IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v88y2011i1p316-322.html
   My bibliography  Save this article

Products properties from fast pyrolysis of enzymatic/mild acidolysis lignin

Author

Listed:
  • Lou, Rui
  • Wu, Shu-bin

Abstract

The conversion of enzymatic/mild acidolysis lignin (EMAL) isolated from moso bamboo to aromatic chemicals by fast pyrolysis were investigated under nitrogen atmosphere and atmospheric pressure. The experiment of EMAL pyrolyzing was set on a tubular reactor furnace at the temperature levels of 400, 500, 600, 700, 800 and 900 °C, and the products derived from EMAL pyrolyzing were classified into three-phase of gas, condensed liquid (tar), and solid (char). The chemical structure and surface morphology of solid product were characterized by fourier transforms infrared spectroscopy (FTIR) and scanning electron microscopy (SEM), and the ingredients of gas product and liquid (tar) were analyzed with gas chromatography (GC) and gas chromatography/mass spectrometer (GC/MS). The analysis results indicated that the yield of char decreased rapidly from 43% to 28% with an increase of temperature, and the yield of gas product increased gradually from 6% to 26%, and the yield of tar attained a maximum at 700 °C. SEM showed that char took on lots of vesicles that resulted from the gas release from EMAL pyrolyzing. The ingredients of gas product were comprised of H2, CO, CO2 and light hydrocarbons (CH4, C2H4 and C2H6), and the amount of H2, CO were high. Besides a huge amount of phenols, the tar contained aromatic hydrocarbons, chain hydrocarbons, monoaromatic aromatic hydrocarbons and some ketones, and the carbon number of chemical compounds were C6-C10.

