IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v365y2024ics0306261924006676.html
   My bibliography  Save this article

Interfacial structuring of MnN and MnC bonds by defect engineering for high-performance Zn-Mn battery

Author

Listed:
  • Gong, Shengen
  • Zhao, Jiaxin
  • Sun, Kaisheng
  • Jia, Xiaoteng
  • Chao, Danming

Abstract

Zinc‑manganese batteries (ZMBs), with their non-flammable aqueous electrolyte and lower electrode material costs, offer a safer and more economical solution to the problem of energy intermittency. However, current ZMBs still face significant challenges, such as the presence of low electrical conductivity and poor structural stability of the manganese-based cathode, as well as unclear mechanisms of structural changes during charge storage. Here, we present a strategy to construct MnO2 containing MnC and MnN bonds (PAMO) by defect engineering and interface bonding design. This strategy benefits from the fact that MnN and MnC bonds can stabilize the structure and promote the interfacial dynamics of MnO2, thus effectively mitigating manganese dissolution. Meanwhile, the oxygen defects generated by interfacial bonding increase the electrical conductivity of MnO2. In addition, in terms of morphology and structure, the leafy vein-like secondary compartmentalized structure formed by PAMO provides more reactive sites for the redox reaction of MnO2, accelerating charge transfer and ion diffusion. The experimental results show that compared with pure MnO2 (326.8 mAh g−1), the capacity of PAMO material is enhanced by 30.1% (426.6 mAh g−1), and the battery still has 85.4% residual capacity (144.2–123.1 mAh g−1) after 6000 cycles, and coulombic efficiency is always maintained above 99.5%. This heterostructure design strategy of C- and N-doped MnO2 provides high electronic conductivity while playing an important role in improving structural stability.

