IDEAS home Printed from https://ideas.repec.org/a/wly/greenh/v7y2017i1p182-201.html
   My bibliography  Save this article

Measurement of CO 2 adsorption kinetics on activated carbons suitable for gas storage systems

Author

Listed:
  • Vinod Kumar Singh
  • E. Anil Kumar

Abstract

The adsorption kinetics of CO 2 on three commercially available activated carbons namely Norit RB3 (steam activated rod) (RB3), Norit Darco 100 mesh size (Darco 100 mesh), and Norit Darco 12 × 20 US mesh size (Darco 12 × 20) are measured using Sievert's apparatus at different supply pressures (1, 5, 10, and 20 bar) and temperatures (298, 308, 318, and 338 K). Extracts of experimental results of CO 2 adsorption kinetics are used for mathematical modelling using different standard models, such as pseudo‐first order, pseudo‐second order, Elovich, and intra‐particle diffusion kinetics models. The adsorbate‐adsorbent interactions and kinetics behavior of CO 2 adsorption on adsorbents are deduced from the best‐fitted kinetics model. Based on coefficient of correlation and normalized standard deviation, it has been found that pseudo‐second order kinetics model very well suits with the experimental data of CO 2 adsorption kinetics. Activation energies at different pressures are calculated by fitting the Arrhenius equation to the adsorption kinetics data. Analysis of the mechanism of interaction between CO 2 molecules and adsorbents during the adsorption process is attempted using interparticle and Boyd's diffusion models. It has been found that the film‐diffusion is an important rate controlling step in CO 2 adsorption process. © 2016 Society of Chemical Industry and John Wiley & Sons, Ltd.

Suggested Citation

  • Vinod Kumar Singh & E. Anil Kumar, 2017. "Measurement of CO 2 adsorption kinetics on activated carbons suitable for gas storage systems," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 7(1), pages 182-201, February.
    • Handle: RePEc:wly:greenh:v:7:y:2017:i:1:p:182-201
    as

    Download full text from publisher

    File URL: http://hdl.handle.net/10.1002/ghg.1641
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Rashidi, Nor Adilla & Yusup, Suzana & Hameed, Bassim H., 2013. "Kinetic studies on carbon dioxide capture using lignocellulosic based activated carbon," Energy, Elsevier, vol. 61(C), pages 440-446.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Pan, Ruming & Martins, Marcio Ferreira & Debenest, Gérald, 2022. "Optimization of oil production through ex-situ catalytic pyrolysis of waste polyethylene with activated carbon," Energy, Elsevier, vol. 248(C).
    2. Singh, Vinod Kumar & Kumar, E. Anil & Saha, Bidyut Baran, 2018. "Adsorption isotherms, kinetics and thermodynamic simulation of CO2-CSAC pair for cooling application," Energy, Elsevier, vol. 160(C), pages 1158-1173.
    3. Yanchi Jiang & Zhongxiao Zhang & Haojie Fan & Junjie Fan & Haiquan An, 2018. "Experimental study on hybrid MS†CA system for post†combustion CO2 capture," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 8(2), pages 379-392, April.
    4. Zongxiao Hu & Guozhi Fan & Yuexin Wang & Jianfen Li & Guangsen Song, 2018. "Synthesis of cyclic carbonate via the coupling reaction of carbon dioxide with epoxide at ambient pressure," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 8(3), pages 570-579, June.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Gao, Pin & Zhou, Yiyuan & Meng, Fang & Zhang, Yihui & Liu, Zhenhong & Zhang, Wenqi & Xue, Gang, 2016. "Preparation and characterization of hydrochar from waste eucalyptus bark by hydrothermal carbonization," Energy, Elsevier, vol. 97(C), pages 238-245.
    2. Huang, Yu-Fong & Chiueh, Pei-Te & Shih, Chun-Hao & Lo, Shang-Lien & Sun, Liping & Zhong, Yuan & Qiu, Chunsheng, 2015. "Microwave pyrolysis of rice straw to produce biochar as an adsorbent for CO2 capture," Energy, Elsevier, vol. 84(C), pages 75-82.
    3. Ridha, Firas N. & Manovic, Vasilije & Macchi, Arturo & Anthony, Edward J., 2015. "CO2 capture at ambient temperature in a fixed bed with CaO-based sorbents," Applied Energy, Elsevier, vol. 140(C), pages 297-303.
    4. Mulu, Elshaday & M'Arimi, Milton M. & Ramkat, Rose C., 2021. "A review of recent developments in application of low cost natural materials in purification and upgrade of biogas," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    5. Sreenivasulu, B. & Gayatri, D.V. & Sreedhar, I. & Raghavan, K.V., 2015. "A journey into the process and engineering aspects of carbon capture technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 1324-1350.
    6. Tan, Y.L. & Islam, Md. Azharul & Asif, M. & Hameed, B.H., 2014. "Adsorption of carbon dioxide by sodium hydroxide-modified granular coconut shell activated carbon in a fixed bed," Energy, Elsevier, vol. 77(C), pages 926-931.
    7. Benedetti, Vittoria & Patuzzi, Francesco & Baratieri, Marco, 2018. "Characterization of char from biomass gasification and its similarities with activated carbon in adsorption applications," Applied Energy, Elsevier, vol. 227(C), pages 92-99.
    8. Heo, Young-Jung & Park, Soo-Jin, 2015. "A role of steam activation on CO2 capture and separation of narrow microporous carbons produced from cellulose fibers," Energy, Elsevier, vol. 91(C), pages 142-150.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:wly:greenh:v:7:y:2017:i:1:p:182-201. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Wiley Content Delivery (email available below). General contact details of provider: https://doi.org/10.1002/(ISSN)2152-3878 .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.