Suggested Citation

  • Lou, Rui & Wu, Shu-bin, 2011. "Products properties from fast pyrolysis of enzymatic/mild acidolysis lignin," Applied Energy, Elsevier, vol. 88(1), pages 316-322, January.
    • Handle: RePEc:eee:appene:v:88:y:2011:i:1:p:316-322
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306-2619(10)00264-3
    Download Restriction: Full text for ScienceDirect subscribers only
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Behera, Shuvashish & Mohanty, Rama Chandra & Ray, Ramesh Chandra, 2010. "Comparative study of bio-ethanol production from mahula (Madhuca latifolia L.) flowers by Saccharomyces cerevisiae and Zymomonas mobilis," Applied Energy, Elsevier, vol. 87(7), pages 2352-2355, July.
    2. Behera, Shuvashish & Kar, Shaktimay & Mohanty, Rama Chandra & Ray, Ramesh Chandra, 2010. "Comparative study of bio-ethanol production from mahula (Madhuca latifolia L.) flowers by Saccharomyces cerevisiae cells immobilized in agar agar and Ca-alginate matrices," Applied Energy, Elsevier, vol. 87(1), pages 96-100, January.
    3. Mesa, Leyanis & González, Erenio & Ruiz, Encarnación & Romero, Inmaculada & Cara, Cristóbal & Felissia, Fernando & Castro, Eulogio, 2010. "Preliminary evaluation of organosolv pre-treatment of sugar cane bagasse for glucose production: Application of 23 experimental design," Applied Energy, Elsevier, vol. 87(1), pages 109-114, January.
    4. Cardoso, Marcelo & de Oliveira, Kátia Dionísio & Costa, George Alberto Avelar & Passos, Maria Laura, 2009. "Chemical process simulation for minimizing energy consumption in pulp mills," Applied Energy, Elsevier, vol. 86(1), pages 45-51, January.
    5. Na, Jae Ik & Park, So Jin & Kim, Yong Koo & Lee, Jae Goo & Kim, Jae Ho, 2003. "Characteristics of oxygen-blown gasification for combustible waste in a fixed-bed gasifier," Applied Energy, Elsevier, vol. 75(3-4), pages 275-285, July.
    6. Fatih Demirbas, M., 2009. "Biorefineries for biofuel upgrading: A critical review," Applied Energy, Elsevier, vol. 86(Supplemen), pages 151-161, November.
    7. Zheng, Yi & Pan, Zhongli & Zhang, Ruihong & Wang, Donghai, 2009. "Enzymatic saccharification of dilute acid pretreated saline crops for fermentable sugar production," Applied Energy, Elsevier, vol. 86(11), pages 2459-2465, November.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Lou, Rui & Wu, Shubin & Lv, Gaojin & Yang, Qing, 2012. "Energy and resource utilization of deinking sludge pyrolysis," Applied Energy, Elsevier, vol. 90(1), pages 46-50.
    2. Long, Jinxing & Shu, Riyang & Yuan, Zhengqiu & Wang, Tiejun & Xu, Ying & Zhang, Xinghua & Zhang, Qi & Ma, Longlong, 2015. "Efficient valorization of lignin depolymerization products in the present of NixMg1−xO," Applied Energy, Elsevier, vol. 157(C), pages 540-545.
    3. Florian Marin & Felicia Bucura & Violeta-Carolina Niculescu & Antoaneta Roman & Oana Romina Botoran & Marius Constantinescu & Stefan Ionuț Spiridon & Eusebiu Ilarian Ionete & Simona Oancea & Anca Mari, 2024. "Mesoporous Silica Nanocatalyst-Based Pyrolysis of a By-Product of Paper Manufacturing, Black Liquor," Sustainability, MDPI, vol. 16(8), pages 1-17, April.
    4. Yue Cao & Yongsheng Sun & Peng Gao & Wenbo Li, 2023. "Utilization of Waste Straw Biomass in Suspension Magnetization Roasting of Refractory Iron Ore: Iron Recovery, Gas Analysis and Roasted Product Characterization," Sustainability, MDPI, vol. 15(22), pages 1-18, November.
    5. Collard, François-Xavier & Blin, Joël, 2014. "A review on pyrolysis of biomass constituents: Mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 594-608.
    6. Marathe, P.S. & Westerhof, R.J.M. & Kersten, S.R.A., 2019. "Fast pyrolysis of lignins with different molecular weight: Experiments and modelling," Applied Energy, Elsevier, vol. 236(C), pages 1125-1137.
    7. Zhang, Xinghua & Wang, Tiejun & Ma, Longlong & Zhang, Qi & Huang, Xiaoming & Yu, Yuxiao, 2013. "Production of cyclohexane from lignin degradation compounds over Ni/ZrO2–SiO2 catalysts," Applied Energy, Elsevier, vol. 112(C), pages 533-538.
    8. Kan, Tao & Strezov, Vladimir & Evans, Tim J., 2016. "Lignocellulosic biomass pyrolysis: A review of product properties and effects of pyrolysis parameters," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1126-1140.
    9. Chen, Xinyang & Cai, Di & Yang, Yumiao & Sun, Yuhang & Wang, Binhui & Yao, Zhitong & Jin, Meiqing & Liu, Jie & Reinmöller, Markus & Badshah, Syed Lal & Magdziarz, Aneta, 2023. "Pyrolysis kinetics of bio-based polyurethane: Evaluating the kinetic parameters, thermodynamic parameters, and complementary product gas analysis using TG/FTIR and TG/GC-MS," Renewable Energy, Elsevier, vol. 205(C), pages 490-498.
    10. Cheng, Feng & Brewer, Catherine E., 2017. "Producing jet fuel from biomass lignin: Potential pathways to alkyl-benzenes and cycloalkanes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 673-722.
    11. Chen, Hao & Su, Xin & He, Jingjing & Zhang, Peng & Xu, Hongming & Zhou, Chenglong, 2021. "Investigation on combustion characteristics of cyclopentanol/diesel fuel blends in an optical engine," Renewable Energy, Elsevier, vol. 167(C), pages 811-829.
    12. Long, Jinxing & Xu, Ying & Wang, Tiejun & Yuan, Zhengqiu & Shu, Riyang & Zhang, Qi & Ma, Longlong, 2015. "Efficient base-catalyzed decomposition and in situ hydrogenolysis process for lignin depolymerization and char elimination," Applied Energy, Elsevier, vol. 141(C), pages 70-79.
    13. Guo, Da-liang & Wu, Shu-bin & Liu, Bei & Yin, Xiu-li & Yang, Qing, 2012. "Catalytic effects of NaOH and Na2CO3 additives on alkali lignin pyrolysis and gasification," Applied Energy, Elsevier, vol. 95(C), pages 22-30.
