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Fluidized-bed and fixed-bed reactor testing of methane chemical looping combustion with MgO-promoted hematite

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  • Miller, Duane D.
  • Siriwardane, Ranjani
  • Poston, James

Abstract

In this study MgO-promoted Fe2O3 hematite oxygen carriers were synthesized from various Mg sources and evaluated for methane chemical looping combustion. Particles suitable for fluidized bed flow reactor studies were prepared in the lab. Cyclic CLC tests conducted in the fluidized bed with MgO promoted hematite showed better performance than that with hematite. Attrition resistance of laboratory prepared MgO promoted hematite was excellent. Reactivity and stability of the oxygen carrier materials were also tested in the thermogravimetric analyzer and bench-scale reactors. Scanning electron microscopy and energy-dispersive X-ray spectroscopy, and X-ray diffraction were used to study the morphology and elemental compositions present in the hematite and promoted hematite oxygen carriers prior to and following the multi-cycle chemical looping reaction. The incorporation of 5wt% MgO led to an increased reaction rate and an increase in oxygen utilized as compared to the pure hematite oxygen carrier. Possible reasons for the promotion effect by MgO were evaluated. These studies reveal that the best performing oxygen carrier was the 5wt% MgO/Fe2O3 which exhibited no observed degradation in the kinetics and conversion performance in the methane step over 15 reduction and oxidation cycles. The Mg promoted oxygen carrier also showed reduced coke formation as compared to the pure hematite carrier.

Suggested Citation

  • Miller, Duane D. & Siriwardane, Ranjani & Poston, James, 2015. "Fluidized-bed and fixed-bed reactor testing of methane chemical looping combustion with MgO-promoted hematite," Applied Energy, Elsevier, vol. 146(C), pages 111-121.
    • Handle: RePEc:eee:appene:v:146:y:2015:i:c:p:111-121
    DOI: 10.1016/j.apenergy.2015.02.047
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    References listed on IDEAS

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    2. Lin, Shen & Gu, Zhenhua & Zhu, Xing & Wei, Yonggang & Long, Yanhui & Yang, Kun & He, Fang & Wang, Hua & Li, Kongzhai, 2020. "Synergy of red mud oxygen carrier with MgO and NiO for enhanced chemical-looping combustion," Energy, Elsevier, vol. 197(C).
    3. Haider, S.K. & Azimi, G. & Duan, L. & Anthony, E.J. & Patchigolla, K. & Oakey, J.E. & Leion, H. & Mattisson, T. & Lyngfelt, A., 2016. "Enhancing properties of iron and manganese ores as oxygen carriers for chemical looping processes by dry impregnation," Applied Energy, Elsevier, vol. 163(C), pages 41-50.
    4. Di, Zichen & Yilmaz, Duygu & Biswas, Arijit & Cheng, Fangqin & Leion, Henrik, 2022. "Spinel ferrite-contained industrial materials as oxygen carriers in chemical looping combustion," Applied Energy, Elsevier, vol. 307(C).
    5. Siriwardane, Ranjani & Tian, Hanjing & Miller, Duane & Richards, George, 2015. "Fluidized bed testing of commercially prepared MgO-promoted hematite and CuO–Fe2O3 mixed metal oxide oxygen carriers for methane and coal chemical looping combustion," Applied Energy, Elsevier, vol. 157(C), pages 348-357.

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