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Measurement of CO 2 adsorption kinetics on activated carbons suitable for gas storage systems

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  • Vinod Kumar Singh
  • E. Anil Kumar

Abstract

The adsorption kinetics of CO 2 on three commercially available activated carbons namely Norit RB3 (steam activated rod) (RB3), Norit Darco 100 mesh size (Darco 100 mesh), and Norit Darco 12 × 20 US mesh size (Darco 12 × 20) are measured using Sievert's apparatus at different supply pressures (1, 5, 10, and 20 bar) and temperatures (298, 308, 318, and 338 K). Extracts of experimental results of CO 2 adsorption kinetics are used for mathematical modelling using different standard models, such as pseudo‐first order, pseudo‐second order, Elovich, and intra‐particle diffusion kinetics models. The adsorbate‐adsorbent interactions and kinetics behavior of CO 2 adsorption on adsorbents are deduced from the best‐fitted kinetics model. Based on coefficient of correlation and normalized standard deviation, it has been found that pseudo‐second order kinetics model very well suits with the experimental data of CO 2 adsorption kinetics. Activation energies at different pressures are calculated by fitting the Arrhenius equation to the adsorption kinetics data. Analysis of the mechanism of interaction between CO 2 molecules and adsorbents during the adsorption process is attempted using interparticle and Boyd's diffusion models. It has been found that the film‐diffusion is an important rate controlling step in CO 2 adsorption process. © 2016 Society of Chemical Industry and John Wiley & Sons, Ltd.

Suggested Citation

  • Vinod Kumar Singh & E. Anil Kumar, 2017. "Measurement of CO 2 adsorption kinetics on activated carbons suitable for gas storage systems," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 7(1), pages 182-201, February.
    • Handle: RePEc:wly:greenh:v:7:y:2017:i:1:p:182-201
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    File URL: http://hdl.handle.net/10.1002/ghg.1641
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    References listed on IDEAS

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    1. Rashidi, Nor Adilla & Yusup, Suzana & Hameed, Bassim H., 2013. "Kinetic studies on carbon dioxide capture using lignocellulosic based activated carbon," Energy, Elsevier, vol. 61(C), pages 440-446.
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    Cited by:

    1. Pan, Ruming & Martins, Marcio Ferreira & Debenest, Gérald, 2022. "Optimization of oil production through ex-situ catalytic pyrolysis of waste polyethylene with activated carbon," Energy, Elsevier, vol. 248(C).
    2. Zongxiao Hu & Guozhi Fan & Yuexin Wang & Jianfen Li & Guangsen Song, 2018. "Synthesis of cyclic carbonate via the coupling reaction of carbon dioxide with epoxide at ambient pressure," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 8(3), pages 570-579, June.
    3. Singh, Vinod Kumar & Kumar, E. Anil & Saha, Bidyut Baran, 2018. "Adsorption isotherms, kinetics and thermodynamic simulation of CO2-CSAC pair for cooling application," Energy, Elsevier, vol. 160(C), pages 1158-1173.
    4. Yanchi Jiang & Zhongxiao Zhang & Haojie Fan & Junjie Fan & Haiquan An, 2018. "Experimental study on hybrid MS†CA system for post†combustion CO2 capture," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 8(2), pages 379-392, April.

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