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CFD and kinetic modelling study of methane MILD combustion in O2/N2, O2/CO2 and O2/H2O atmospheres

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  • Tu, Yaojie
  • Xu, Mingchen
  • Zhou, Dezhi
  • Wang, Qingxiang
  • Yang, Wenming
  • Liu, Hao

Abstract

To deepen the understanding of combining moderate or intense low-oxygen dilution (MILD) combustion with oxy-fuel combustion for enhancing flame stability while realizing carbon capturing and storage, this paper presents a numerical study of methane MILD combustion in three atmospheres, i.e.: O2/N2, O2/CO2 and O2/H2O, with both computational fluid dynamics (CFD) and kinetic calculation approaches. Firstly, CFD predictions for the three conditions were performed following a systematic validation of the numerical method against experimental measurement from methane/air MILD combustion in a laboratory-scale closed furnace. Subsequently, kinetic calculations with a well-stirred reactor model was used to quantitatively identify the operating ranges of MILD combustion in the three atmospheres for methane. Moreover, the kinetic calculation provided additional insight into the fuel oxidation pathway. The results reveal that replacing N2 with either CO2 or H2O would help to establish MILD combustion mode from the viewpoint of lower temperature increase, due to both physical and chemical property discrepancies among the diluents. Specifically, the chemical effect and physical effect are responsible to the lower temperature rise for CO2-diluted case and H2O-diluted case, respectively. Inside the MILD combustion furnace, the negative heat release region disappears in regardless of atmospheres, indicating the eliminated fuel pyrolysis process under MILD combustion mode. Detailed analysis of the flame structure suggests that the combustion regimes inside the furnace in the three atmospheres are all in well-stirred combustion regime, and CO2-diluted case has the most extended reaction zone. Kinetic calculation indicates that CO2 or H2O dilution would result in a wider MILD combustion operating range compared to N2 dilution, while it is more pronounced for CO2. These observations all imply that MILD combustion will be more easily established with CO2 dilution than N2 or H2O dilution. However, higher CO formation is obtained in O2/CO2, forcing more attention to be paid on CO emission under CO2-diluted MILD combustion. Furthermore, the hydrocarbon recombination route is negligible under MILD combustion in spite of the atmospheres, implying lower sooting tendency as compared with conventional combustion.

Suggested Citation

  • Tu, Yaojie & Xu, Mingchen & Zhou, Dezhi & Wang, Qingxiang & Yang, Wenming & Liu, Hao, 2019. "CFD and kinetic modelling study of methane MILD combustion in O2/N2, O2/CO2 and O2/H2O atmospheres," Applied Energy, Elsevier, vol. 240(C), pages 1003-1013.
  • Handle: RePEc:eee:appene:v:240:y:2019:i:c:p:1003-1013
    DOI: 10.1016/j.apenergy.2019.02.046
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    1. Khalil, Ahmed E.E. & Gupta, Ashwani K., 2017. "The role of CO2 on oxy-colorless distributed combustion," Applied Energy, Elsevier, vol. 188(C), pages 466-474.
    2. Chen, Sheng & Liu, Hao & Zheng, Chuguang, 2017. "Methane combustion in MILD oxyfuel regime: Influences of dilution atmosphere in co-flow configuration," Energy, Elsevier, vol. 121(C), pages 159-175.
    3. He, Yizhuo & Zou, Chun & Song, Yu & Luo, Jianghui & Jia, Huiqiao & Chen, Wuzhong & Zheng, Junmei & Zheng, Chuguang, 2017. "Comparison of the characteristics and mechanism of CO formation in O2/N2, O2/CO2 and O2/H2O atmospheres," Energy, Elsevier, vol. 141(C), pages 1429-1438.
    4. Arghode, Vaibhav K. & Gupta, Ashwani K. & Bryden, Kenneth M., 2012. "High intensity colorless distributed combustion for ultra low emissions and enhanced performance," Applied Energy, Elsevier, vol. 92(C), pages 822-830.
    5. Yin, Chungen & Yan, Jinyue, 2016. "Oxy-fuel combustion of pulverized fuels: Combustion fundamentals and modeling," Applied Energy, Elsevier, vol. 162(C), pages 742-762.
    6. Cheong, Kin-Pang & Li, Pengfei & Wang, Feifei & Mi, Jianchun, 2017. "Emissions of NO and CO from counterflow combustion of CH4 under MILD and oxyfuel conditions," Energy, Elsevier, vol. 124(C), pages 652-664.
    7. Ramadan, Islam A. & Ibrahim, Abdelmaged H. & Abou-Arab, Tharwat W. & Rashwan, Sherif S. & Nemitallah, Medhat A. & Habib, Mohamed A., 2016. "Effects of oxidizer flexibility and bluff-body blockage ratio on flammability limits of diffusion flames," Applied Energy, Elsevier, vol. 178(C), pages 19-28.
    8. Abdelhafez, Ahmed & Rashwan, Sherif S. & Nemitallah, Medhat A. & Habib, Mohamed A., 2018. "Stability map and shape of premixed CH4/O2/CO2 flames in a model gas-turbine combustor," Applied Energy, Elsevier, vol. 215(C), pages 63-74.
    9. Liu, Hao & Shao, Yingjuan, 2010. "Predictions of the impurities in the CO2 stream of an oxy-coal combustion plant," Applied Energy, Elsevier, vol. 87(10), pages 3162-3170, October.
    10. Khalil, Ahmed E.E. & Gupta, Ashwani K., 2017. "Flame fluctuations in Oxy-CO2-methane mixtures in swirl assisted distributed combustion," Applied Energy, Elsevier, vol. 204(C), pages 303-317.
    11. Hu, Xianzhong & Yu, Qingbo & Liu, Junxiang & Sun, Nan, 2014. "Investigation of laminar flame speeds of CH4/O2/CO2 mixtures at ordinary pressure and kinetic simulation," Energy, Elsevier, vol. 70(C), pages 626-634.
    12. Wang, Feifei & Li, Pengfei & Mei, Zhenfeng & Zhang, Jianpeng & Mi, Jianchun, 2014. "Combustion of CH4/O2/N2 in a well stirred reactor," Energy, Elsevier, vol. 72(C), pages 242-253.
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    2. Fordoei, Esmaeil Ebrahimi & Boyaghchi, Fateme Ahmadi, 2022. "Influence of wall thermal conditions on the ignition, flame structure, and temperature behaviors in air-fuel, oxygen-enhanced, and oxy-fuel combustion under the MILD and high-temperature regimes," Energy, Elsevier, vol. 255(C).
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    7. Shaker, Ahmad & Fordoei, E. Ebrahimi & Boyaghchi, Fateme Ahmadi, 2023. "Study of NO emission from CH4-air, oxygen-enriched, and oxy-CH4 combustion under HTC and MILD regimes: Impact of wall thermal condition in different oxidant temperature and dilution level," Energy, Elsevier, vol. 277(C).
    8. Sayadzadeh, Mohammad Esmaiel & Samani, Majid Riahi & Toghraie, Davood & Emami, Sobhan & Eftekhari, Seyed Ali, 2023. "Numerical study on pollutant emissions characteristics and chemical and physical exergy analysis in Mild combustion," Energy, Elsevier, vol. 278(PB).
    9. Fordoei, E. Ebrahimi & Mazaheri, Kiumars & Mohammadpour, Amirreza, 2021. "Numerical study on the heat transfer characteristics, flame structure, and pollutants emission in the MILD methane-air, oxygen-enriched and oxy-methane combustion," Energy, Elsevier, vol. 218(C).
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