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Effect of torrefaction on the pyrolysis characteristics of high moisture herbaceous residues

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  • Xin, Shanzhi
  • Mi, Tie
  • Liu, Xiaoye
  • Huang, Fang

Abstract

High moisture herbaceous residues (HR) cause a series of environment problems. Torrefaction has proven to be a promising technology for upgrading the fuel properties of biomass. In this study, a typical HR, Licorice residue (LR), was torrefied in a tubular reactor under nitrogen at 210, 240 and 280 °C. The effect of temperature on the fuel properties and the decomposition characteristic of the torrefied samples, as well as the pyrolysis products, were investigated. The mass and energy yield were altered in the range of 91.8–52.3% and 99.3–72.9%, respectively. The higher heating value (HHV) value of the torrefied sample increased by 8.1–39.5% from light to severe torrefaction, compared to untorrefied LR, and reached up to 23.3 MJ/kg at 280 °C. Torrefaction decreased the content of oxygenated organic compounds and the acidity of bio-oil from pyrolysis. The increase in alkanes from torrefied sample pyrolysis implies that torrefied LR has the potential for use in liquid fuel production. The present findings revealed that torrefaction turns industrial LR with poor energy content into a more easily exploitable solid fuel.

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  • Xin, Shanzhi & Mi, Tie & Liu, Xiaoye & Huang, Fang, 2018. "Effect of torrefaction on the pyrolysis characteristics of high moisture herbaceous residues," Energy, Elsevier, vol. 152(C), pages 586-593.
    • Handle: RePEc:eee:energy:v:152:y:2018:i:c:p:586-593
    DOI: 10.1016/j.energy.2018.03.104
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    10. Xin, Shanzhi & Huang, Fang & Qi, Wei & Mi, Tie, 2020. "Pyrolysis of torrefied herbal medicine wastes: Characterization of pyrolytic products," Energy, Elsevier, vol. 210(C).
    11. Abdulyekeen, Kabir Abogunde & Daud, Wan Mohd Ashri Wan & Patah, Muhamad Fazly Abdul, 2024. "Torrefaction of wood and garden wastes from municipal solid waste to enhanced solid fuel using helical screw rotation-induced fluidised bed reactor: Effect of particle size, helical screw speed and te," Energy, Elsevier, vol. 293(C).
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    13. Bai, Xiaopeng & Wang, Guanghui & Zhu, Zheng & Cai, Chen & Wang, Zhiqin & Wang, Decheng, 2020. "Investigation of improving the yields and qualities of pyrolysis products with combination rod-milled and torrefaction pretreatment," Renewable Energy, Elsevier, vol. 151(C), pages 446-453.
    14. Yek, Peter Nai Yuh & Chen, Xiangmeng & Peng, Wanxi & Liew, Rock Keey & Cheng, Chin Kui & Sonne, Christian & Sii, How Sing & Lam, Su Shiung, 2021. "Microwave co-torrefaction of waste oil and biomass pellets for simultaneous recovery of waste and co-firing fuel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    15. Tang, Shouhang & Zhou, Sicheng & Li, Ge & Xin, Shanzhi & Huang, Fang & Liu, Xiaoye & Huang, Kai & Zeng, Lixi & Mi, Tie, 2023. "Combination of torrefaction and catalytic fast pyrolysis for aromatic hydrocarbon production from herbaceous medicine waste," Energy, Elsevier, vol. 270(C).
    16. da Silva, Jean Constantino Gomes & Pereira, Jefferson Leque Claudio & Andersen, Silvia Layara Floriani & Moreira, Regina de Fatima Peralta Muniz & José, Humberto Jorge, 2020. "Torrefaction of ponkan peel waste in tubular fixed-bed reactor: In-depth bioenergetic evaluation of torrefaction products," Energy, Elsevier, vol. 210(C).
    17. Chen, Zhiyun & Liu, Jingyong & Chen, Huashan & Ding, Ziyi & Tang, Xiaojie & Evrendilek, Fatih, 2022. "Oxy-fuel and air atmosphere combustions of Chinese medicine residues: Performances, mechanisms, flue gas emission, and ash properties," Renewable Energy, Elsevier, vol. 182(C), pages 102-118.
    18. Lin, Xiaona & Kong, Lingshuai & Ren, Xiajin & Zhang, Donghong & Cai, Hongzhen & Lei, Hanwu, 2021. "Catalytic co-pyrolysis of torrefied poplar wood and high-density polyethylene over hierarchical HZSM-5 for mono-aromatics production," Renewable Energy, Elsevier, vol. 164(C), pages 87-95.

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