IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v306y2022ipas0306261921012976.html
   My bibliography  Save this article

Synergetic enhancement of heat storage density and heat transport ability of phase change materials inlaid in 3D hierarchical ceramics

Author

Listed:
  • Luo, Qingyang
  • Liu, Xianglei
  • Wang, Haolei
  • Xu, Qiao
  • Tian, Yang
  • Liang, Ting
  • Liu, Qibin
  • Liu, Zhan
  • Yang, Xiaohu
  • Xuan, Yimin
  • Li, Yongliang
  • Ding, Yulong

Abstract

Phase change materials (PCMs) based thermal energy storage techniques are promising to bridge the gap between thermal energy demand and intermittent supply. However, the low specific heat capacity (Cp) and thermal conductivity of PCMs preclude the simultaneous realization of high energy density and high power density thermal charging/discharging. Here, concurrent enhancement of Cp and thermal conductivity are demonstrated to be possible based on SiO2 nanoparticles decorated LiNO3/NaCl eutectics inlaid in three-dimensional (3D) hierarchical ultralight silicon carbide (SiC) foams. The average Cp is 4.86% higher than that of pure PCMs due to the high surface energy and interfacial thermal resistance induced by weak interaction between SiO2 nanoparticles and eutectics, as confirmed by molecular dynamics (MD) simulations. The thermal conductivity of composites achieves an ultrahigh value of 2.78 W·m−1·K−1, which is 259% of LiNO3/NaCl, accompanied with a large phase change enthalpy of 331.9 kJ/kg. Continuous heat transport paths provided by ultralight SiC foams have dominant contributions to the enhancement of thermal conductivity, although the presence of SiO2 nanoparticles deteriorates it slightly. In addition, the full-spectrum solar absorptance is enhanced from 25.2% to 76.3%. Rapid thermal transport and enhanced solar absorptance of composites enable heat charging rate to rise by 150% compared with SiO2 nanoparticles decorated eutectics. This work provides a strategy for the realization of high energy density and power density compatible thermal energy storage technology.

