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Increasing energy efficiency in chemical looping combustion of methane by in-situ activation of perovskite-based oxygen carriers

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  • Cabello, Arturo
  • Abad, Alberto
  • Gayán, Pilar
  • García-Labiano, Francisco
  • de Diego, Luis F.
  • Adánez, Juan

Abstract

CaMnO3-based perovskites are attractive for use as oxygen carriers in chemical looping combustion (CLC) because they are made from cheap materials (manganese, calcium). However, these materials show low reactivity with methane, and high oxygen carrier-to-fuel ratios (ϕ) are required to achieve complete fuel combustion. It is believed that energy efficiency in the chemical looping process would be improved if the reactivity of these materials were higher. In this work, the increase in reactivity of a perovskite (CaMn0.775Mg0.1Ti0.125O2.9-δ) material is evaluated during its in-situ activation under determined operating conditions in a 0.5 kWth CLC pilot plant. The combustion efficiency of methane over 60 h of continuous operation was analysed taking into consideration the effect of operating conditions on the activation process for increasing the reactivity of the perovskite. The material increased in reactivity as the ϕ ratio decreased to below 6, improving combustion efficiency. Moreover, the material was pre-activated by being fully reduced in the CLC plant. The conversion of methane with the pre-activated material was subsequently higher than the conversion achieved before the activation process, and almost complete combustion was achieved at a lower ϕ ratio. Characterization of the particles after the combustion tests showed good stability of the material with the operating time, although a negative effect on the crushing strength was observed when the particles were highly reduced. The impact of the perovskite material activation on the energy efficiency of the process is discussed.

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  • Cabello, Arturo & Abad, Alberto & Gayán, Pilar & García-Labiano, Francisco & de Diego, Luis F. & Adánez, Juan, 2021. "Increasing energy efficiency in chemical looping combustion of methane by in-situ activation of perovskite-based oxygen carriers," Applied Energy, Elsevier, vol. 287(C).
    • Handle: RePEc:eee:appene:v:287:y:2021:i:c:s0306261921001057
    DOI: 10.1016/j.apenergy.2021.116557
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    1. Håkonsen, Silje Fosse & Grande, Carlos A. & Blom, Richard, 2014. "Rotating bed reactor for CLC: Bed characteristics dependencies on internal gas mixing," Applied Energy, Elsevier, vol. 113(C), pages 1952-1957.
    2. Schmitz, Matthias & Linderholm, Carl Johan, 2016. "Performance of calcium manganate as oxygen carrier in chemical looping combustion of biochar in a 10kW pilot," Applied Energy, Elsevier, vol. 169(C), pages 729-737.
    3. Abad, A. & Pérez-Vega, R. & de Diego, L.F. & Gayán, P. & Izquierdo, M.T. & García-Labiano, F. & Adánez, J., 2019. "Thermochemical assessment of chemical looping assisted by oxygen uncoupling with a MnFe-based oxygen carrier," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    4. Galinsky, Nathan & Sendi, Marwan & Bowers, Lindsay & Li, Fanxing, 2016. "CaMn1−xBxO3−δ (B=Al, V, Fe, Co, and Ni) perovskite based oxygen carriers for chemical looping with oxygen uncoupling (CLOU)," Applied Energy, Elsevier, vol. 174(C), pages 80-87.
    5. Zhang, Hao & Hong, Hui & Jiang, Qiongqiong & Deng, Ya'nan & Jin, Hongguang & Kang, Qilan, 2018. "Development of a chemical-looping combustion reactor having porous honeycomb chamber and experimental validation by using NiO/NiAl2O4," Applied Energy, Elsevier, vol. 211(C), pages 259-268.
    6. Rydén, Magnus & Leion, Henrik & Mattisson, Tobias & Lyngfelt, Anders, 2014. "Combined oxides as oxygen-carrier material for chemical-looping with oxygen uncoupling," Applied Energy, Elsevier, vol. 113(C), pages 1924-1932.
    7. Galinsky, Nathan & Mishra, Amit & Zhang, Jia & Li, Fanxing, 2015. "Ca1−xAxMnO3 (A=Sr and Ba) perovskite based oxygen carriers for chemical looping with oxygen uncoupling (CLOU)," Applied Energy, Elsevier, vol. 157(C), pages 358-367.
    8. Fernández, J.R. & Abanades, J.C., 2014. "Conceptual design of a Ni-based chemical looping combustion process using fixed-beds," Applied Energy, Elsevier, vol. 135(C), pages 309-319.
    9. Mayer, Karl & Penthor, Stefan & Stollhof, Michael & Hofbauer, Hermann, 2019. "Evaluation of a new DCFB reactor system for chemical looping combustion of gaseous fuels," Applied Energy, Elsevier, vol. 255(C).
    10. Rajabi, Mahsa & Mehrpooya, Mehdi & Haibo, Zhao & Huang, Zhen, 2019. "Chemical looping technology in CHP (combined heat and power) and CCHP (combined cooling heating and power) systems: A critical review," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    11. Iloeje, Chukwunwike O. & Zhao, Zhenlong & Ghoniem, Ahmed F., 2018. "Design and techno-economic optimization of a rotary chemical looping combustion power plant with CO2 capture," Applied Energy, Elsevier, vol. 231(C), pages 1179-1190.
    12. Abad, Alberto & Adánez, Juan & Gayán, Pilar & de Diego, Luis F. & García-Labiano, Francisco & Sprachmann, Gerald, 2015. "Conceptual design of a 100MWth CLC unit for solid fuel combustion," Applied Energy, Elsevier, vol. 157(C), pages 462-474.
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    2. Adánez-Rubio, Iñaki & Izquierdo, María T. & Brorsson, Joakim & Mei, Daofeng & Mattisson, Tobias & Adánez, Juan, 2024. "Use of a high-entropy oxide as an oxygen carrier for chemical looping," Energy, Elsevier, vol. 298(C).

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