IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v120y2017icp864-871.html
   My bibliography  Save this article

Influence of torrefaction on the characteristics and pyrolysis behavior of cellulose

Author

Listed:
  • Wang, Shurong
  • Dai, Gongxin
  • Ru, Bin
  • Zhao, Yuan
  • Wang, Xiaoliu
  • Xiao, Gang
  • Luo, Zhongyang

Abstract

The influence of torrefaction on cellulose structural characteristics and the resulting pyrolysis behavior was investigated in this study. Torrefaction reduced O/C ratio in cellulose and increased its high heating value. The crystallinity of cellulose increased slightly first and then decreased sharply with the increase of torrefaction temperature, which could be ascribed to competitive degradation between crystalline region and amorphous region, as indicated by 13C CP/MAS NMR analysis. Besides, the cleavage of β-1,4-glycosidic bond and the dehydration of hydroxyl were the major reactions occurring in torrefaction. Avrami-Erofeev model was found to be the most suitable kinetic reaction model for explaining the thermogravimetric weight loss during the pyrolysis of the raw and torrefied cellulose. A distributed activation energy model based on Avrami-Erofeev model was subsequently used to reveal the pyrolytic kinetics. It was found that the changes in cellulose structure influenced the kinetic parameters greatly. Torrefaction also changed pyrolytic product distribution. The yields of furfural, alicyclic ketones and anhydrosugars increased while that of 5-hydroxymethyl-furfural decreased as torrefaction temperature increased.

