IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v194y2022icp1277-1287.html
   My bibliography  Save this article

Corrosion of metallic bipolar plates accelerated by operating conditions in a simulated PEM fuel cell cathode environment

Author

Listed:
  • Ren, Peng
  • Pei, Pucheng
  • Chen, Dongfang
  • Zhang, Lu
  • Li, Yuehua
  • Song, Xin
  • Wang, Mingkai
  • Wang, He

Abstract

Metallic bipolar plates (BPs) are extensively applied in fuel cell stacks to achieve an extremely high power density, and are thus suitable for vehicle applications. Corrosion of metallic BPs and contamination on membrane electrode assemblies have become key issues. Automotive operating conditions significantly accelerate BP corrosion and surface destruction. Accelerated stress tests, simulating dynamic load and startup-shutdown, are conducted to reveal the operation-induced corrosion mechanisms of typical SS316L BPs. The dynamic potential in the normal range (0.6–0.95 V) accelerates the local breakdown and damage of the passivation layer, leaving pits rich in Cr-species. The abundant Cr-species in the pits prevents further dissolution of Fe-speices and relieves local corrosion. The startup-shutdown condition extends the cathode potential to the trans-passivation and secondary passivation regions. Startup-shutdown drives BP into complex evolution stages of corrosion and passivation. Frequent alternation of potentials between passivation and trans-passivation regions accelerates alternant dissolution of outer Fe-species and Cr-species, thus causing global destruction represented by flocculent microstructure and interlinked pits. The ultrahigh cathode potential in startup-shutdown may induce an obvious surface film via strong secondary passivation. This paper can further guide the test protocols to evaluate the durability of metallic BP and condition optimization to avoid extreme corrosion damage.

