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Ethanol adsorption onto metal organic framework: Theory and experiments

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  • Saha, Bidyut Baran
  • El-Sharkawy, Ibrahim I.
  • Miyazaki, Takahiko
  • Koyama, Shigeru
  • Henninger, Stefan K.
  • Herbst, Annika
  • Janiak, Christoph

Abstract

This paper presents experimental and theoretical investigations of adsorption characteristics of ethanol onto metal organic framework namely MIL-101Cr. Adsorption isotherms and kinetics of the studied pair have been measured gravimetrically using a magnetic suspension adsorption measurement unit and volumetrically employing a Quantachrome Autosorb iQ MP machine. The present experiments have been conducted within relative pressures between 0.1 and 0.9 and adsorption temperatures ranging from 30 to 70 °C, which are suitable for adsorption cooling applications. Adsorption isotherm data exhibit that 1 kg of MIL-101Cr can adsorb as high as 1.1 kg of ethanol at adsorption temperature of 30 °C, and the Tóth equation has been used to fit the experimentally measured data. As of the experimentally measured adsorption uptake rate data, the Fickian diffusion model is found to be suitable. These data are essential for designing a new generation of adsorption chiller.

Suggested Citation

  • Saha, Bidyut Baran & El-Sharkawy, Ibrahim I. & Miyazaki, Takahiko & Koyama, Shigeru & Henninger, Stefan K. & Herbst, Annika & Janiak, Christoph, 2015. "Ethanol adsorption onto metal organic framework: Theory and experiments," Energy, Elsevier, vol. 79(C), pages 363-370.
  • Handle: RePEc:eee:energy:v:79:y:2015:i:c:p:363-370
    DOI: 10.1016/j.energy.2014.11.022
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    1. Gordeeva, Larisa G. & Aristov, Yuriy I., 2011. "Composite sorbent of methanol “LiCl in mesoporous silica gel” for adsorption cooling: Dynamic optimization," Energy, Elsevier, vol. 36(2), pages 1273-1279.
    2. Rezk, Ahmed & AL-Dadah, Raya & Mahmoud, Saad & Elsayed, Ahmed, 2013. "Investigation of Ethanol/metal organic frameworks for low temperature adsorption cooling applications," Applied Energy, Elsevier, vol. 112(C), pages 1025-1031.
    3. Henninger, S.K. & Munz, G. & Ratzsch, K.-F. & Schossig, P., 2011. "Cycle stability of sorption materials and composites for the use in heat pumps and cooling machines," Renewable Energy, Elsevier, vol. 36(11), pages 3043-3049.
    4. Cui, Qun & Tao, Gang & Chen, Haijun & Guo, Xinyue & Yao, Huqing, 2005. "Environmentally benign working pairs for adsorption refrigeration," Energy, Elsevier, vol. 30(2), pages 261-271.
    5. Gordeeva, Larisa & Aristov, Yuriy, 2010. "Novel sorbents of ethanol “salt confined to porous matrix” for adsorptive cooling," Energy, Elsevier, vol. 35(6), pages 2703-2708.
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    1. Askalany, Ahmed A. & Ernst, Sebastian-Johannes & Hügenell, Philipp P.C. & Bart, Hans-Jörg & Henninger, Stefan K. & Alsaman, Ahmed S., 2017. "High potential of employing bentonite in adsorption cooling systems driven by low grade heat source temperatures," Energy, Elsevier, vol. 141(C), pages 782-791.
    2. Brancato, V. & Frazzica, A. & Sapienza, A. & Gordeeva, L. & Freni, A., 2015. "Ethanol adsorption onto carbonaceous and composite adsorbents for adsorptive cooling system," Energy, Elsevier, vol. 84(C), pages 177-185.
    3. Xu, Zhou & Yin, Yu & Shao, Junpeng & Liu, Yerong & Zhang, Lin & Cui, Qun & Wang, Haiyan, 2020. "Study on heat transfer and cooling performance of copper foams cured MIL-101 adsorption unit tube," Energy, Elsevier, vol. 191(C).
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    5. Frazzica, A. & Palomba, V. & Dawoud, B. & Gullì, G. & Brancato, V. & Sapienza, A. & Vasta, S. & Freni, A. & Costa, F. & Restuccia, G., 2016. "Design, realization and testing of an adsorption refrigerator based on activated carbon/ethanol working pair," Applied Energy, Elsevier, vol. 174(C), pages 15-24.
    6. Henninger, Stefan K. & Ernst, Sebastian-Johannes & Gordeeva, Larisa & Bendix, Phillip & Fröhlich, Dominik & Grekova, Alexandra D. & Bonaccorsi, Lucio & Aristov, Yuri & Jaenchen, Jochen, 2017. "New materials for adsorption heat transformation and storage," Renewable Energy, Elsevier, vol. 110(C), pages 59-68.
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    8. Shabir, Faizan & Sultan, Muhammad & Miyazaki, Takahiko & Saha, Bidyut B. & Askalany, Ahmed & Ali, Imran & Zhou, Yuguang & Ahmad, Riaz & Shamshiri, Redmond R., 2020. "Recent updates on the adsorption capacities of adsorbent-adsorbate pairs for heat transformation applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    9. Mohammed, Ramy H. & Rezk, Ahmed & Askalany, Ahmed & Ali, Ehab S. & Zohir, A.E. & Sultan, Muhammad & Ghazy, Mohamed & Abdelkareem, Mohammad Ali & Olabi, A.G., 2021. "Metal-organic frameworks in cooling and water desalination: Synthesis and application," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    10. Marcin Sowa & Karol Sztekler & Agata Mlonka-Mędrala & Łukasz Mika, 2023. "An Overview of Developments In Silica Gel Matrix Composite Sorbents for Adsorption Chillers with Desalination Function," Energies, MDPI, vol. 16(15), pages 1-34, August.
    11. Mikhaeil, Makram & Gaderer, Matthias & Dawoud, Belal, 2020. "On the development of an innovative adsorber plate heat exchanger for adsorption heat transformation processes; an experimental and numerical study," Energy, Elsevier, vol. 207(C).
    12. Korhammer, Kathrin & Neumann, Karsten & Opel, Oliver & Ruck, Wolfgang K.L., 2018. "Thermodynamic and kinetic study of CaCl2-CH3OH adducts for solid sorption refrigeration by TGA/DSC," Applied Energy, Elsevier, vol. 230(C), pages 1255-1278.
    13. Ma, Liejun & Yang, Huan & Wu, Qi & Yin, Yu & Liu, Zongjian & Cui, Qun & Wang, Haiyan, 2015. "Study on adsorption refrigeration performance of MIL-101-isobutane working pair," Energy, Elsevier, vol. 93(P1), pages 786-794.
    14. Gado, Mohamed G. & Ookawara, Shinichi & Nada, Sameh & El-Sharkawy, Ibrahim I., 2021. "Hybrid sorption-vapor compression cooling systems: A comprehensive overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    15. Gordeeva, L.G. & Aristov, Yu.I., 2019. "Adsorptive heat storage and amplification: New cycles and adsorbents," Energy, Elsevier, vol. 167(C), pages 440-453.

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