IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v290y2021ics0306261921002828.html
   My bibliography  Save this article

A novel structural design of air cathodes expanding three-phase reaction interfaces for zinc-air batteries

Author

Listed:
  • Pan, Lyuming
  • Chen, Dongfang
  • Pei, Pucheng
  • Huang, Shangwei
  • Ren, Peng
  • Song, Xin

Abstract

Zinc-air batteries are considered as potential energy conversion systems. One of the main issues of zinc-air batteries is the low actual power density. However, the three-phase reaction interfaces are limited in 2D plane of conventional air cathodes, which limits the electrochemical kinetics and the commercialization of zinc-air batteries. Here, a novel structural design of air cathodes with multi current collectors and gradient hydrophobicity to improve the discharge power for zinc-air batteries is proposed. Based on non-noble metal catalysts, the three-phase reaction interfaces expand from 2D plane to 3D zone by the novel structural design, increasing the power density of the battery. The gradient distribution of hydrophobicity in the air cathode can be obtained in one step through the soaking-drying process. When the soaking-drying process reaches twice, the optimal performance is achieved due to the balance of hydrophilicity and hydrophobicity. The peak power density of 120 mW·cm−2 is achieved in the zinc-air battery with MnO2 as catalysts. After continuously discharging at 20 mA·cm−2 exceed 9 h, the electrochemical performance can be restored by replacing with a new metal anode and keeping the initial air cathode. This work illustrates that the novel structural design of air cathodes can effectively improve the power density of zinc-air batteries, which is beneficial to the application of zinc-air batteries in the fields of energy storage and conversion.