Suggested Citation

  • Luo, Qingyang & Liu, Xianglei & Wang, Haolei & Xu, Qiao & Tian, Yang & Liang, Ting & Liu, Qibin & Liu, Zhan & Yang, Xiaohu & Xuan, Yimin & Li, Yongliang & Ding, Yulong, 2022. "Synergetic enhancement of heat storage density and heat transport ability of phase change materials inlaid in 3D hierarchical ceramics," Applied Energy, Elsevier, vol. 306(PA).
    • Handle: RePEc:eee:appene:v:306:y:2022:i:pa:s0306261921012976
    DOI: 10.1016/j.apenergy.2021.117995
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261921012976
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2021.117995?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Nunes, V.M.B. & Lourenço, M.J.V. & Santos, F.J.V. & Nieto de Castro, C.A., 2019. "Molten alkali carbonates as alternative engineering fluids for high temperature applications," Applied Energy, Elsevier, vol. 242(C), pages 1626-1633.
    2. Wei, Xiaolan & Yin, Yue & Qin, Bo & Wang, Weilong & Ding, Jing & Lu, Jianfeng, 2020. "Preparation and enhanced thermal conductivity of molten salt nanofluids with nearly unaltered viscosity," Renewable Energy, Elsevier, vol. 145(C), pages 2435-2444.
    3. Muñoz-Sánchez, Belén & Nieto-Maestre, Javier & Iparraguirre-Torres, Iñigo & García-Romero, Ana & Sala-Lizarraga, Jose M., 2018. "Molten salt-based nanofluids as efficient heat transfer and storage materials at high temperatures. An overview of the literature," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3924-3945.
    4. Chen, Renjie & Yao, Ruimin & Xia, Wei & Zou, Ruqiang, 2015. "Electro/photo to heat conversion system based on polyurethane embedded graphite foam," Applied Energy, Elsevier, vol. 152(C), pages 183-188.
    5. Ni, Haiou & Wu, Jie & Sun, Ze & Lu, Guimin & Yu, Jianguo, 2019. "Molecular simulation of the structure and physical properties of alkali nitrate salts for thermal energy storage," Renewable Energy, Elsevier, vol. 136(C), pages 955-967.
    6. Tian, Heqing & Du, Lichan & Wei, Xiaolan & Deng, Suyan & Wang, Weilong & Ding, Jing, 2017. "Enhanced thermal conductivity of ternary carbonate salt phase change material with Mg particles for solar thermal energy storage," Applied Energy, Elsevier, vol. 204(C), pages 525-530.
    7. Ding, Jing & Pan, Gechuanqi & Du, Lichan & Lu, Jianfeng & Wang, Weilong & Wei, Xiaolan & Li, Jiang, 2018. "Molecular dynamics simulations of the local structures and transport properties of Na2CO3 and K2CO3," Applied Energy, Elsevier, vol. 227(C), pages 555-563.
    8. Jankowski, Nicholas R. & McCluskey, F. Patrick, 2014. "A review of phase change materials for vehicle component thermal buffering," Applied Energy, Elsevier, vol. 113(C), pages 1525-1561.
    9. Sharma, Atul & Tyagi, V.V. & Chen, C.R. & Buddhi, D., 2009. "Review on thermal energy storage with phase change materials and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(2), pages 318-345, February.
    10. Svobodova-Sedlackova, Adela & Barreneche, Camila & Alonso, Gerard & Fernandez, A. Inés & Gamallo, Pablo, 2020. "Effect of nanoparticles in molten salts – MD simulations and experimental study," Renewable Energy, Elsevier, vol. 152(C), pages 208-216.
    11. Zeng, Jia & Xuan, Yimin, 2018. "Enhanced solar thermal conversion and thermal conduction of MWCNT-SiO2/Ag binary nanofluids," Applied Energy, Elsevier, vol. 212(C), pages 809-819.
    12. Yang, Xiaohu & Yu, Jiabang & Guo, Zengxu & Jin, Liwen & He, Ya-Ling, 2019. "Role of porous metal foam on the heat transfer enhancement for a thermal energy storage tube," Applied Energy, Elsevier, vol. 239(C), pages 142-156.
    13. Ding, Jing & Du, Lichan & Pan, Gechuanqi & Lu, Jianfeng & Wei, Xiaolan & Li, Jiang & Wang, Weilong & Yan, Jinyue, 2018. "Molecular dynamics simulations of the local structures and thermodynamic properties on molten alkali carbonate K2CO3," Applied Energy, Elsevier, vol. 220(C), pages 536-544.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Liu, Jinjin & Xiao, Xin, 2023. "Molecular dynamics investigation of thermo-physical properties of molten salt with nanoparticles for solar energy application," Energy, Elsevier, vol. 282(C).
    2. Yao, Haichen & Liu, Xianglei & Li, Jiawei & Luo, Qingyang & Tian, Yang & Xuan, Yimin, 2023. "Chloroplast-granum inspired phase change capsules accelerate energy storage of packed-bed thermal energy storage system," Energy, Elsevier, vol. 284(C).
    3. Tian, Yang & Liu, Xianglei & Zheng, Hangbin & Xu, Qiao & Zhu, Zhonghui & Luo, Qinyang & Song, Chao & Gao, Ke & Yao, Haichen & Dang, Chunzhuo & Xuan, Yimin, 2022. "Artificial mitochondrion for fast latent heat storage: Experimental study and lattice Boltzmann simulation," Energy, Elsevier, vol. 245(C).
    4. Luo, Qingyang & Liu, Xianglei & Xu, Qiao & Tian, Yang & Yao, Haichen & Wang, Jianguo & Lv, Shushan & Dang, Chunzhuo & Xuan, Yimin, 2023. "Ceramic nanoparticles enhancement of latent heat thermal energy storage properties for LiNO3/NaCl: Evaluation from material to system level," Applied Energy, Elsevier, vol. 331(C).
    5. Liu, Xianglei & Ni, Renzhong & Tian, Yang & Yao, Haichen & Xu, Qiao & Xuan, Yimin, 2023. "Environment-friendly efficient thermal energy storage paradigm based on sugarcane-derived eco-ceramics phase change composites: From material to device," Renewable Energy, Elsevier, vol. 217(C).
    6. Yao, Haichen & Liu, Xianglei & Luo, Qingyang & Xu, Qiao & Tian, Yang & Ren, Tianze & Zheng, Hangbin & Gao, Ke & Dang, Chunzhuo & Xuan, Yimin & Liu, Zhan & Yang, Xiaohu & Ding, Yulong, 2022. "Experimental and numerical investigations of solar charging performances of 3D porous skeleton based latent heat storage devices," Applied Energy, Elsevier, vol. 320(C).
