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Thermo-chemical processes for the sustainable utilization of oil-bearing biomass: A case study on apricot seed valorization

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  • Choi, Dongho
  • Kim, Minyoung
  • Kim, Jee Young
  • Tsang, Yiu Fai
  • Jeong, Sanghyun
  • Kwon, Eilhann E.

Abstract

This study investigated the thermochemical processing of defatted residue to achieve zero-waste utilization of oil-bearing biomass using apricot seed as the model compound. Defatted apricot seeds (DAS) obtained after oil extraction from apricot seed were valorized through pyrolysis platform, focusing on enhancing sustainability using CO2 as the reaction medium. The results showed that CO2 plays a crucial role in the pyrolysis process, leading to an enhanced CO formation through homogeneous reaction between CO2 and volatile matters stemming from DAS. Specifically, CO2 oxidized volatile matters while simultaneously reducing to CO and influenced the morphological properties of DAS biochars (DASBs), leading the development of pores with sizes of less than 16 nm and exceeding 50 nm. The larger pore size of DASBs fabricated under N2 and CO2, compared to 2 nm (the molecular size of triglycerides), makes them suitable as porous materials for thermally induced transesterification. The presence of alkaline metals in DASBs expedited thermally induced transesterification. At ≤ 330 °C, DASB fabricated under CO2 condition exhibited faster reaction kinetics than under N2 condition. This suggests that the use of CO2 in the fabrication of DASB results in favorable surface properties conducive to the thermally induced transesterification of apricot oil.

Suggested Citation

  • Choi, Dongho & Kim, Minyoung & Kim, Jee Young & Tsang, Yiu Fai & Jeong, Sanghyun & Kwon, Eilhann E., 2024. "Thermo-chemical processes for the sustainable utilization of oil-bearing biomass: A case study on apricot seed valorization," Energy, Elsevier, vol. 302(C).
    • Handle: RePEc:eee:energy:v:302:y:2024:i:c:s0360544224016700
    DOI: 10.1016/j.energy.2024.131897
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    1. Shahbaz, Muhammad & Raghutla, Chandrashekar & Chittedi, Krishna Reddy & Jiao, Zhilun & Vo, Xuan Vinh, 2020. "The effect of renewable energy consumption on economic growth: Evidence from the renewable energy country attractive index," Energy, Elsevier, vol. 207(C).
    2. Lahijani, Pooya & Zainal, Zainal Alimuddin & Mohammadi, Maedeh & Mohamed, Abdul Rahman, 2015. "Conversion of the greenhouse gas CO2 to the fuel gas CO via the Boudouard reaction: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 615-632.
    3. Cheng, F. & Brewer, C.E., 2021. "Conversion of protein-rich lignocellulosic wastes to bio-energy: Review and recommendations for hydrolysis + fermentation and anaerobic digestion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 146(C).
    4. Lin, Kuang C. & Lin, Yuan-Chung & Hsiao, Yi-Hsing, 2014. "Microwave plasma studies of Spirulina algae pyrolysis with relevance to hydrogen production," Energy, Elsevier, vol. 64(C), pages 567-574.
    5. Ren, Xueyong & Shanb Ghazani, Mohammad & Zhu, Hui & Ao, Wenya & Zhang, Han & Moreside, Emma & Zhu, Jinjiao & Yang, Pu & Zhong, Na & Bi, Xiaotao, 2022. "Challenges and opportunities in microwave-assisted catalytic pyrolysis of biomass: A review," Applied Energy, Elsevier, vol. 315(C).
    6. Sharma, Abhishek & Pareek, Vishnu & Zhang, Dongke, 2015. "Biomass pyrolysis—A review of modelling, process parameters and catalytic studies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 1081-1096.
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