Suggested Citation

  • Ren, Peng & Pei, Pucheng & Chen, Dongfang & Zhang, Lu & Li, Yuehua & Song, Xin & Wang, Mingkai & Wang, He, 2022. "Corrosion of metallic bipolar plates accelerated by operating conditions in a simulated PEM fuel cell cathode environment," Renewable Energy, Elsevier, vol. 194(C), pages 1277-1287.
    • Handle: RePEc:eee:renene:v:194:y:2022:i:c:p:1277-1287
    DOI: 10.1016/j.renene.2022.05.153
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148122008138
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2022.05.153?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Wilberforce, Tabbi & Ijaodola, O. & Ogungbemi, Emmanuel & Khatib, F.N. & Leslie, T. & El-Hassan, Zaki & Thomposon, J. & Olabi, A.G., 2019. "Technical evaluation of proton exchange membrane (PEM) fuel cell performance – A review of the effects of bipolar plates coating," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    2. Adloo, Ali & Sadeghi, Morteza & Masoomi, Mahmood & Pazhooh, Hadi Najafi, 2016. "High performance polymeric bipolar plate based on polypropylene/graphite/graphene/nano-carbon black composites for PEM fuel cells," Renewable Energy, Elsevier, vol. 99(C), pages 867-874.
    3. Zhang, Tong & Wang, Peiqi & Chen, Huicui & Pei, Pucheng, 2018. "A review of automotive proton exchange membrane fuel cell degradation under start-stop operating condition," Applied Energy, Elsevier, vol. 223(C), pages 249-262.
    4. Bouziane, Khadidja & Khetabi, El Mahdi & Lachat, Rémy & Zamel, Nada & Meyer, Yann & Candusso, Denis, 2020. "Impact of cyclic mechanical compression on the electrical contact resistance between the gas diffusion layer and the bipolar plate of a polymer electrolyte membrane fuel cell," Renewable Energy, Elsevier, vol. 153(C), pages 349-361.
    5. Huang, Kaikai & Zhang, Dongming & Hu, Mingming & Hu, Qinghui, 2014. "Cr2O3/C composite coatings on stainless steel 304 as bipolar plate for proton exchange membrane fuel cell," Energy, Elsevier, vol. 76(C), pages 816-821.
    6. Esbo, M. Rahimi- & Ranjbar, A.A. & Rahgoshay, S.M., 2020. "Analysis of water management in PEM fuel cell stack at dead-end mode using direct visualization," Renewable Energy, Elsevier, vol. 162(C), pages 212-221.
    7. Bolouri, Amir & Kang, Chung Gil, 2014. "Study on dimensional and corrosion properties of thixoformed A356 and AA7075 aluminum bipolar plates for proton exchange membrane fuel cells," Renewable Energy, Elsevier, vol. 71(C), pages 616-628.
    8. Lee, Chi-Yuan & Fang, Li-Hsing & Su, Ay & Liu, Yun-Min & Lee, Chung-Ju, 2015. "Real time interior water and thermal monitoring of fuel cell with micro 3-in-1 sensor," Renewable Energy, Elsevier, vol. 74(C), pages 517-522.
    9. Chen, Huicui & Song, Zhen & Zhao, Xin & Zhang, Tong & Pei, Pucheng & Liang, Chen, 2018. "A review of durability test protocols of the proton exchange membrane fuel cells for vehicle," Applied Energy, Elsevier, vol. 224(C), pages 289-299.
    10. Pei, Pucheng & Chen, Dongfang & Wu, Ziyao & Ren, Peng, 2019. "Nonlinear methods for evaluating and online predicting the lifetime of fuel cells," Applied Energy, Elsevier, vol. 254(C).
    11. Lee, Choong-Hyun & Lee, Yang-Bok & Kim, Kyung-Min & Jeong, Min-Gun & Lim, Dae-Soon, 2013. "Electrically conductive polymer composite coating on aluminum for PEM fuel cells bipolar plate," Renewable Energy, Elsevier, vol. 54(C), pages 46-50.
    12. Pandiyan, S. & Elayaperumal, A. & Rajalakshmi, N. & Dhathathreyan, K.S. & Venkateshwaran, N., 2013. "Design and analysis of a proton exchange membrane fuel cells (PEMFC)," Renewable Energy, Elsevier, vol. 49(C), pages 161-165.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zuo, Jian & Steiner, Nadia Yousfi & Li, Zhongliang & Hissel, Daniel, 2024. "Health management review for fuel cells: Focus on action phase," Renewable and Sustainable Energy Reviews, Elsevier, vol. 201(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chen, Hong & Zhan, Zhigang & Jiang, Panxing & Sun, Yahao & Liao, Liwen & Wan, Xiongbiao & Du, Qing & Chen, Xiaosong & Song, Hao & Zhu, Ruijie & Shu, Zhanhong & Li, Shang & Pan, Mu, 2022. "Whole life cycle performance degradation test and RUL prediction research of fuel cell MEA," Applied Energy, Elsevier, vol. 310(C).
    2. Bhosale, Amit C. & Rengaswamy, Raghunathan, 2019. "Interfacial contact resistance in polymer electrolyte membrane fuel cells: Recent developments and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 115(C).