    14. Fan, Liangliang & Ruan, Roger & Li, Jun & Ma, Longlong & Wang, Chenguang & Zhou, Wenguang, 2020. "Aromatics production from fast co-pyrolysis of lignin and waste cooking oil catalyzed by HZSM-5 zeolite," Applied Energy, Elsevier, vol. 263(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wirawan, Ferdian & Cheng, Chieh-Lun & Kao, Wei-Chen & Lee, Duu-Jong & Chang, Jo-Shu, 2012. "Cellulosic ethanol production performance with SSF and SHF processes using immobilized Zymomonas mobilis," Applied Energy, Elsevier, vol. 100(C), pages 19-26.
    2. Wirawan, Ferdian & Cheng, Chieh-Lun & Lo, Yung-Chung & Chen, Chun-Yen & Chang, Jo-Shu & Leu, Shao-Yuan & Lee, Duu-Jong, 2020. "Continuous cellulosic bioethanol co-fermentation by immobilized Zymomonas mobilis and suspended Pichia stipitis in a two-stage process," Applied Energy, Elsevier, vol. 266(C).
    3. Dodić, Jelena M. & Vučurović, Damjan G. & Dodić, Siniša N. & Grahovac, Jovana A. & Popov, Stevan D. & Nedeljković, Nataša M., 2012. "Kinetic modelling of batch ethanol production from sugar beet raw juice," Applied Energy, Elsevier, vol. 99(C), pages 192-197.
    4. Ntihuga, Jean Nepomuscene & Senn, Thomas & Gschwind, Peter & Kohlus, Reinhard, 2013. "An evaluation of different bioreactor configurations for continuous bio-ethanol production," Applied Energy, Elsevier, vol. 108(C), pages 194-201.
    5. Tripti Agrawal & Afaque Quraishi & Shailesh Kumar Jadhav, 2019. "Bioethanol production from Madhuca latifolia L. flowers by a newly isolated strain of Pichia kudriavzevii," Energy & Environment, , vol. 30(8), pages 1477-1490, December.
    6. Behera, Shuvashish & Arora, Richa & Nandhagopal, N. & Kumar, Sachin, 2014. "Importance of chemical pretreatment for bioconversion of lignocellulosic biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 36(C), pages 91-106.
    7. Mishra, Abhishek & Sharma, Ajay K. & Sharma, Sumit & Bagai, Rashmi & Mathur, Anshu S. & Gupta, Ravi P. & Tuli, Deepak K., 2016. "Lignocellulosic ethanol production employing immobilized Saccharomyces cerevisiae in packed bed reactor," Renewable Energy, Elsevier, vol. 98(C), pages 57-63.
    8. Chen, Wei-Hsin & Tu, Yi-Jian & Sheen, Herng-Kuang, 2011. "Disruption of sugarcane bagasse lignocellulosic structure by means of dilute sulfuric acid pretreatment with microwave-assisted heating," Applied Energy, Elsevier, vol. 88(8), pages 2726-2734, August.
    9. Rattanapan, Anuchit & Limtong, Savitree & Phisalaphong, Muenduen, 2011. "Ethanol production by repeated batch and continuous fermentations of blackstrap molasses using immobilized yeast cells on thin-shell silk cocoons," Applied Energy, Elsevier, vol. 88(12), pages 4400-4404.
    10. Moretti, Marcia Maria de Souza & Bocchini-Martins, Daniela Alonso & Nunes, Christiane da Costa Carreira & Villena, Maria Arévalo & Perrone, Olavo Micali & Silva, Roberto da & Boscolo, Maurício & Gomes, 2014. "Pretreatment of sugarcane bagasse with microwaves irradiation and its effects on the structure and on enzymatic hydrolysis," Applied Energy, Elsevier, vol. 122(C), pages 189-195.
    11. Dwidar, Mohammed & Lee, Siseon & Mitchell, Robert J., 2012. "The production of biofuels from carbonated beverages," Applied Energy, Elsevier, vol. 100(C), pages 47-51.
    12. Karagoz, Pınar & Bill, Roslyn M. & Ozkan, Melek, 2019. "Lignocellulosic ethanol production: Evaluation of new approaches, cell immobilization and reactor configurations," Renewable Energy, Elsevier, vol. 143(C), pages 741-752.
    13. Kyriakou, Maria & Chatziiona, Vasiliki K. & Costa, Costas N. & Kallis, Michalis & Koutsokeras, Loukas & Constantinides, Georgios & Koutinas, Michalis, 2019. "Biowaste-based biochar: A new strategy for fermentative bioethanol overproduction via whole-cell immobilization," Applied Energy, Elsevier, vol. 242(C), pages 480-491.
    14. Tian, Shen & Zhu, Junyong & Yang, Xiushan, 2011. "Evaluation of an adapted inhibitor-tolerant yeast strain for ethanol production from combined hydrolysate of softwood," Applied Energy, Elsevier, vol. 88(5), pages 1792-1796, May.
    15. Sun, Shao-Long & Wen, Jia-Long & Ma, Ming-Guo & Sun, Run-Cang, 2014. "Enhanced enzymatic digestibility of bamboo by a combined system of multiple steam explosion and alkaline treatments," Applied Energy, Elsevier, vol. 136(C), pages 519-526.
    16. Aboagye, D. & Banadda, N. & Kiggundu, N. & Kabenge, I., 2017. "Assessment of orange peel waste availability in ghana and potential bio-oil yield using fast pyrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 814-821.
    17. Bharathiraja, B. & Jayamuthunagai, J. & Sudharsanaa, T. & Bharghavi, A. & Praveenkumar, R. & Chakravarthy, M. & Yuvaraj, D., 2017. "Biobutanol – An impending biofuel for future: A review on upstream and downstream processing tecniques," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P1), pages 788-807.
    18. Fernand, Francois & Israel, Alvaro & Skjermo, Jorunn & Wichard, Thomas & Timmermans, Klaas R. & Golberg, Alexander, 2017. "Offshore macroalgae biomass for bioenergy production: Environmental aspects, technological achievements and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 75(C), pages 35-45.
    19. Sánchez, S. & Lozano, L.J. & Godínez, C. & Juan, D. & Pérez, A. & Hernández, F.J., 2010. "Carob pod as a feedstock for the production of bioethanol in Mediterranean areas," Applied Energy, Elsevier, vol. 87(11), pages 3417-3424, November.
    20. Mesa, Leyanis & López, Nancy & Cara, Cristóbal & Castro, Eulogio & González, Erenio & Mussatto, Solange I., 2016. "Techno-economic evaluation of strategies based on two steps organosolv pretreatment and enzymatic hydrolysis of sugarcane bagasse for ethanol production," Renewable Energy, Elsevier, vol. 86(C), pages 270-279.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:88:y:2011:i:1:p:316-322. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.