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Ethanol adsorption onto metal organic framework: Theory and experiments

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  • Saha, Bidyut Baran
  • El-Sharkawy, Ibrahim I.
  • Miyazaki, Takahiko
  • Koyama, Shigeru
  • Henninger, Stefan K.
  • Herbst, Annika
  • Janiak, Christoph

Abstract

This paper presents experimental and theoretical investigations of adsorption characteristics of ethanol onto metal organic framework namely MIL-101Cr. Adsorption isotherms and kinetics of the studied pair have been measured gravimetrically using a magnetic suspension adsorption measurement unit and volumetrically employing a Quantachrome Autosorb iQ MP machine. The present experiments have been conducted within relative pressures between 0.1 and 0.9 and adsorption temperatures ranging from 30 to 70 °C, which are suitable for adsorption cooling applications. Adsorption isotherm data exhibit that 1 kg of MIL-101Cr can adsorb as high as 1.1 kg of ethanol at adsorption temperature of 30 °C, and the Tóth equation has been used to fit the experimentally measured data. As of the experimentally measured adsorption uptake rate data, the Fickian diffusion model is found to be suitable. These data are essential for designing a new generation of adsorption chiller.

Suggested Citation

  • Saha, Bidyut Baran & El-Sharkawy, Ibrahim I. & Miyazaki, Takahiko & Koyama, Shigeru & Henninger, Stefan K. & Herbst, Annika & Janiak, Christoph, 2015. "Ethanol adsorption onto metal organic framework: Theory and experiments," Energy, Elsevier, vol. 79(C), pages 363-370.
    • Handle: RePEc:eee:energy:v:79:y:2015:i:c:p:363-370
    DOI: 10.1016/j.energy.2014.11.022
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    10. Marcin Sowa & Karol Sztekler & Agata Mlonka-Mędrala & Łukasz Mika, 2023. "An Overview of Developments In Silica Gel Matrix Composite Sorbents for Adsorption Chillers with Desalination Function," Energies, MDPI, vol. 16(15), pages 1-34, August.
    11. Mikhaeil, Makram & Gaderer, Matthias & Dawoud, Belal, 2020. "On the development of an innovative adsorber plate heat exchanger for adsorption heat transformation processes; an experimental and numerical study," Energy, Elsevier, vol. 207(C).
    12. Korhammer, Kathrin & Neumann, Karsten & Opel, Oliver & Ruck, Wolfgang K.L., 2018. "Thermodynamic and kinetic study of CaCl2-CH3OH adducts for solid sorption refrigeration by TGA/DSC," Applied Energy, Elsevier, vol. 230(C), pages 1255-1278.
    13. Ma, Liejun & Yang, Huan & Wu, Qi & Yin, Yu & Liu, Zongjian & Cui, Qun & Wang, Haiyan, 2015. "Study on adsorption refrigeration performance of MIL-101-isobutane working pair," Energy, Elsevier, vol. 93(P1), pages 786-794.
    14. Gado, Mohamed G. & Ookawara, Shinichi & Nada, Sameh & El-Sharkawy, Ibrahim I., 2021. "Hybrid sorption-vapor compression cooling systems: A comprehensive overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
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