Suggested Citation

  • Gong, Shengen & Zhao, Jiaxin & Sun, Kaisheng & Jia, Xiaoteng & Chao, Danming, 2024. "Interfacial structuring of MnN and MnC bonds by defect engineering for high-performance Zn-Mn battery," Applied Energy, Elsevier, vol. 365(C).
  • Handle: RePEc:eee:appene:v:365:y:2024:i:c:s0306261924006676
    DOI: 10.1016/j.apenergy.2024.123284
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261924006676
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.apenergy.2024.123284?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Yijing Wang & Rong Wang & Katsumasa Tanaka & Philippe Ciais & Josep Penuelas & Yves Balkanski & Jordi Sardans & Didier Hauglustaine & Wang Liu & Xiaofan Xing & Jiarong Li & Siqing Xu & Yuankang Xiong , 2023. "Accelerating the energy transition towards photovoltaic and wind in China," Nature, Nature, vol. 619(7971), pages 761-767, July.
    2. Jianhang Huang & Zhuo Wang & Mengyan Hou & Xiaoli Dong & Yao Liu & Yonggang Wang & Yongyao Xia, 2018. "Polyaniline-intercalated manganese dioxide nanolayers as a high-performance cathode material for an aqueous zinc-ion battery," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Jin & Zhao, Zhipeng & Zhou, Jinglin & Cheng, Chuntian & Su, Huaying, 2024. "Co-optimization for day-ahead scheduling and flexibility response mode of a hydro–wind–solar hybrid system considering forecast uncertainty of variable renewable energy," Energy, Elsevier, vol. 311(C).
    2. Pedro Gomes da Cruz Filho & Danielle Devequi Gomes Nunes & Hayna Malta Santos & Alex Álisson Bandeira Santos & Bruna Aparecida Souza Machado, 2023. "From Patents to Progress: Genetic Algorithms in Harmonic Distortion Monitoring Technology," Energies, MDPI, vol. 16(24), pages 1-21, December.
    3. Tao, Kejun & Zhao, Jinghao & Tao, Ye & Qi, Qingqing & Tian, Yajun, 2024. "Operational day-ahead photovoltaic power forecasting based on transformer variant," Applied Energy, Elsevier, vol. 373(C).
    4. Runlin Wang & Haozhe Zhang & Qiyu Liu & Fu Liu & Xile Han & Xiaoqing Liu & Kaiwei Li & Gaozhi Xiao & Jacques Albert & Xihong Lu & Tuan Guo, 2022. "Operando monitoring of ion activities in aqueous batteries with plasmonic fiber-optic sensors," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    5. Yao, En-jian & Zhang, Tian-yu & Wang, David Z.W. & Zhang, Jun-yi, 2024. "Dynamic planning and decarbonization pathways of the highway power supply network," Applied Energy, Elsevier, vol. 376(PB).
    6. Yifei Deng & Yijing Wang & Xiaofan Xing & Yuankang Xiong & Siqing Xu & Rong Wang, 2024. "Requirement on the Capacity of Energy Storage to Meet the 2 °C Goal," Sustainability, MDPI, vol. 16(9), pages 1-17, April.
    7. Yang, Mao & Han, Chao & Zhang, Wei & Wang, Bo, 2024. "A short-term power prediction method for wind farm cluster based on the fusion of multi-source spatiotemporal feature information," Energy, Elsevier, vol. 294(C).
    8. Zhang, Lei & Jiang, Peng & Zhang, Yibo & Fan, Yee Van & Geng, Yong, 2024. "Recycling impacts of renewable energy generation-related rare earth resources: A SWOT-based strategical analysis," Energy, Elsevier, vol. 312(C).
    9. Hou, Yaru & Yang, Mian & Ma, Yanran & Zhang, Haiying, 2024. "Study on city's energy transition: Evidence from the establishment of the new energy demonstration cities in China," Energy, Elsevier, vol. 292(C).
    10. Li, Jiacong & Zhang, Chongyu & Davidson, Michael R. & Lu, Xi, 2025. "Assessing the synergies of flexibly-operated carbon capture power plants with variable renewable energy in large-scale power systems," Applied Energy, Elsevier, vol. 377(PB).
    11. Haozhi Zhang & Haibing Wang, 2025. "Research on Energy Storage Planning and Operation for New Energy in the Substitute Power Product Market," Sustainability, MDPI, vol. 17(5), pages 1-23, February.
    12. Zhang, Bingqian & Yan, Kun & Lyu, Yizheng & Qian, Yisen & Gao, Hanbo & Tian, Jinping & Zheng, Wei & Chen, Lyujun, 2024. "A “water and carbon” near-zero emission WWTP system: Model development and techno-economic-environmental benefits assessment," Applied Energy, Elsevier, vol. 371(C).
    13. Deroubaix, Paul & Kobashi, Takuro & Gurriaran, Léna & Benkhelifa, Fouzi & Ciais, Philippe & Tanaka, Katsumasa, 2023. "SolarEV City Concept for Paris," Applied Energy, Elsevier, vol. 350(C).
    14. Zhang, Jie & Xiao, Bo & Niu, Geng & Xie, Xuanzhi & Wu, Saixiang, 2024. "Joint estimation of state-of-charge and state-of-power for hybrid supercapacitors using fractional-order adaptive unscented Kalman filter," Energy, Elsevier, vol. 294(C).
    15. Li, Ruohan & Wang, Dongdong & Wang, Zhihao & Liang, Shunlin & Li, Zhanqing & Xie, Yiqun & He, Jiena, 2025. "Transformer approach to nowcasting solar energy using geostationary satellite data," Applied Energy, Elsevier, vol. 377(PA).
    16. Minde An & Ronald G. Prinn & Luke M. Western & Xingchen Zhao & Bo Yao & Jianxin Hu & Anita L. Ganesan & Jens Mühle & Ray F. Weiss & Paul B. Krummel & Simon O’Doherty & Dickon Young & Matthew Rigby, 2024. "Sustained growth of sulfur hexafluoride emissions in China inferred from atmospheric observations," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    17. Quanquan Guo & Wei Li & Xiaodong Li & Jiaxu Zhang & Davood Sabaghi & Jianjun Zhang & Bowen Zhang & Dongqi Li & Jingwei Du & Xingyuan Chu & Sein Chung & Kilwon Cho & Nguyen Ngan Nguyen & Zhongquan Liao, 2024. "Proton-selective coating enables fast-kinetics high-mass-loading cathodes for sustainable zinc batteries," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    18. Jiayu Bao & Xianglong Li & Tao Yu & Liangliang Jiang & Jialin Zhang & Fengjiao Song & Wenqiang Xu, 2024. "Are Regions Conducive to Photovoltaic Power Generation Demonstrating Significant Potential for Harnessing Solar Energy via Photovoltaic Systems?," Sustainability, MDPI, vol. 16(8), pages 1-19, April.
    19. Kang, Hyuna & Kim, Hakpyeong & Hong, Juwon & Zhang, Ruixiaoxiao & Lee, Minhyun & Hong, Taehoon, 2024. "Harnessing sunlight beyond earth: Sustainable vision of space-based solar power systems in smart grid," Renewable and Sustainable Energy Reviews, Elsevier, vol. 202(C).
    20. Wang, Lunche & Lu, Yunbo & Wang, Zhitong & Li, Huaping & Zhang, Ming, 2024. "Hourly solar radiation estimation and uncertainty quantification using hybrid models," Renewable and Sustainable Energy Reviews, Elsevier, vol. 202(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:365:y:2024:i:c:s0306261924006676. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.