Suggested Citation

  • Pan, Lyuming & Chen, Dongfang & Pei, Pucheng & Huang, Shangwei & Ren, Peng & Song, Xin, 2021. "A novel structural design of air cathodes expanding three-phase reaction interfaces for zinc-air batteries," Applied Energy, Elsevier, vol. 290(C).
    • Handle: RePEc:eee:appene:v:290:y:2021:i:c:s0306261921002828
    DOI: 10.1016/j.apenergy.2021.116777
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261921002828
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2021.116777?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Wang, Keliang & Pei, Pucheng & Wang, Yichun & Liao, Cheng & Wang, Wei & Huang, Shangwei, 2018. "Advanced rechargeable zinc-air battery with parameter optimization," Applied Energy, Elsevier, vol. 225(C), pages 848-856.
    2. Pei, Pucheng & Wang, Keliang & Ma, Ze, 2014. "Technologies for extending zinc–air battery’s cyclelife: A review," Applied Energy, Elsevier, vol. 128(C), pages 315-324.
    3. Xu, Nengneng & Zhang, Yanxing & Wang, Yudong & Wang, Min & Su, Tianshun & Coco, Cameron A. & Qiao, Jinli & Zhou, Xiao-Dong, 2020. "Hierarchical bifunctional catalysts with tailored catalytic activity for high-energy rechargeable Zn-air batteries," Applied Energy, Elsevier, vol. 279(C).
    4. Zachary P. Cano & Dustin Banham & Siyu Ye & Andreas Hintennach & Jun Lu & Michael Fowler & Zhongwei Chen, 2018. "Batteries and fuel cells for emerging electric vehicle markets," Nature Energy, Nature, vol. 3(4), pages 279-289, April.
    5. Mohideen, Mohamedazeem M. & Liu, Yong & Ramakrishna, Seeram, 2020. "Recent progress of carbon dots and carbon nanotubes applied in oxygen reduction reaction of fuel cell for transportation," Applied Energy, Elsevier, vol. 257(C).
    6. Hou, Yuze & Deng, Hao & Pan, Fengwen & Chen, Wenmiao & Du, Qing & Jiao, Kui, 2019. "Pore-scale investigation of catalyst layer ingredient and structure effect in proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    7. M. Armand & J.-M. Tarascon, 2008. "Building better batteries," Nature, Nature, vol. 451(7179), pages 652-657, February.
    8. She, Yiyi & Chen, Jinfan & Zhang, Chengxu & Lu, Zhouguang & Ni, Meng & Sit, Patrick H.-L. & Leung, Michael K.H., 2018. "Nitrogen-doped graphene derived from ionic liquid as metal-free catalyst for oxygen reduction reaction and its mechanisms," Applied Energy, Elsevier, vol. 225(C), pages 513-521.
    9. Pei, Pucheng & Huang, Shangwei & Chen, Dongfang & Li, Yuehua & Wu, Ziyao & Ren, Peng & Wang, Keliang & Jia, Xiaoning, 2019. "A high-energy-density and long-stable-performance zinc-air fuel cell system," Applied Energy, Elsevier, vol. 241(C), pages 124-129.
    10. Steven Chu & Arun Majumdar, 2012. "Opportunities and challenges for a sustainable energy future," Nature, Nature, vol. 488(7411), pages 294-303, August.
    11. Yuan, Rong-hua & He, Yun & He, Wei & Ni, Meng & Leung, Michael K.H., 2019. "Bifunctional electrocatalytic activity of La0.8Sr0.2MnO3-based perovskite with the A-site deficiency for oxygen reduction and evolution reactions in alkaline media," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    12. Han, Gwangwoo & Kwon, YongKeun & Kim, Joong Bae & Lee, Sanghun & Bae, Joongmyeon & Cho, EunAe & Lee, Bong Jae & Cho, Sungbaek & Park, Jinwoo, 2020. "Development of a high-energy-density portable/mobile hydrogen energy storage system incorporating an electrolyzer, a metal hydride and a fuel cell," Applied Energy, Elsevier, vol. 259(C).
    13. Wang, Likun & Bliznakov, Stoyan & Isseroff, Rebecca & Zhou, Yuchen & Zuo, Xianghao & Raut, Aniket & Wang, Wanhua & Cuiffo, Michael & Kim, Taejin & Rafailovich, Miriam H., 2020. "Enhancing proton exchange membrane fuel cell performance via graphene oxide surface synergy," Applied Energy, Elsevier, vol. 261(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Huang, Huiyu & Liu, Pengzhan & Ma, Qiuxia & Tang, Zihao & Wang, Mu & Hu, Junhui, 2023. "Airborne ultrasound catalyzed saltwater Al/Mg-air flow batteries," Energy, Elsevier, vol. 270(C).
    2. Wei, Manhui & Wang, Keliang & Pei, Pucheng & Zuo, Yayu & Zhong, Liping & Shang, Nuo & Wang, Hengwei & Chen, Junfeng & Zhang, Pengfei & Chen, Zhuo, 2022. "An enhanced-performance Al-air battery optimizing the alkaline electrolyte with a strong Lewis acid ZnCl2," Applied Energy, Elsevier, vol. 324(C).
    3. Shang, Wenxu & Yu, Wentao & Xiao, Xu & Ma, Yanyi & Chen, Ziqi & Ni, Meng & Tan, Peng, 2022. "Optimizing the charging protocol to address the self-discharge issues in rechargeable alkaline Zn-Co batteries," Applied Energy, Elsevier, vol. 308(C).
    4. Pedram Asef & Marzia Milan & Andrew Lapthorn & Sanjeevikumar Padmanaban, 2021. "Future Trends and Aging Analysis of Battery Energy Storage Systems for Electric Vehicles," Sustainability, MDPI, vol. 13(24), pages 1-28, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chen, Dongfang & Pan, Lyuming & Pei, Pucheng & Huang, Shangwei & Ren, Peng & Song, Xin, 2021. "Carbon-coated oxygen vacancies-rich Co3O4 nanoarrays grow on nickel foam as efficient bifunctional electrocatalysts for rechargeable zinc-air batteries," Energy, Elsevier, vol. 224(C).
    2. Wei, Manhui & Wang, Keliang & Pei, Pucheng & Zuo, Yayu & Zhong, Liping & Shang, Nuo & Wang, Hengwei & Chen, Junfeng & Zhang, Pengfei & Chen, Zhuo, 2022. "An enhanced-performance Al-air battery optimizing the alkaline electrolyte with a strong Lewis acid ZnCl2," Applied Energy, Elsevier, vol. 324(C).