Suggested Citation

  • Wang, Shurong & Dai, Gongxin & Ru, Bin & Zhao, Yuan & Wang, Xiaoliu & Xiao, Gang & Luo, Zhongyang, 2017. "Influence of torrefaction on the characteristics and pyrolysis behavior of cellulose," Energy, Elsevier, vol. 120(C), pages 864-871.
    • Handle: RePEc:eee:energy:v:120:y:2017:i:c:p:864-871
    DOI: 10.1016/j.energy.2016.11.135
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544216317923
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2016.11.135?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Chen, Wei-Hsin & Peng, Jianghong & Bi, Xiaotao T., 2015. "A state-of-the-art review of biomass torrefaction, densification and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 847-866.
    2. Chen, Wei-Hsin & Kuo, Po-Chih, 2011. "Torrefaction and co-torrefaction characterization of hemicellulose, cellulose and lignin as well as torrefaction of some basic constituents in biomass," Energy, Elsevier, vol. 36(2), pages 803-811.
    3. Chen, Wei-Hsin & Hsu, Huan-Chun & Lu, Ke-Miao & Lee, Wen-Jhy & Lin, Ta-Chang, 2011. "Thermal pretreatment of wood (Lauan) block by torrefaction and its influence on the properties of the biomass," Energy, Elsevier, vol. 36(5), pages 3012-3021.
    4. Chen, Wei-Hsin & Kuo, Po-Chih, 2011. "Isothermal torrefaction kinetics of hemicellulose, cellulose, lignin and xylan using thermogravimetric analysis," Energy, Elsevier, vol. 36(11), pages 6451-6460.
    5. Rodriguez Alonso, Elvira & Dupont, Capucine & Heux, Laurent & Da Silva Perez, Denilson & Commandre, Jean-Michel & Gourdon, Christophe, 2016. "Study of solid chemical evolution in torrefaction of different biomasses through solid-state 13C cross-polarization/magic angle spinning NMR (nuclear magnetic resonance) and TGA (thermogravimetric ana," Energy, Elsevier, vol. 97(C), pages 381-390.
    6. Park, Sang-Woo & Jang, Cheol-Hyeon & Baek, Kyung-Ryul & Yang, Jae-Kyung, 2012. "Torrefaction and low-temperature carbonization of woody biomass: Evaluation of fuel characteristics of the products," Energy, Elsevier, vol. 45(1), pages 676-685.
    7. Wen, Jia-Long & Sun, Shao-Long & Yuan, Tong-Qi & Xu, Feng & Sun, Run-Cang, 2014. "Understanding the chemical and structural transformations of lignin macromolecule during torrefaction," Applied Energy, Elsevier, vol. 121(C), pages 1-9.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ong, Hwai Chyuan & Yu, Kai Ling & Chen, Wei-Hsin & Pillejera, Ma Katreena & Bi, Xiaotao & Tran, Khanh-Quang & Pétrissans, Anelie & Pétrissans, Mathieu, 2021. "Variation of lignocellulosic biomass structure from torrefaction: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    2. Batidzirai, B. & Mignot, A.P.R. & Schakel, W.B. & Junginger, H.M. & Faaij, A.P.C., 2013. "Biomass torrefaction technology: Techno-economic status and future prospects," Energy, Elsevier, vol. 62(C), pages 196-214.
    3. Chen, Wei-Hsin & Peng, Jianghong & Bi, Xiaotao T., 2015. "A state-of-the-art review of biomass torrefaction, densification and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 847-866.
    4. Chen, Wei-Hsin & Liu, Shih-Hsien & Juang, Tarng-Tzuen & Tsai, Chi-Ming & Zhuang, Yi-Qing, 2015. "Characterization of solid and liquid products from bamboo torrefaction," Applied Energy, Elsevier, vol. 160(C), pages 829-835.
    5. Wilk, Małgorzata & Magdziarz, Aneta & Kalemba, Izabela, 2015. "Characterisation of renewable fuels' torrefaction process with different instrumental techniques," Energy, Elsevier, vol. 87(C), pages 259-269.
    6. Jaime Martín-Pascual & Joaquín Jódar & Miguel L. Rodríguez & Montserrat Zamorano, 2020. "Determination of the Optimal Operative Conditions for the Torrefaction of Olive Waste Biomass," Sustainability, MDPI, vol. 12(16), pages 1-11, August.
    7. Wu, Keng-Tung & Tsai, Chia-Ju & Chen, Chih-Shen & Chen, Hsiao-Wei, 2012. "The characteristics of torrefied microalgae," Applied Energy, Elsevier, vol. 100(C), pages 52-57.
    8. Nocquet, Timothée & Dupont, Capucine & Commandre, Jean-Michel & Grateau, Maguelone & Thiery, Sébastien & Salvador, Sylvain, 2014. "Volatile species release during torrefaction of wood and its macromolecular constituents: Part 1 – Experimental study," Energy, Elsevier, vol. 72(C), pages 180-187.
    9. Niu, Yanqing & Lv, Yuan & Lei, Yu & Liu, Siqi & Liang, Yang & Wang, Denghui & Hui, Shi'en, 2019. "Biomass torrefaction: properties, applications, challenges, and economy," Renewable and Sustainable Energy Reviews, Elsevier, vol. 115(C).
    10. Wang, L. & Barta-Rajnai, E. & Skreiberg, Ø. & Khalil, R. & Czégény, Z. & Jakab, E. & Barta, Z. & Grønli, M., 2018. "Effect of torrefaction on physiochemical characteristics and grindability of stem wood, stump and bark," Applied Energy, Elsevier, vol. 227(C), pages 137-148.
    11. Silveira, Edgar A. & Macedo, Lucélia A. & Rousset, Patrick & Candelier, Kevin & Galvão, Luiz Gustavo O. & Chaves, Bruno S. & Commandré, Jean-Michel, 2022. "A potassium responsive numerical path to model catalytic torrefaction kinetics," Energy, Elsevier, vol. 239(PB).
    12. Wilk, Małgorzata & Magdziarz, Aneta & Kalemba, Izabela & Gara, Paweł, 2016. "Carbonisation of wood residue into charcoal during low temperature process," Renewable Energy, Elsevier, vol. 85(C), pages 507-513.
    13. Granados, D.A. & Ruiz, R.A. & Vega, L.Y. & Chejne, F., 2017. "Study of reactivity reduction in sugarcane bagasse as consequence of a torrefaction process," Energy, Elsevier, vol. 139(C), pages 818-827.
    14. Álvarez, Ana & Nogueiro, Dositeo & Pizarro, Consuelo & Matos, María & Bueno, Julio L., 2018. "Non-oxidative torrefaction of biomass to enhance its fuel properties," Energy, Elsevier, vol. 158(C), pages 1-8.
    15. Stroh, Alexander & Alobaid, Falah & Busch, Jan-Peter & Ströhle, Jochen & Epple, Bernd, 2015. "3-D numerical simulation for co-firing of torrefied biomass in a pulverized-fired 1 MWth combustion chamber," Energy, Elsevier, vol. 85(C), pages 105-116.
    16. Arriola, Emmanuel & Chen, Wei-Hsin & Chih, Yi-Kai & De Luna, Mark Daniel & Show, Pau Loke, 2020. "Impact of post-torrefaction process on biochar formation from wood pellets and self-heating phenomena for production safety," Energy, Elsevier, vol. 207(C).
    17. Madanayake, Buddhike Neminda & Gan, Suyin & Eastwick, Carol & Ng, Hoon Kiat, 2016. "Thermochemical and structural changes in Jatropha curcas seed cake during torrefaction for its use as coal co-firing feedstock," Energy, Elsevier, vol. 100(C), pages 262-272.
    18. Abdulyekeen, Kabir Abogunde & Umar, Ahmad Abulfathi & Patah, Muhamad Fazly Abdul & Daud, Wan Mohd Ashri Wan, 2021. "Torrefaction of biomass: Production of enhanced solid biofuel from municipal solid waste and other types of biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    19. Chen, Wei-Hsin & Kuo, Po-Chih & Liu, Shih-Hsien & Wu, Wei, 2014. "Thermal characterization of oil palm fiber and eucalyptus in torrefaction," Energy, Elsevier, vol. 71(C), pages 40-48.
    20. Lu, Ke-Miao & Lee, Wen-Jhy & Chen, Wei-Hsin & Lin, Ta-Chang, 2013. "Thermogravimetric analysis and kinetics of co-pyrolysis of raw/torrefied wood and coal blends," Applied Energy, Elsevier, vol. 105(C), pages 57-65.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:120:y:2017:i:c:p:864-871. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.