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Challenges and opportunities in microwave-assisted catalytic pyrolysis of biomass: A review

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  • Ren, Xueyong
  • Shanb Ghazani, Mohammad
  • Zhu, Hui
  • Ao, Wenya
  • Zhang, Han
  • Moreside, Emma
  • Zhu, Jinjiao
  • Yang, Pu
  • Zhong, Na
  • Bi, Xiaotao

Abstract

Microwave-assisted catalytic pyrolysis (MACP) is one of the emerging technologies for efficiently converting the solid biomass residues to valuable products, including liquid bio-oil and solid biochar. However, due to the poor dielectric properties, low thermal-conductivity, and complex compositions of biomass feedstock, two major technical challenges of biomass MACP technologies are how to heat biomass efficiently by microwave, and how to tune the pyrolysis process to improve the quality of products by catalysis. In the literature, direct, indirect as well as hybrid (localized and segregated) heating modes have been explored to improve the heating performance of microwave reactors, and in-situ, ex-situ and hybrid (dual, layered and series) catalyst configurations have been applied using different microwave absorbents and catalysts. In this review, those heating and catalysis strategies are systematically and critically reviewed (data from about 80 lab-scale studies and 1 pilot-scale unit) to reveal their differences in terms of heating efficiency and product qualities. For some biomass feedstock with high dielectric properties or under high electromagnetic field, direct heating without the use of microwave absorbent could be used. Indirect heating, on the other hand, can be used for all feedstock in which heat is transferred to the biomass via conduction/convection from high temperature surfaces heated by microwave. Hybrid heating with the use of microwave absorbents can greatly increase the local heating rate, promote the pyrolysis reaction rate and tune the distribution of pyrolytic products. In-situ catalysis shows the capability to tune the quantity and quality of both bio-oil and biochar by promoting direct interaction of catalyst and biomass via the pyrolysis vapour, while ex-situ catalysis exhibits a better potential to adjust the bio-oil yield and selectivity of desired compounds in bio-oil, and extends the catalyst life by avoiding the direct contact between biochar and catalyst. Hybrid catalytic mode combines in-situ and ex-situ catalysis in a more complex setup, but shows a great potential to regulate the yield, composition and properties of multiple products. Techno-economic-environmental assessments were also reported on the benefits of MACP processes with different heating and catalytic strategies, mostly based on the lab and limited pilot scale performance data. Future research and development should be focused on the evaluation of different absorbent-catalyst integration, heating-catalysis synergistic effect, optimization of products yields and properties, and how to scale up the MACP reactor technologies toward commercialization with continuous biomass feeding.

