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Adsorption isotherms, kinetics and thermodynamic simulation of CO2-CSAC pair for cooling application

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  • Singh, Vinod Kumar
  • Kumar, E. Anil
  • Saha, Bidyut Baran

Abstract

This research article proposes to develop a waste heat driven single-stage adsorption-based cooling system by selecting CO2 and indigenous coconut shell based activated carbon (CSAC) as the adsorbate/adsorbent pair. The CO2 adsorption isotherms and kinetics of activated carbon are measured at different temperatures (273–368 K) using volumetric method. In order to illustrate adsorption isotherms, experimental data of CO2 uptake is correlated with the Langmuir and Dubinin-Astakhov (D-A) models. On the other hand, Linear Driving Force (LDF) and Fickian Diffusion (FD) models are utilized to explain adsorption kinetics data. Fugacity and pseudosaturation pressure of CO2 plays a significant role in the estimation of high-pressure CO2 adsorption and thermodynamic properties above the critical temperature of CO2, and these parameters are evaluated using adsorption isotherms data. The key thermodynamic properties and kinetics parameters of the assorted pair are estimated using measured adsorption isotherms and kinetics data which are used for the thermodynamic analysis of CO2-CSAC pair based cooling system. The maximum theoretical values of SCE and COP of CO2-CSAC pair are obtained as 12.52 kJ kg−1 and 0.10, respectively at the regeneration temperature of 80 °C along with the evaporator temperature of 15 °C.

Suggested Citation

  • Singh, Vinod Kumar & Kumar, E. Anil & Saha, Bidyut Baran, 2018. "Adsorption isotherms, kinetics and thermodynamic simulation of CO2-CSAC pair for cooling application," Energy, Elsevier, vol. 160(C), pages 1158-1173.
  • Handle: RePEc:eee:energy:v:160:y:2018:i:c:p:1158-1173
    DOI: 10.1016/j.energy.2018.07.063
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    References listed on IDEAS

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    Cited by:

    1. Rupa, Mahua Jahan & Pal, Animesh & Saha, Bidyut Baran, 2020. "Activated carbon-graphene nanoplatelets based green cooling system: Adsorption kinetics, heat of adsorption, and thermodynamic performance," Energy, Elsevier, vol. 193(C).
    2. Aristov, Yuri I., 2020. "Dynamics of adsorptive heat conversion systems: Review of basics and recent advances," Energy, Elsevier, vol. 205(C).
    3. Wawrzyńczak, Dariusz & Panowski, Marcin & Majchrzak-Kucęba, Izabela, 2019. "Possibilities of CO2 purification coming from oxy-combustion for enhanced oil recovery and storage purposes by adsorption method on activated carbon," Energy, Elsevier, vol. 180(C), pages 787-796.
    4. Piotr Boruta & Tomasz Bujok & Łukasz Mika & Karol Sztekler, 2021. "Adsorbents, Working Pairs and Coated Beds for Natural Refrigerants in Adsorption Chillers—State of the Art," Energies, MDPI, vol. 14(15), pages 1-41, August.

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