    7. Zhang, Shuai & Yan, Yuying, 2023. "Energy, exergy and economic analysis of ceramic foam-enhanced molten salt as phase change material for medium- and high-temperature thermal energy storage," Energy, Elsevier, vol. 262(PA).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Luo, Qingyang & Liu, Xianglei & Xu, Qiao & Tian, Yang & Yao, Haichen & Wang, Jianguo & Lv, Shushan & Dang, Chunzhuo & Xuan, Yimin, 2023. "Ceramic nanoparticles enhancement of latent heat thermal energy storage properties for LiNO3/NaCl: Evaluation from material to system level," Applied Energy, Elsevier, vol. 331(C).
    2. Ruan, Zhao-Hui & Gao, Peng & Yuan, Yuan & Tan, He-Ping, 2022. "Theoretical estimation of temperature-dependent radiation properties of molten solar salt using molecular dynamics and first principles," Energy, Elsevier, vol. 246(C).
    3. Jingyu Zhong & Jing Ding & Jianfeng Lu & Xiaolan Wei & Weilong Wang, 2022. "Thermal Stability Calculation and Experimental Investigation of Common Binary Chloride Molten Salts Applied in Concentrating Solar Power Plants," Energies, MDPI, vol. 15(7), pages 1-31, March.
    4. Jayathunga, D.S. & Karunathilake, H.P. & Narayana, M. & Witharana, S., 2024. "Phase change material (PCM) candidates for latent heat thermal energy storage (LHTES) in concentrated solar power (CSP) based thermal applications - A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    5. Rostami, Sara & Afrand, Masoud & Shahsavar, Amin & Sheikholeslami, M. & Kalbasi, Rasool & Aghakhani, Saeed & Shadloo, Mostafa Safdari & Oztop, Hakan F., 2020. "A review of melting and freezing processes of PCM/nano-PCM and their application in energy storage," Energy, Elsevier, vol. 211(C).
    6. Costa, Sol Carolina & Kenisarin, Murat, 2022. "A review of metallic materials for latent heat thermal energy storage: Thermophysical properties, applications, and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    7. Kumar, Ashish & Saha, Sandip K., 2020. "Experimental and numerical study of latent heat thermal energy storage with high porosity metal matrix under intermittent heat loads," Applied Energy, Elsevier, vol. 263(C).
    8. Haiming Long & Yunkun Lu & Liang Chang & Haifeng Zhang & Jingcen Zhang & Gaoqun Zhang & Junjie Hao, 2022. "Molecular Dynamics Simulation of Thermophysical Properties and the Microstructure of Na 2 CO 3 Heat Storage Materials," Energies, MDPI, vol. 15(19), pages 1-13, September.
    9. Han, Lipeng & Xie, Shaolei & Liu, Shang & Sun, Jinhe & Jia, Yongzhong & Jing, Yan, 2017. "Effects of sodium chloride on the thermal behavior of oxalic acid dihydrate for thermal energy storage," Applied Energy, Elsevier, vol. 185(P1), pages 762-767.
    10. Nunes, V.M.B. & Lourenço, M.J.V. & Santos, F.J.V. & Nieto de Castro, C.A., 2019. "Molten alkali carbonates as alternative engineering fluids for high temperature applications," Applied Energy, Elsevier, vol. 242(C), pages 1626-1633.
    11. Lin, Yaxue & Alva, Guruprasad & Fang, Guiyin, 2018. "Review on thermal performances and applications of thermal energy storage systems with inorganic phase change materials," Energy, Elsevier, vol. 165(PA), pages 685-708.
    12. Liu, Yilin & Cui, Xin & Yan, Weichao & Wang, Jiawei & Su, Jincai & Jin, Liwen, 2022. "A molecular level based parametric study of transport behavior in different polymer composite membranes for water vapor separation," Applied Energy, Elsevier, vol. 326(C).
    13. Gunasekara, Saman Nimali & Pan, Ruijun & Chiu, Justin Ningwei & Martin, Viktoria, 2016. "Polyols as phase change materials for surplus thermal energy storage," Applied Energy, Elsevier, vol. 162(C), pages 1439-1452.
    14. Pereira da Cunha, Jose & Eames, Philip, 2016. "Thermal energy storage for low and medium temperature applications using phase change materials – A review," Applied Energy, Elsevier, vol. 177(C), pages 227-238.
    15. Zhang, P. & Xiao, X. & Ma, Z.W., 2016. "A review of the composite phase change materials: Fabrication, characterization, mathematical modeling and application to performance enhancement," Applied Energy, Elsevier, vol. 165(C), pages 472-510.
    16. Browne, M.C. & Norton, B. & McCormack, S.J., 2015. "Phase change materials for photovoltaic thermal management," Renewable and Sustainable Energy Reviews, Elsevier, vol. 47(C), pages 762-782.
    17. Kondaiah, P. & Pitchumani, R., 2023. "Progress and opportunities in corrosion mitigation in heat transfer fluids for next-generation concentrating solar power," Renewable Energy, Elsevier, vol. 205(C), pages 956-991.
    18. Liu, Yang & Zheng, Ruowei & Li, Ji, 2022. "High latent heat phase change materials (PCMs) with low melting temperature for thermal management and storage of electronic devices and power batteries: Critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    19. Zhang, Huili & Kong, Weibin & Tan, Tianwei & Baeyens, Jan, 2017. "High-efficiency concentrated solar power plants need appropriate materials for high-temperature heat capture, conveying and storage," Energy, Elsevier, vol. 139(C), pages 52-64.
    20. Rong, Zhenzhou & Pan, Gechuanqi & Lu, Jianfeng & Liu, Shule & Ding, Jing & Wang, Weilong & Lee, Duu-Jong, 2021. "Ab-initio molecular dynamics study on thermal property of NaCl–CaCl2 molten salt for high-temperature heat transfer and storage," Renewable Energy, Elsevier, vol. 163(C), pages 579-588.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:306:y:2022:i:pa:s0306261921012976. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.