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Efficient base-catalyzed decomposition and in situ hydrogenolysis process for lignin depolymerization and char elimination

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  • Long, Jinxing
  • Xu, Ying
  • Wang, Tiejun
  • Yuan, Zhengqiu
  • Shu, Riyang
  • Zhang, Qi
  • Ma, Longlong

Abstract

Serious char formation caused by the repolymerization of unsaturated decomposition products is a considerable challenge for current lignin utilization. Here, a novel and efficient base-catalyzed depolymerization and in situ hydrogenolysis process for lignin decomposition and char elimination was proposed using the synergic catalyst of NaOH coordinated with Ru/C. In which, lignin was first depolymerized to phenolic monomer and its oligomer, and then the oligomer was further converted to more stable aliphatic alcohols simultaneously. The results showed that more than 92.5% of lignin was converted, giving 12.69% phenolic monomer, 6.12% aliphatic alcohol and less than 14.03% residual solid. This residual solid selectivity was far lower than it from the single catalyst condition. Furthermore, the products were analyzed using GC–MS, GPC, HPLC–MS and 1H NMR. The synergistic effect between depolymerization and hydrogenolysis was also investigated through comparative analysis of the feedstock, products, and the recovered lignin.

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  • Long, Jinxing & Xu, Ying & Wang, Tiejun & Yuan, Zhengqiu & Shu, Riyang & Zhang, Qi & Ma, Longlong, 2015. "Efficient base-catalyzed decomposition and in situ hydrogenolysis process for lignin depolymerization and char elimination," Applied Energy, Elsevier, vol. 141(C), pages 70-79.
    • Handle: RePEc:eee:appene:v:141:y:2015:i:c:p:70-79
    DOI: 10.1016/j.apenergy.2014.12.025
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    1. Zhang, Xinghua & Wang, Tiejun & Ma, Longlong & Zhang, Qi & Huang, Xiaoming & Yu, Yuxiao, 2013. "Production of cyclohexane from lignin degradation compounds over Ni/ZrO2–SiO2 catalysts," Applied Energy, Elsevier, vol. 112(C), pages 533-538.
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    3. Guo, Da-liang & Wu, Shu-bin & Liu, Bei & Yin, Xiu-li & Yang, Qing, 2012. "Catalytic effects of NaOH and Na2CO3 additives on alkali lignin pyrolysis and gasification," Applied Energy, Elsevier, vol. 95(C), pages 22-30.
    4. Lou, Rui & Wu, Shu-bin, 2011. "Products properties from fast pyrolysis of enzymatic/mild acidolysis lignin," Applied Energy, Elsevier, vol. 88(1), pages 316-322, January.
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    4. Patil, Vivek & Adhikari, Sushil & Cross, Phillip & Jahromi, Hossein, 2020. "Progress in the solvent depolymerization of lignin," Renewable and Sustainable Energy Reviews, Elsevier, vol. 133(C).
    5. Li, Haowei & Ma, Hongwei & Zhao, Weijie & Li, Xuehui & Long, Jinxing, 2019. "Upgrading lignin bio-oil for oxygen-containing fuel production using Ni/MgO: Effect of the catalyst calcination temperature," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    6. Garlapati, Vijay Kumar & Chandel, Anuj K. & Kumar, S.P. Jeevan & Sharma, Swati & Sevda, Surajbhan & Ingle, Avinash P. & Pant, Deepak, 2020. "Circular economy aspects of lignin: Towards a lignocellulose biorefinery," Renewable and Sustainable Energy Reviews, Elsevier, vol. 130(C).
    7. Biswas, Bijoy & Kumar, Avnish & Krishna, Bhavya B. & Bhaskar, Thallada, 2021. "Effects of solid base catalysts on depolymerization of alkali lignin for the production of phenolic monomer compounds," Renewable Energy, Elsevier, vol. 175(C), pages 270-280.
    8. Yiwen Yang & Cheng Zhang & Z. Conrad Zhang, 2018. "Advances in catalytic transformations of carbohydrates and lignin in ionic liquids and mechanistic studies," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 7(3), May.
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    10. Zhao, Weijie & Li, Yingwen & Song, Changhua & Liu, Sijie & Li, Xuehui & Long, Jinxing, 2017. "Intensified levulinic acid/ester production from cassava by one-pot cascade prehydrolysis and delignification," Applied Energy, Elsevier, vol. 204(C), pages 1094-1100.

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