    3. Yan, Wei-Mon & Lin, Jian-Cheng & Chen, Chen-Yu & Amani, Mohammad, 2023. "Performance evaluation of TiN/Ti coatings on the aluminum alloy bipolar plates for PEM fuel cells," Renewable Energy, Elsevier, vol. 216(C).
    4. Nicu Bizon & Mircea Raceanu & Emmanouel Koudoumas & Adriana Marinoiu & Emmanuel Karapidakis & Elena Carcadea, 2020. "Renewable/Fuel Cell Hybrid Power System Operation Using Two Search Controllers of the Optimal Power Needed on the DC Bus," Energies, MDPI, vol. 13(22), pages 1-26, November.
    5. Chen, Kui & Badji, Abderrezak & Laghrouche, Salah & Djerdir, Abdesslem, 2022. "Polymer electrolyte membrane fuel cells degradation prediction using multi-kernel relevance vector regression and whale optimization algorithm," Applied Energy, Elsevier, vol. 318(C).
    6. Pei, Pucheng & Meng, Yining & Chen, Dongfang & Ren, Peng & Wang, Mingkai & Wang, Xizhong, 2023. "Lifetime prediction method of proton exchange membrane fuel cells based on current degradation law," Energy, Elsevier, vol. 265(C).
    7. Chen, Dongfang & Pei, Pucheng & Meng, Yining & Ren, Peng & Li, Yuehua & Wang, Mingkai & Wang, Xizhong, 2022. "Novel extraction method of working condition spectrum for the lifetime prediction and energy management strategy evaluation of automotive fuel cells," Energy, Elsevier, vol. 255(C).
    8. Liu, Ze & Zhang, Baitao & Xu, Sichuan, 2022. "Research on air mass flow-pressure combined control and dynamic performance of fuel cell system for vehicles application," Applied Energy, Elsevier, vol. 309(C).
    9. Ke Song & Yimin Wang & Xiao Hu & Jing Cao, 2020. "Online Prediction of Vehicular Fuel Cell Residual Lifetime Based on Adaptive Extended Kalman Filter," Energies, MDPI, vol. 13(23), pages 1-21, November.
    10. Abdul Ghani Olabi & Tabbi Wilberforce & Abdulrahman Alanazi & Parag Vichare & Enas Taha Sayed & Hussein M. Maghrabie & Khaled Elsaid & Mohammad Ali Abdelkareem, 2022. "Novel Trends in Proton Exchange Membrane Fuel Cells," Energies, MDPI, vol. 15(14), pages 1-35, July.
    11. Huu Linh Nguyen & Jeasu Han & Xuan Linh Nguyen & Sangseok Yu & Young-Mo Goo & Duc Dung Le, 2021. "Review of the Durability of Polymer Electrolyte Membrane Fuel Cell in Long-Term Operation: Main Influencing Parameters and Testing Protocols," Energies, MDPI, vol. 14(13), pages 1-34, July.
    12. Feng, Yanbiao & Dong, Zuomin, 2020. "Integrated design and control optimization of fuel cell hybrid mining truck with minimized lifecycle cost," Applied Energy, Elsevier, vol. 270(C).
    13. Pei, Pucheng & Chen, Dongfang & Wu, Ziyao & Ren, Peng, 2019. "Nonlinear methods for evaluating and online predicting the lifetime of fuel cells," Applied Energy, Elsevier, vol. 254(C).
    14. Shen, Yuanting & Yan, Xiaohui & An, Liang & Shen, Shuiyun & An, Lu & Zhang, Junliang, 2022. "Portable proton exchange membrane fuel cell using polyoxometalates as multi-functional hydrogen carrier," Applied Energy, Elsevier, vol. 313(C).
    15. Chen, Dongfang & Pei, Pucheng & Ren, Peng & Song, Xin & Wang, He & Zhang, Lu & Wang, Mingkai, 2022. "Analytical methods for the effect of anode nitrogen concentration on performance and voltage consistency of proton exchange membrane fuel cell stack," Energy, Elsevier, vol. 258(C).
    16. Liu, Zhao & Chen, Huicui & Zhang, Tong, 2022. "Review on system mitigation strategies for start-stop degradation of automotive proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 327(C).
    17. Zhang, Xiaojie & Zhang, Tong & Chen, Huicui & Cao, Yinliang, 2021. "A review of online electrochemical diagnostic methods of on-board proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 286(C).
    18. Xu, Liangfei & Fang, Chuan & Li, Jianqiu & Ouyang, Minggao & Lehnert, Werner, 2018. "Nonlinear dynamic mechanism modeling of a polymer electrolyte membrane fuel cell with dead-ended anode considering mass transport and actuator properties," Applied Energy, Elsevier, vol. 230(C), pages 106-121.
    19. Komini Babu, S. & Spernjak, D. & Dillet, J. & Lamibrac, A. & Maranzana, G. & Didierjean, S. & Lottin, O. & Borup, R.L. & Mukundan, R., 2019. "Spatially resolved degradation during startup and shutdown in polymer electrolyte membrane fuel cell operation," Applied Energy, Elsevier, vol. 254(C).
    20. K/bidi, Fabrice & Damour, Cedric & Grondin, Dominique & Hilairet, Mickaël & Benne, Michel, 2022. "Multistage power and energy management strategy for hybrid microgrid with photovoltaic production and hydrogen storage," Applied Energy, Elsevier, vol. 323(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:194:y:2022:i:c:p:1277-1287. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.