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Strategy of alternating bias voltage on corrosion resistance and interfacial conductivity enhancement of TiCx/a-C coatings on metallic bipolar plates in PEMFCs

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  • Zhang, Weixin
  • Yi, Peiyun
  • Peng, Linfa
  • Lai, Xinmin

Abstract

Proton exchange membrane fuel cells (PEMFCs) are deemed to be a promising renewable energy for variety of applications. However, metallic bipolar plates, one of key components in PEMFCs, still suffer from severe corrosion and degradation of interfacial conductivity under the humid and acid operating condition. Herein we proposed a novel strategy to enhance interfacial conductivity and corrosion resistance of TiCx/a-C coatings for metallic bipolar plates by alternating substrate bias voltage during the deposition process. The effects of the alternating substrate bias voltage strategy on the composition and morphology of the multilayered TiCx/a-C coatings had been explored. Both the corrosion resistance and the interfacial conductivity of the multilayered TiCx/a-C coatings were improved with more alternating periods of bias voltage. The effects of the enhanced performance had been discussed, and it was found that the alternating bias voltage strategy will restrain the columnar structures in the a-C layers and promote the generation of sp2-rich clusters on the surface. This versatile strategy based on moderately alternating cycles of substrate bias voltage exhibits great potential in many applications.

Suggested Citation

  • Zhang, Weixin & Yi, Peiyun & Peng, Linfa & Lai, Xinmin, 2018. "Strategy of alternating bias voltage on corrosion resistance and interfacial conductivity enhancement of TiCx/a-C coatings on metallic bipolar plates in PEMFCs," Energy, Elsevier, vol. 162(C), pages 933-943.
    • Handle: RePEc:eee:energy:v:162:y:2018:i:c:p:933-943
    DOI: 10.1016/j.energy.2018.08.099
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    References listed on IDEAS

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    1. Lin, R. & Ren, Y.S. & Lin, X.W. & Jiang, Z.H. & Yang, Z. & Chang, Y.T., 2017. "Investigation of the internal behavior in segmented PEMFCs of different flow fields during cold start process," Energy, Elsevier, vol. 123(C), pages 367-377.
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    3. Huang, Kaikai & Zhang, Dongming & Hu, Mingming & Hu, Qinghui, 2014. "Cr2O3/C composite coatings on stainless steel 304 as bipolar plate for proton exchange membrane fuel cell," Energy, Elsevier, vol. 76(C), pages 816-821.
    4. Pugal Mani, S. & Rajendran, N., 2017. "Corrosion and interfacial contact resistance behavior of electrochemically nitrided 316L SS bipolar plates for proton exchange membrane fuel cells," Energy, Elsevier, vol. 133(C), pages 1050-1062.
    5. Hu, Qinghui & Zhang, Dongming & Fu, Hao, 2015. "Effect of flow-field dimensions on the formability of Fe–Ni–Cr alloy as bipolar plate for PEM (proton exchange membrane) fuel cell," Energy, Elsevier, vol. 83(C), pages 156-163.
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    Cited by:

    1. Bhosale, Amit C. & Rengaswamy, Raghunathan, 2019. "Interfacial contact resistance in polymer electrolyte membrane fuel cells: Recent developments and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 115(C).
    2. Fan, Hong-Qiang & Wu, Yuan-Min & Su, Shuo & Shi, Dong-Dong & Wang, Xian-Zong & Behnamian, Yashar & Zhang, Jie-Yu & Li, Qian, 2022. "Solution acidity and temperature induced anodic dissolution and degradation of through-plane electrical conductivity of Au/TiN coated metal bipolar plates used in PEMFC," Energy, Elsevier, vol. 254(PC).
    3. Hao, Wenbin & Ma, Hongyan & Sun, Guoxing & Li, Zongjin, 2019. "Magnesia phosphate cement composite bipolar plates for passive type direct methanol fuel cells," Energy, Elsevier, vol. 168(C), pages 80-87.

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