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Operando monitoring of ion activities in aqueous batteries with plasmonic fiber-optic sensors

Author

Listed:
  • Runlin Wang

    (Jinan University)

  • Haozhe Zhang

    (School of Chemistry, Sun Yat-Sen University)

  • Qiyu Liu

    (School of Chemistry, Sun Yat-Sen University)

  • Fu Liu

    (Carleton University)

  • Xile Han

    (Jinan University)

  • Xiaoqing Liu

    (School of Chemistry, Sun Yat-Sen University)

  • Kaiwei Li

    (Jinan University)

  • Gaozhi Xiao

    (National Research Council of Canada)

  • Jacques Albert

    (Carleton University)

  • Xihong Lu

    (School of Chemistry, Sun Yat-Sen University)

  • Tuan Guo

    (Jinan University
    Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai))

Abstract

Understanding ion transport kinetics and electrolyte-electrode interactions at electrode surfaces of batteries in operation is essential to determine their performance and state of health. However, it remains a challenging task to capture in real time the details of surface-localized and rapid ion transport at the microscale. To address this, a promising approach based on an optical fiber plasmonic sensor capable of being inserted near the electrode surface of a working battery to monitor its electrochemical kinetics without disturbing its operation is demonstrated using aqueous Zn-ion batteries as an example. The miniature and chemically inert sensor detects perturbations of surface plasmon waves propagating on its surface to rapidly screen localized electrochemical events on a sub-μm-scale thickness adjacent to the electrode interface. A stable and reproducible correlation between the real-time ion insertions over charge-discharge cycles and the optical plasmon response has been observed and quantified. This new operando measurement tool will provide crucial additional capabilities to battery monitoring methods and help guide the design of better batteries with improved electro-chemistries.

Suggested Citation

  • Runlin Wang & Haozhe Zhang & Qiyu Liu & Fu Liu & Xile Han & Xiaoqing Liu & Kaiwei Li & Gaozhi Xiao & Jacques Albert & Xihong Lu & Tuan Guo, 2022. "Operando monitoring of ion activities in aqueous batteries with plasmonic fiber-optic sensors," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-28267-y
    DOI: 10.1038/s41467-022-28267-y
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    References listed on IDEAS

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    1. Jianhang Huang & Zhuo Wang & Mengyan Hou & Xiaoli Dong & Yao Liu & Yonggang Wang & Yongyao Xia, 2018. "Polyaniline-intercalated manganese dioxide nanolayers as a high-performance cathode material for an aqueous zinc-ion battery," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    2. M. Armand & J.-M. Tarascon, 2008. "Building better batteries," Nature, Nature, vol. 451(7179), pages 652-657, February.
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    Cited by:

    1. Fu Liu & Wenqing Lu & Jiaqiang Huang & Vanessa Pimenta & Steven Boles & Rezan Demir-Cakan & Jean-Marie Tarascon, 2023. "Detangling electrolyte chemical dynamics in lithium sulfur batteries by operando monitoring with optical resonance combs," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    2. Wenxin Mei & Zhi Liu & Chengdong Wang & Chuang Wu & Yubin Liu & Pengjie Liu & Xudong Xia & Xiaobin Xue & Xile Han & Jinhua Sun & Gaozhi Xiao & Hwa-yaw Tam & Jacques Albert & Qingsong Wang & Tuan Guo, 2023. "Operando monitoring of thermal runaway in commercial lithium-ion cells via advanced lab-on-fiber technologies," Nature Communications, Nature, vol. 14(1), pages 1-12, December.

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