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A particle-scale reduction model of copper iron manganese oxide with CO for chemical looping combustion

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  • Benincosa, William
  • Siriwardane, Ranjani
  • Tian, Hanjing
  • Riley, Jarrett
  • Poston, James

Abstract

Chemical looping combustion is a promising power generation technology that produces sequestration-ready CO2 and heat/power from the combustion of fossil fuels with oxygen provided by an oxygen carrier, or metal oxide, rather than air. Successful implementation of chemical looping combustion depends highly on the choice of oxygen carrier and the development of reaction rate parameters for process design and scale-up of the multi-reactor system. In this work, the reaction profile of a promising trimetallic oxygen carrier, copper iron manganese oxide with CO, a component of coal-derived synthesis gas was characterized using differential scanning calorimetry/thermogravimetric analysis and in-situ X-Ray diffraction. A unique phase formation with reactivities different from that with single metal components and phase changes during the reaction with CO were identified. Three major reactions were identified from the phase changes to use for reaction modelling. A particle-scale reaction model was selected which best described the experimental thermogravimetric analysis data to determine the valuable intrinsic reaction values for reactor design and scale-up. A particle-scale reaction model based on nucleation and growth and 1-D phase boundary behavior exhibited the most accurate correlation with the experimental data and provided intrinsic rate constants which were validated with the conventional mass transport analysis.

Suggested Citation

  • Benincosa, William & Siriwardane, Ranjani & Tian, Hanjing & Riley, Jarrett & Poston, James, 2020. "A particle-scale reduction model of copper iron manganese oxide with CO for chemical looping combustion," Applied Energy, Elsevier, vol. 262(C).
    • Handle: RePEc:eee:appene:v:262:y:2020:i:c:s030626191932094x
    DOI: 10.1016/j.apenergy.2019.114407
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    1. Siriwardane, Ranjani & Riley, Jarrett & Bayham, Samuel & Straub, Douglas & Tian, Hanjing & Weber, Justin & Richards, George, 2018. "50-kWth methane/air chemical looping combustion tests with commercially prepared CuO-Fe2O3-alumina oxygen carrier with two different techniques," Applied Energy, Elsevier, vol. 213(C), pages 92-99.
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    7. Riley, Jarrett & Siriwardane, Ranjani & Tian, Hanjing & Benincosa, William & Poston, James, 2018. "Experimental and kinetic analysis for particle scale modeling of a CuO-Fe2O3-Al2O3 oxygen carrier during reduction with H2 in chemical looping combustion applications," Applied Energy, Elsevier, vol. 228(C), pages 1515-1530.
    8. Samuel C. Bayham & Andrew Tong & Mandar Kathe & Liang-Shih Fan, 2016. "Chemical looping technology for energy and chemical production," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 5(2), pages 216-241, March.
    9. Benincosa, William & Siriwardane, Ranjani & Tian, Hanjing & Riley, Jarrett, 2017. "Unique phase identification of trimetallic copper iron manganese oxygen carrier using simultaneous differential scanning calorimetry/thermogravimetric analysis during chemical looping combustion react," Applied Energy, Elsevier, vol. 203(C), pages 522-534.
    10. Riley, Jarrett & Siriwardane, Ranjani & Tian, Hanjing & Benincosa, William & Poston, James, 2019. "Particle scale modeling of CuFeAlO4 during reduction with CO in chemical looping applications," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    11. Riley, Jarrett & Siriwardane, Ranjani & Tian, Hanjing & Benincosa, William & Poston, James, 2017. "Kinetic analysis of the interactions between calcium ferrite and coal char for chemical looping gasification applications: Identifying reduction routes and modes of oxygen transfer," Applied Energy, Elsevier, vol. 201(C), pages 94-110.
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    3. Siriwardane, Ranjani & Riley, Jarrett & Benincosa, William & Bayham, Samuel & Bobek, Michael & Straub, Douglas & Weber, Justin, 2021. "Development of CuFeMnAlO4+δ oxygen carrier with high attrition resistance and 50-kWth methane/air chemical looping combustion tests," Applied Energy, Elsevier, vol. 286(C).

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