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Increasing the bio-aromatics yield in the biomass pyrolysis oils by the integration of torrefaction deoxygenation pretreatment and catalytic fast pyrolysis with a dual catalyst system

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  • Tian, Hong
  • Chen, Lei
  • Huang, Zhangjun
  • Cheng, Shan
  • Yang, Yang

Abstract

The integration of Torrefaction Deoxygenation Pretreatment (TDP) and Catalytic Fast Pyrolysis (CFP) with dual catalysts was employed to improve the yield of bio-aromatics (BTX) derived from Miscanthus. Results showed that the TDP could effectively remove the oxygen content up to 38.16% at 280 °C. This resulted in a remarkable reduction of undesired oxygenate compounds in the pyrolysis oil. With ZSM-5 catalyst, the dominant components in pyrolysis oil became aromatic hydrocarbons (up to 66.29%) instead of oxygenates. The selectivity of bio-BTX increased with the increase of torrefaction temperature up to 56.63%. For the pyrolysis process, the highest yield (37.54%) and selectivity (56.63%) of bio-BTX were obtained at 600 °C. Compared with ZSM-5, the addition of CaO and MoO3 promoted bio-BTX yield due to the enhanced deoxygenation and olefins aromatization. The integrated TDP and CFP with ZSM-5 and MoO3 significantly improved the selectivity of bio-BTX, reaching the highest selectivity of 70.69% and a yield of 51.07%. Combining these two processes can enhance bio-aromatics yields from biomass, thus considerably improving the quality and value of the liquid product.

Suggested Citation

  • Tian, Hong & Chen, Lei & Huang, Zhangjun & Cheng, Shan & Yang, Yang, 2022. "Increasing the bio-aromatics yield in the biomass pyrolysis oils by the integration of torrefaction deoxygenation pretreatment and catalytic fast pyrolysis with a dual catalyst system," Renewable Energy, Elsevier, vol. 187(C), pages 561-571.
    • Handle: RePEc:eee:renene:v:187:y:2022:i:c:p:561-571
    DOI: 10.1016/j.renene.2022.01.096
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    References listed on IDEAS

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    1. Liang, Jie & Shan, Guangcun & Sun, Yifei, 2021. "Catalytic fast pyrolysis of lignocellulosic biomass: Critical role of zeolite catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).
    2. Tian, Hong & Hu, Qingsong & Wang, Jiawei & Chen, Donglin & Yang, Yang & Bridgwater, Anthony V., 2021. "Kinetic study on the CO2 gasification of biochar derived from Miscanthus at different processing conditions," Energy, Elsevier, vol. 217(C).
    3. Chen, Wei-Hsin & Lu, Ke-Miao & Lee, Wen-Jhy & Liu, Shih-Hsien & Lin, Ta-Chang, 2014. "Non-oxidative and oxidative torrefaction characterization and SEM observations of fibrous and ligneous biomass," Applied Energy, Elsevier, vol. 114(C), pages 104-113.
    4. Yang, Y. & Brammer, J.G. & Samanya, J. & Hossain, A.K. & Hornung, A., 2013. "Investigation into the performance and emissions of a stationary diesel engine fuelled by sewage sludge intermediate pyrolysis oil and biodiesel blends," Energy, Elsevier, vol. 62(C), pages 269-276.
    5. Nanduri, Arvind & Kulkarni, Shreesh S. & Mills, Patrick L., 2021. "Experimental techniques to gain mechanistic insight into fast pyrolysis of lignocellulosic biomass: A state-of-the-art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    6. Singh, Satyansh & Chakraborty, Jyoti Prasad & Mondal, Monoj Kumar, 2020. "Torrefaction of woody biomass (Acacia nilotica): Investigation of fuel and flow properties to study its suitability as a good quality solid fuel," Renewable Energy, Elsevier, vol. 153(C), pages 711-724.
    7. Xin, Shanzhi & Mi, Tie & Liu, Xiaoye & Huang, Fang, 2018. "Effect of torrefaction on the pyrolysis characteristics of high moisture herbaceous residues," Energy, Elsevier, vol. 152(C), pages 586-593.
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    Cited by:

    1. Riaz, Sajid & Oluwoye, Ibukun & Al-Abdeli, Yasir M., 2022. "Oxidative torrefaction of densified woody biomass: Performance, combustion kinetics and thermodynamics," Renewable Energy, Elsevier, vol. 199(C), pages 908-918.
    2. Li, Yingkai & Zhu, Linyu & Yellezuome, Dominic & Zhou, Zhongyue & Tao, Shanwen & Liu, Ronghou, 2024. "Catalytic pyrolysis of poplar sawdust pretreated with combined leaching and torrefaction over Fe–Ni/ZSM-5 for aromatic-rich bio-oil production," Renewable Energy, Elsevier, vol. 227(C).
    3. Zhu, Liang & Cai, Wei & Li, Jie & Chen, Dengyu & Ma, Zhongqing, 2024. "Highly selective production of light aromatics from co-catalytic fast pyrolysis of pre-deoxygenated biomass and hydrogen-rich polyethylene using a dual-catalyst system," Energy, Elsevier, vol. 296(C).

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