. & Abanades, J.C., 2014. "Conceptual design of a Ni-based chemical looping combustion process using fixed-beds," Applied Energy, Elsevier, vol. 135(C), pages 309-319.
    3. Samuel C. Bayham & Andrew Tong & Mandar Kathe & Liang-Shih Fan, 2016. "Chemical looping technology for energy and chemical production," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 5(2), pages 216-241, March.
    4. Meng, William X. & Banerjee, Subhodeep & Zhang, Xiao & Agarwal, Ramesh K., 2015. "Process simulation of multi-stage chemical-looping combustion using Aspen Plus," Energy, Elsevier, vol. 90(P2), pages 1869-1877.
    5. Zhao, Ying-jie & Zhang, Yu-ke & Cui, Yang & Duan, Yuan-yuan & Huang, Yi & Wei, Guo-qiang & Mohamed, Usama & Shi, Li-juan & Yi, Qun & Nimmo, William, 2022. "Pinch combined with exergy analysis for heat exchange network and techno-economic evaluation of coal chemical looping combustion power plant with CO2 capture," Energy, Elsevier, vol. 238(PA).
    6. Penthor, Stefan & Zerobin, Florian & Mayer, Karl & Pröll, Tobias & Hofbauer, Hermann, 2015. "Investigation of the performance of a copper based oxygen carrier for chemical looping combustion in a 120kW pilot plant for gaseous fuels," Applied Energy, Elsevier, vol. 145(C), pages 52-59.
    7. Hamers, H.P. & Romano, M.C. & Spallina, V. & Chiesa, P. & Gallucci, F. & van Sint Annaland, M., 2015. "Energy analysis of two stage packed-bed chemical looping combustion configurations for integrated gasification combined cycles," Energy, Elsevier, vol. 85(C), pages 489-502.
    8. Zheng, Yawen & Gao, Lin & He, Song, 2023. "Analysis of the mechanism of energy consumption for CO2 capture in a power system," Energy, Elsevier, vol. 262(PA).
    9. Shareq Mohd Nazir & Olav Bolland & Shahriar Amini, 2018. "Analysis of Combined Cycle Power Plants with Chemical Looping Reforming of Natural Gas and Pre-Combustion CO 2 Capture," Energies, MDPI, vol. 11(1), pages 1-13, January.
    10. Nazir, Shareq Mohd & Cloete, Jan Hendrik & Cloete, Schalk & Amini, Shahriar, 2019. "Gas switching reforming (GSR) for power generation with CO2 capture: Process efficiency improvement studies," Energy, Elsevier, vol. 167(C), pages 757-765.
    11. Zhang, Hao & Hong, Hui & Jiang, Qiongqiong & Deng, Ya'nan & Jin, Hongguang & Kang, Qilan, 2018. "Development of a chemical-looping combustion reactor having porous honeycomb chamber and experimental validation by using NiO/NiAl2O4," Applied Energy, Elsevier, vol. 211(C), pages 259-268.
    12. Chen, Shiyi & Lior, Noam & Xiang, Wenguo, 2015. "Coal gasification integration with solid oxide fuel cell and chemical looping combustion for high-efficiency power generation with inherent CO2 capture," Applied Energy, Elsevier, vol. 146(C), pages 298-312.
    13. Håkonsen, Silje Fosse & Grande, Carlos A. & Blom, Richard, 2014. "Rotating bed reactor for CLC: Bed characteristics dependencies on internal gas mixing," Applied Energy, Elsevier, vol. 113(C), pages 1952-1957.
    14. Bhavsar, Saurabh & Isenberg, Natalie & More, Amey & Veser, Götz, 2016. "Lanthana-doped ceria as active support for oxygen carriers in chemical looping combustion," Applied Energy, Elsevier, vol. 168(C), pages 236-247.
    15. Cloete, Schalk & Zaabout, Abdelghafour & Romano, Matteo C. & Chiesa, Paolo & Lozza, Giovanni & Gallucci, Fausto & van Sint Annaland, Martin & Amini, Shahriar, 2017. "Optimization of a Gas Switching Combustion process through advanced heat management strategies," Applied Energy, Elsevier, vol. 185(P2), pages 1459-1470.
    16. Mansouri Majoumerd, Mohammad & De, Sudipta & Assadi, Mohsen & Breuhaus, Peter, 2012. "An EU initiative for future generation of IGCC power plants using hydrogen-rich syngas: Simulation results for the baseline configuration," Applied Energy, Elsevier, vol. 99(C), pages 280-290.
    17. Najmus S. Sifat & Yousef Haseli, 2019. "A Critical Review of CO 2 Capture Technologies and Prospects for Clean Power Generation," Energies, MDPI, vol. 12(21), pages 1-33, October.
    18. Sorgenfrei, Max & Tsatsaronis, George, 2014. "Design and evaluation of an IGCC power plant using iron-based syngas chemical-looping (SCL) combustion," Applied Energy, Elsevier, vol. 113(C), pages 1958-1964.
    19. Iloeje, Chukwunwike O. & Zhao, Zhenlong & Ghoniem, Ahmed F., 2017. "A reduced fidelity model for the rotary chemical looping combustion reactor," Applied Energy, Elsevier, vol. 190(C), pages 725-739.
    20. Mohammed N. Khan & Schalk Cloete & Shahriar Amini, 2020. "Efficient Production of Clean Power and Hydrogen Through Synergistic Integration of Chemical Looping Combustion and Reforming," Energies, MDPI, vol. 13(13), pages 1-19, July.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:102:y:2016:i:c:p:669-681. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.