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Analysis of Ice Formation during Start-Up of PEM Fuel Cells at Subzero Temperatures Using Experimental and Simulative Methods

Author

Listed:
  • Maximilian Schmitz

    (Chair of Thermodynamics of Mobile Energy Conversion Systems (TME), RWTH Aachen University, Forckenbeckstraße 4, 52074 Aachen, Germany)

  • Matthias Bahr

    (The Hydrogen and Fuel Cell Center (ZBT), Carl-Benz-Straße 201, 47057 Duisburg, Germany)

  • Sönke Gößling

    (The Hydrogen and Fuel Cell Center (ZBT), Carl-Benz-Straße 201, 47057 Duisburg, Germany)

  • Stefan Pischinger

    (Chair of Thermodynamics of Mobile Energy Conversion Systems (TME), RWTH Aachen University, Forckenbeckstraße 4, 52074 Aachen, Germany)

Abstract

Freeze start is a challenge in the commercialization of PEM fuel cells. In this study, ice formation in cell layers is investigated through experiments and simulations. Segmentation of the fuel cell on the test bench allows to determine the local distributions of current density and high frequency resistance over the active cell area. The location and timing of ice formation are analyzed in the experiments. It is shown that the formation of ice lenses can be detected by local measurements of the high frequency resistances. Then, a multiphysical CFD model is built and validated with the measurements and the commonalities and differences between the model results and the experiments are studied. It is shown that the model determines the freeze start behavior very well in wide operating ranges. Together with the findings from the experimental investigations, the model will finally be used to investigate local ice formation in detail.

Suggested Citation

  • Maximilian Schmitz & Matthias Bahr & Sönke Gößling & Stefan Pischinger, 2023. "Analysis of Ice Formation during Start-Up of PEM Fuel Cells at Subzero Temperatures Using Experimental and Simulative Methods," Energies, MDPI, vol. 16(18), pages 1-26, September.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:18:p:6534-:d:1237444
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    References listed on IDEAS

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    1. Yang, Zirong & Jiao, Kui & Wu, Kangcheng & Shi, Weilong & Jiang, Shangfeng & Zhang, Longhai & Du, Qing, 2021. "Numerical investigations of assisted heating cold start strategies for proton exchange membrane fuel cell systems," Energy, Elsevier, vol. 222(C).
    2. Liu, Dengcheng & Lin, Rui & Feng, Bowen & Han, Lihang & Zhang, Yu & Ni, Meng & Wu, Sai, 2019. "Localised electrochemical impedance spectroscopy investigation of polymer electrolyte membrane fuel cells using Print circuit board based interference-free system," Applied Energy, Elsevier, vol. 254(C).
    3. Lin, R. & Ren, Y.S. & Lin, X.W. & Jiang, Z.H. & Yang, Z. & Chang, Y.T., 2017. "Investigation of the internal behavior in segmented PEMFCs of different flow fields during cold start process," Energy, Elsevier, vol. 123(C), pages 367-377.
    4. Wang, Yun & Chen, Ken S. & Mishler, Jeffrey & Cho, Sung Chan & Adroher, Xavier Cordobes, 2011. "A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research," Applied Energy, Elsevier, vol. 88(4), pages 981-1007, April.
    5. Ko, Johan & Ju, Hyunchul, 2012. "Comparison of numerical simulation results and experimental data during cold-start of polymer electrolyte fuel cells," Applied Energy, Elsevier, vol. 94(C), pages 364-374.
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