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Energy and resource utilization of deinking sludge pyrolysis

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  • Lou, Rui
  • Wu, Shubin
  • Lv, Gaojin
  • Yang, Qing

Abstract

The thermochemical conversion technique was applied in deinking sludge from the pulp and papermaking industrial to indagate the utilization of sludge biomass to energy, and the pyrolysis characteristics and pyrolytic products of deinking sludge were studied with thermogravimetric analysis (TGA) and pyrolysis coupled with gas chromatograph–mass spectrometer (Py-GC/MS). The static tubular furnace as an applied industrial research was used to study deinking sludge pyrolysis. The solid, gas and liquid of products was characterized by electron probe microanalysis (EPMA), gas chromatograph (GC) and gas chromatograph–mass (GC/MS), respectively. The results revealed that the weight-loss process of deinking sludge was a non-isothermal reaction and composed of four stages, i.e. dewater stage, volatile releasing stage, carbon burnout stage and some calcium carbonate decomposition. Pyrolytic products from deinking sludge in the static tubular furnace were comprised of the gaseous (29.78%), condensed liquid (bio-oil, 24.41%) and solid residues (45.81%). The volatiles from deinking sludge pyrolyzing were almost aromatic hydrocarbons, i.e. styrene, toluene and benzene and few acids and the solid was calcium carbonate (CaCO3) that can be reused as paper filler. Deinking sludge was converted into high-grade fuel and chemicals by means of thermochemical conversion techniques, hence, pyrolysis of paper deinking sludge had a promising development on the comprehensive utilization.

Suggested Citation

  • Lou, Rui & Wu, Shubin & Lv, Gaojin & Yang, Qing, 2012. "Energy and resource utilization of deinking sludge pyrolysis," Applied Energy, Elsevier, vol. 90(1), pages 46-50.
    • Handle: RePEc:eee:appene:v:90:y:2012:i:1:p:46-50
    DOI: 10.1016/j.apenergy.2010.12.025
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    1. Xiao, Han-min & Ma, Xiao-qian & Lai, Zhi-yi, 2009. "Isoconversional kinetic analysis of co-combustion of sewage sludge with straw and coal," Applied Energy, Elsevier, vol. 86(9), pages 1741-1745, September.
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    4. Chen, Hui & Chen, Dezhen & Hong, Liu, 2015. "Influences of activation agent impregnated sewage sludge pyrolysis on emission characteristics of volatile combustion and De-NOx performance of activated char," Applied Energy, Elsevier, vol. 156(C), pages 767-775.
    5. Ning-Yi Wang & Chun-Hao Shih & Pei-Te Chiueh & Yu-Fong Huang, 2013. "Environmental Effects of Sewage Sludge Carbonization and Other Treatment Alternatives," Energies, MDPI, vol. 6(2), pages 1-13, February.
    6. Wang, Shule & Wen, Yuming & Hammarström, Henry & Jönsson, Pär Göran & Yang, Weihong, 2021. "Pyrolysis behaviour, kinetics and thermodynamic data of hydrothermal carbonization–Treated pulp and paper mill sludge," Renewable Energy, Elsevier, vol. 177(C), pages 1282-1292.
    7. Faubert, Patrick & Barnabé, Simon & Bouchard, Sylvie & Côté, Richard & Villeneuve, Claude, 2016. "Pulp and paper mill sludge management practices: What are the challenges to assess the impacts on greenhouse gas emissions?," Resources, Conservation & Recycling, Elsevier, vol. 108(C), pages 107-133.
    8. Cordiner, S. & De Simone, G. & Mulone, V., 2012. "Experimental–numerical design of a biomass bubbling fluidized bed gasifier for paper sludge energy recovery," Applied Energy, Elsevier, vol. 97(C), pages 532-542.

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