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  • Ren, Xueyong & Shanb Ghazani, Mohammad & Zhu, Hui & Ao, Wenya & Zhang, Han & Moreside, Emma & Zhu, Jinjiao & Yang, Pu & Zhong, Na & Bi, Xiaotao, 2022. "Challenges and opportunities in microwave-assisted catalytic pyrolysis of biomass: A review," Applied Energy, Elsevier, vol. 315(C).
    • Handle: RePEc:eee:appene:v:315:y:2022:i:c:s0306261922003828
    DOI: 10.1016/j.apenergy.2022.118970
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    as
    1. Bhattacharya, Madhuchhanda & Basak, Tanmay, 2016. "A review on the susceptor assisted microwave processing of materials," Energy, Elsevier, vol. 97(C), pages 306-338.
    2. Chen, Wei-Hsin & Peng, Jianghong & Bi, Xiaotao T., 2015. "A state-of-the-art review of biomass torrefaction, densification and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 847-866.
    3. Muley, P.D. & Henkel, C.E. & Aguilar, G. & Klasson, K.T. & Boldor, D., 2016. "Ex situ thermo-catalytic upgrading of biomass pyrolysis vapors using a traveling wave microwave reactor," Applied Energy, Elsevier, vol. 183(C), pages 995-1004.
    4. Shen, Yafei, 2015. "Chars as carbonaceous adsorbents/catalysts for tar elimination during biomass pyrolysis or gasification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 281-295.
    5. Alhashimi, Hashim A. & Aktas, Can B., 2017. "Life cycle environmental and economic performance of biochar compared with activated carbon: A meta-analysis," Resources, Conservation & Recycling, Elsevier, vol. 118(C), pages 13-26.
    6. Motasemi, F. & Afzal, Muhammad T., 2013. "A review on the microwave-assisted pyrolysis technique," Renewable and Sustainable Energy Reviews, Elsevier, vol. 28(C), pages 317-330.
    7. Mushtaq, Faisal & Mat, Ramli & Ani, Farid Nasir, 2014. "A review on microwave assisted pyrolysis of coal and biomass for fuel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 39(C), pages 555-574.
    8. Ellison, Candice Raffaela & Hoff, Ryan & Mărculescu, Cosmin & Boldor, Dorin, 2020. "Investigation of microwave-assisted pyrolysis of biomass with char in a rectangular waveguide applicator with built-in phase-shifting," Applied Energy, Elsevier, vol. 259(C).
    9. Wei, Xiaocui & Xue, Xiangfei & Wu, Liu & Yu, Haozhe & Liang, Jie & Sun, Yifei, 2020. "High-grade bio-oil produced from coconut shell: A comparative study of microwave reactor and core-shell catalyst," Energy, Elsevier, vol. 212(C).
    10. Luo, Juan & Sun, Shichang & Chen, Xing & Lin, Junhao & Ma, Rui & Zhang, Rui & Fang, Lin, 2021. "In-depth exploration of the energy utilization and pyrolysis mechanism of advanced continuous microwave pyrolysis," Applied Energy, Elsevier, vol. 292(C).
    11. Huang, Yu-Fong & Kuan, Wen-Hui & Chang, Chun-Yuan, 2018. "Effects of particle size, pretreatment, and catalysis on microwave pyrolysis of corn stover," Energy, Elsevier, vol. 143(C), pages 696-703.
    12. Bridgwater, A. V. & Peacocke, G. V. C., 2000. "Fast pyrolysis processes for biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 4(1), pages 1-73, March.
    13. Galinato, Suzette P. & Yoder, Jonathan K. & Granatstein, David, 2011. "The economic value of biochar in crop production and carbon sequestration," Energy Policy, Elsevier, vol. 39(10), pages 6344-6350, October.
    14. Mutsengerere, S. & Chihobo, C.H. & Musademba, D. & Nhapi, I., 2019. "A review of operating parameters affecting bio-oil yield in microwave pyrolysis of lignocellulosic biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 104(C), pages 328-336.
    15. Guo, Mingxin & Song, Weiping & Buhain, Jeremy, 2015. "Bioenergy and biofuels: History, status, and perspective," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 712-725.
    16. Roy, Poritosh & Dias, Goretty, 2017. "Prospects for pyrolysis technologies in the bioenergy sector: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 59-69.
    17. Ge, Shengbo & Yek, Peter Nai Yuh & Cheng, Yoke Wang & Xia, Changlei & Wan Mahari, Wan Adibah & Liew, Rock Keey & Peng, Wanxi & Yuan, Tong-Qi & Tabatabaei, Meisam & Aghbashlo, Mortaza & Sonne, Christia, 2021. "Progress in microwave pyrolysis conversion of agricultural waste to value-added biofuels: A batch to continuous approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    18. Asomaning, Justice & Haupt, Susan & Chae, Michael & Bressler, David C., 2018. "Recent developments in microwave-assisted thermal conversion of biomass for fuels and chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 92(C), pages 642-657.
    19. Mohd Mokhta, Zafri & Ong, Mei Yin & Salman, Bello & Nomanbhay, Saifuddin & Salleh, Siti Fatihah & Chew, Kit Wayne & Show, Pau-Loke & Chen, Wei-Hsin, 2020. "Simulation studies on microwave-assisted pyrolysis of biomass for bioenergy production with special attention on waveguide number and location," Energy, Elsevier, vol. 190(C).
    20. Ao, Wenya & Fu, Jie & Mao, Xiao & Kang, Qinhao & Ran, Chunmei & Liu, Yang & Zhang, Hedong & Gao, Zuopeng & Li, Jing & Liu, Guangqing & Dai, Jianjun, 2018. "Microwave assisted preparation of activated carbon from biomass: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 92(C), pages 958-979.
    21. Edward M. Rubin, 2008. "Genomics of cellulosic biofuels," Nature, Nature, vol. 454(7206), pages 841-845, August.
    22. Patel, Madhumita & Zhang, Xiaolei & Kumar, Amit, 2016. "Techno-economic and life cycle assessment on lignocellulosic biomass thermochemical conversion technologies: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1486-1499.
    23. Ong, Hwai Chyuan & Chen, Wei-Hsin & Farooq, Abid & Gan, Yong Yang & Lee, Keat Teong & Ashokkumar, Veeramuthu, 2019. "Catalytic thermochemical conversion of biomass for biofuel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    24. Yang, Zixu & Qian, Kezhen & Zhang, Xuesong & Lei, Hanwu & Xin, Chunhua & Zhang, Yayun & Qian, Moriko & Villota, Elmar, 2018. "Process design and economics for the conversion of lignocellulosic biomass into jet fuel range cycloalkanes," Energy, Elsevier, vol. 154(C), pages 289-297.
    25. Ma, Rui & Sun, Shichang & Geng, Haihong & Fang, Lin & Zhang, Peixin & Zhang, Xianghua, 2018. "Study on the characteristics of microwave pyrolysis of high-ash sludge, including the products, yields, and energy recovery efficiencies," Energy, Elsevier, vol. 144(C), pages 515-525.
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