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Low-cost Ca-based composites synthesized by biotemplate method for thermochemical energy storage of concentrated solar power

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  • Benitez-Guerrero, Monica
  • Valverde, Jose Manuel
  • Perejon, Antonio
  • Sanchez-Jimenez, Pedro E.
  • Perez-Maqueda, Luis A.

Abstract

An ever more environmentally conscious society demands the use of green, sustainable and high-efficiency renewable energy resources. However, large-scale energy storage remains a challenge for a deep penetration of power produced from renewables into the grid. The Calcium-Looping (CaL) process, based on the reversible carbonation/calcination of CaO, is a promising technology for thermochemical energy storage (TCES) in Concentrated Solar Power (CSP) plants. Natural limestone to be used as CaO precursor is cheap, non-toxic and abundant. Nevertheless, recent works have shown that carbonation of CaO derived limestone at optimum conditions for TCES is limited by pore-plugging, which leads to severe deactivation for large enough particles to be employed in practice. In our work, we have synthesized inexpensive CaO/SiO2 composites by means of a biotemplate method using rice husk as support. The morphological and compositional features of the biomorphic materials synthesized help improve the CaO multicycle activity under optimum CSP storage conditions and for particles sufficiently large to be managed in practical processes.

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  • Benitez-Guerrero, Monica & Valverde, Jose Manuel & Perejon, Antonio & Sanchez-Jimenez, Pedro E. & Perez-Maqueda, Luis A., 2018. "Low-cost Ca-based composites synthesized by biotemplate method for thermochemical energy storage of concentrated solar power," Applied Energy, Elsevier, vol. 210(C), pages 108-116.
    • Handle: RePEc:eee:appene:v:210:y:2018:i:c:p:108-116
    DOI: 10.1016/j.apenergy.2017.10.109
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    Cited by:

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    5. Ortiz, C. & Valverde, J.M. & Chacartegui, R. & Perez-Maqueda, L.A. & Giménez, P., 2019. "The Calcium-Looping (CaCO3/CaO) process for thermochemical energy storage in Concentrating Solar Power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    6. Ying Yang & Yingjie Li & Xianyao Yan & Jianli Zhao & Chunxiao Zhang, 2021. "Development of Thermochemical Heat Storage Based on CaO/CaCO 3 Cycles: A Review," Energies, MDPI, vol. 14(20), pages 1-26, October.
    7. Abanades, Stéphane & André, Laurie, 2018. "Design and demonstration of a high temperature solar-heated rotary tube reactor for continuous particles calcination," Applied Energy, Elsevier, vol. 212(C), pages 1310-1320.
    8. Rehan Anwar & M. Veronica Sofianos, 2024. "Exploring the Role of Additives in Enhancing the Performance of Limestone-Based Thermochemical Energy Storage: A Review," Energies, MDPI, vol. 17(11), pages 1-20, May.
    9. Han, Rui & Gao, Jihui & Wei, Siyu & Su, Yanlin & Sun, Fei & Zhao, Guangbo & Qin, Yukun, 2018. "Strongly coupled calcium carbonate/antioxidative graphite nanosheets composites with high cycling stability for thermochemical energy storage," Applied Energy, Elsevier, vol. 231(C), pages 412-422.
    10. Nemś, Magdalena & Kasperski, Jacek & Nemś, Artur & Bać, Anna, 2018. "Validation of a new concept of a solar air heating system with a long-term granite storage bed for a single-family house," Applied Energy, Elsevier, vol. 215(C), pages 384-395.
    11. Li, Caili & Li, Yingjie & Fang, Yi & Zhang, Chunxiao & Ren, Yu, 2024. "TiO2/MnFe2O4 co-modified alkaline papermaking waste for CaO-CaCO3 thermochemical energy storage," Applied Energy, Elsevier, vol. 362(C).
    12. Khosa, Azhar Abbas & Yan, J. & Zhao, C.Y., 2021. "Investigating the effects of ZnO dopant on the thermodynamic and kinetic properties of CaCO3/CaO TCES system," Energy, Elsevier, vol. 215(PA).
    13. Carlos Ortiz, 2021. "Thermochemical Energy Storage Based on Carbonates: A Brief Overview," Energies, MDPI, vol. 14(14), pages 1-3, July.
    14. Sun, Hao & Li, Yingjie & Yan, Xianyao & Zhao, Jianli & Wang, Zeyan, 2020. "Thermochemical energy storage performance of Al2O3/CeO2 co-doped CaO-based material under high carbonation pressure," Applied Energy, Elsevier, vol. 263(C).
    15. Ma, Zhangke & Li, Yingjie & Zhang, Wan & Wang, Yuzhuo & Zhao, Jianli & Wang, Zeyan, 2020. "Energy storage and attrition performance of limestone under fluidization during CaO/CaCO3 cycles," Energy, Elsevier, vol. 207(C).
    16. Ortiz, C. & Romano, M.C. & Valverde, J.M. & Binotti, M. & Chacartegui, R., 2018. "Process integration of Calcium-Looping thermochemical energy storage system in concentrating solar power plants," Energy, Elsevier, vol. 155(C), pages 535-551.
    17. Wong-Pinto, Liey-Si & Milian, Yanio & Ushak, Svetlana, 2020. "Progress on use of nanoparticles in salt hydrates as phase change materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 122(C).
    18. Sánchez Jiménez, Pedro E. & Perejón, Antonio & Benítez Guerrero, Mónica & Valverde, José M. & Ortiz, Carlos & Pérez Maqueda, Luis A., 2019. "High-performance and low-cost macroporous calcium oxide based materials for thermochemical energy storage in concentrated solar power plants," Applied Energy, Elsevier, vol. 235(C), pages 543-552.
    19. Ma, Xiaotong & Li, Yingjie & Duan, Lunbo & Anthony, Edward & Liu, Hantao, 2018. "CO2 capture performance of calcium-based synthetic sorbent with hollow core-shell structure under calcium looping conditions," Applied Energy, Elsevier, vol. 225(C), pages 402-412.

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