    3. Wang, Yifei & Kwok, Holly Y.H. & Pan, Wending & Zhang, Huimin & Lu, Xu & Leung, Dennis Y.C., 2019. "Parametric study and optimization of a low-cost paper-based Al-air battery with corrosion inhibition ability," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    4. Sangeetha, Thangavel & Chen, Po-Tuan & Yan, Wei-Mon & Huang, K. David, 2020. "Enhancement of air-flow management in Zn-air fuel cells by the optimization of air-flow parameters," Energy, Elsevier, vol. 197(C).
    5. Géremi Gilson Dranka & Paula Ferreira, 2020. "Electric Vehicles and Biofuels Synergies in the Brazilian Energy System," Energies, MDPI, vol. 13(17), pages 1-22, August.
    6. Lili Zhang & Ning Zhang & Huishan Shang & Zhiyi Sun & Zihao Wei & Jingtao Wang & Yuanting Lei & Xiaochen Wang & Dan Wang & Yafei Zhao & Zhongti Sun & Fang Zhang & Xu Xiang & Bing Zhang & Wenxing Chen, 2024. "High-density asymmetric iron dual-atom sites for efficient and stable electrochemical water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    7. Du, Peng & Cao, Liang & Zhang, Bao & Wang, Chunhui & Xiao, Zhiming & Zhang, Jiafeng & Wang, Dong & Ou, Xing, 2021. "Recent progress on heterostructure materials for next-generation sodium/potassium ion batteries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    8. Shaozhen Huang & Zhibin Wu & Bernt Johannessen & Kecheng Long & Piao Qing & Pan He & Xiaobo Ji & Weifeng Wei & Yuejiao Chen & Libao Chen, 2023. "Interfacial friction enabling ≤ 20 μm thin free-standing lithium strips for lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    9. Trocino, Stefano & Lo Faro, Massimiliano & Zignani, Sabrina Campagna & Antonucci, Vincenzo & Aricò, Antonino Salvatore, 2019. "High performance solid-state iron-air rechargeable ceramic battery operating at intermediate temperatures (500–650 °C)," Applied Energy, Elsevier, vol. 233, pages 386-394.
    10. Chunbo Zhang & Xiang Zhao & Romain Sacchi & Fengqi You, 2023. "Trade-off between critical metal requirement and transportation decarbonization in automotive electrification," Nature Communications, Nature, vol. 14(1), pages 1-16, December.
    11. Thangavel Sangeetha & Po-Tuan Chen & Wu-Fu Cheng & Wei-Mon Yan & K. David Huang, 2019. "Optimization of the Electrolyte Parameters and Components in Zinc Particle Fuel Cells," Energies, MDPI, vol. 12(6), pages 1-13, March.
    12. Chen, Haosen & Fan, Jinbao & Zhang, Mingliang & Feng, Xiaolong & Zhong, Ximing & He, Jianchao & Ai, Shigang, 2023. "Mechanism of inhomogeneous deformation and equal-stiffness design of large-format prismatic lithium-ion batteries," Applied Energy, Elsevier, vol. 332(C).
    13. Wei, Manhui & Wang, Keliang & Pei, Pucheng & Zhong, Liping & Züttel, Andreas & Pham, Thi Ha My & Shang, Nuo & Zuo, Yayu & Wang, Hengwei & Zhao, Siyuan, 2023. "Zinc carboxylate optimization strategy for extending Al-air battery system's lifetime," Applied Energy, Elsevier, vol. 350(C).
    14. Ban Seok Lee & Sang-Hwan Oh & Yoon Jeong Choi & Min-Jeong Yi & So Hee Kim & Shin-Yeong Kim & Yung-Eun Sung & Sun Young Shin & Yongju Lee & Seung-Ho Yu, 2023. "SiO-induced thermal instability and interplay between graphite and SiO in graphite/SiO composite anode," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    15. Zhou, Wenbin & Cleaver, Christopher J. & Dunant, Cyrille F. & Allwood, Julian M. & Lin, Jianguo, 2023. "Cost, range anxiety and future electricity supply: A review of how today's technology trends may influence the future uptake of BEVs," Renewable and Sustainable Energy Reviews, Elsevier, vol. 173(C).
    16. Xu, Nengneng & Qiao, Jinli & Zhang, Xia & Ma, Chengyu & Jian, Saiai & Liu, Yuyu & Pei, Pucheng, 2016. "Morphology controlled La2O3/Co3O4/MnO2–CNTs hybrid nanocomposites with durable bi-functional air electrode in high-performance zinc–air energy storage," Applied Energy, Elsevier, vol. 175(C), pages 495-504.
    17. Manzetti, Sergio & Mariasiu, Florin, 2015. "Electric vehicle battery technologies: From present state to future systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 1004-1012.
    18. Xiangyong Zhang & Hua Wei & Shizhen Li & Baohui Ren & Jingjing Jiang & Guangmeng Qu & Haiming Lv & Guojin Liang & Guangming Chen & Chunyi Zhi & Hongfei Li & Zhuoxin Liu, 2023. "Manipulating coordination environment for a high-voltage aqueous copper-chlorine battery," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    19. Minsung Baek & Jinyoung Kim & Kwanghoon Jeong & Seonmo Yang & Heejin Kim & Jimin Lee & Minkwan Kim & Ki Jae Kim & Jang Wook Choi, 2023. "Naked metallic skin for homo-epitaxial deposition in lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    20. Mohideen, Mohamedazeem M. & Subramanian, Balachandran & Sun, Jingyi & Ge, Jing & Guo, Han & Radhamani, Adiyodi Veettil & Ramakrishna, Seeram & Liu, Yong, 2023. "Techno-economic analysis of different shades of renewable and non-renewable energy-based hydrogen for fuel cell electric vehicles," Renewable and Sustainable Energy Reviews, Elsevier, vol. 174(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:290:y:2021:i:c:s0306261921002828. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.