IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-36934-x.html
   My bibliography  Save this article

Naked metallic skin for homo-epitaxial deposition in lithium metal batteries

Author

Listed:
  • Minsung Baek

    (Seoul National University)

  • Jinyoung Kim

    (Seoul National University)

  • Kwanghoon Jeong

    (Seoul National University)

  • Seonmo Yang

    (Seoul National University)

  • Heejin Kim

    (Korea Basic Science Institute)

  • Jimin Lee

    (Seoul National University)

  • Minkwan Kim

    (Seoul National University)

  • Ki Jae Kim

    (Konkuk University)

  • Jang Wook Choi

    (Seoul National University
    Seoul National University)

Abstract

Regulating the morphology of lithium plating is the key to extending the cycle life of lithium metal batteries. Fatal dendritic growth is closely related to out-of-plane nucleation on the lithium metal surface. Herein, we report a nearly perfect lattice match between the lithium metal foil and lithium deposits by removing the native oxide layer using simple bromine-based acid-base chemistry. The naked lithium surface induces homo-epitaxial lithium plating with columnar morphologies and lower overpotentials. Using the naked lithium foil, the lithium-lithium symmetric cell maintains stable cycling at 10 mA cm−2 for more than 10,000 cycles, and the full-cell paired with LiFePO4 with high areal capacity of 3.3 mAh cm−2 and practical N/P ratio of 2.5 exhibits 86% capacity retention after 300 cycles. This study elucidates the usefulness of controlling the initial surface state to facilitate homo-epitaxial lithium plating for sustainable cycling of lithium metal batteries.

Suggested Citation

  • Minsung Baek & Jinyoung Kim & Kwanghoon Jeong & Seonmo Yang & Heejin Kim & Jimin Lee & Minkwan Kim & Ki Jae Kim & Jang Wook Choi, 2023. "Naked metallic skin for homo-epitaxial deposition in lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36934-x
    DOI: 10.1038/s41467-023-36934-x
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-36934-x
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-023-36934-x?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Chun-Peng Yang & Ya-Xia Yin & Shuai-Feng Zhang & Nian-Wu Li & Yu-Guo Guo, 2015. "Accommodating lithium into 3D current collectors with a submicron skeleton towards long-life lithium metal anodes," Nature Communications, Nature, vol. 6(1), pages 1-9, November.
    2. Yayuan Liu & Dingchang Lin & Zheng Liang & Jie Zhao & Kai Yan & Yi Cui, 2016. "Lithium-coated polymeric matrix as a minimum volume-change and dendrite-free lithium metal anode," Nature Communications, Nature, vol. 7(1), pages 1-9, April.
    3. M. Armand & J.-M. Tarascon, 2008. "Building better batteries," Nature, Nature, vol. 451(7179), pages 652-657, February.
    4. Rochelle Weber & Matthew Genovese & A. J. Louli & Samuel Hames & Cameron Martin & Ian G. Hill & J. R. Dahn, 2019. "Long cycle life and dendrite-free lithium morphology in anode-free lithium pouch cells enabled by a dual-salt liquid electrolyte," Nature Energy, Nature, vol. 4(8), pages 683-689, August.
    5. J.-M. Tarascon & M. Armand, 2001. "Issues and challenges facing rechargeable lithium batteries," Nature, Nature, vol. 414(6861), pages 359-367, November.
    6. Jiangyan Wang & William Huang & Allen Pei & Yuzhang Li & Feifei Shi & Xiaoyun Yu & Yi Cui, 2019. "Improving cyclability of Li metal batteries at elevated temperatures and its origin revealed by cryo-electron microscopy," Nature Energy, Nature, vol. 4(8), pages 664-670, August.
    7. Steven Chu & Arun Majumdar, 2012. "Opportunities and challenges for a sustainable energy future," Nature, Nature, vol. 488(7411), pages 294-303, August.
    8. Yadong Liu & Qi Liu & Le Xin & Yuzi Liu & Fan Yang & Eric A. Stach & Jian Xie, 2017. "Making Li-metal electrodes rechargeable by controlling the dendrite growth direction," Nature Energy, Nature, vol. 2(7), pages 1-10, July.
    9. Yuki Yamada & Jianhui Wang & Seongjae Ko & Eriko Watanabe & Atsuo Yamada, 2019. "Advances and issues in developing salt-concentrated battery electrolytes," Nature Energy, Nature, vol. 4(4), pages 269-280, April.
    10. Jiangfeng Qian & Wesley A. Henderson & Wu Xu & Priyanka Bhattacharya & Mark Engelhard & Oleg Borodin & Ji-Guang Zhang, 2015. "High rate and stable cycling of lithium metal anode," Nature Communications, Nature, vol. 6(1), pages 1-9, May.
    11. Hui Wang & Masaki Matsui & Hiroko Kuwata & Hidetoshi Sonoki & Yasuaki Matsuda & Xuefu Shang & Yasuo Takeda & Osamu Yamamoto & Nobuyuki Imanishi, 2017. "A reversible dendrite-free high-areal-capacity lithium metal electrode," Nature Communications, Nature, vol. 8(1), pages 1-9, April.
    12. Mukul D. Tikekar & Snehashis Choudhury & Zhengyuan Tu & Lynden A. Archer, 2016. "Design principles for electrolytes and interfaces for stable lithium-metal batteries," Nature Energy, Nature, vol. 1(9), pages 1-7, September.
    13. Yu Gu & Wei-Wei Wang & Yi-Juan Li & Qi-Hui Wu & Shuai Tang & Jia-Wei Yan & Ming-Sen Zheng & De-Yin Wu & Chun-Hai Fan & Wei-Qiang Hu & Zhao-Bin Chen & Yuan Fang & Qing-Hong Zhang & Quan-Feng Dong & Bin, 2018. "Designable ultra-smooth ultra-thin solid-electrolyte interphases of three alkali metal anodes," Nature Communications, Nature, vol. 9(1), pages 1-9, December.
    14. Chaojiang Niu & Hongkyung Lee & Shuru Chen & Qiuyan Li & Jason Du & Wu Xu & Ji-Guang Zhang & M. Stanley Whittingham & Jie Xiao & Jun Liu, 2019. "High-energy lithium metal pouch cells with limited anode swelling and long stable cycles," Nature Energy, Nature, vol. 4(7), pages 551-559, July.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chao Wang & Ming Liu & Michel Thijs & Frans G. B. Ooms & Swapna Ganapathy & Marnix Wagemaker, 2021. "High dielectric barium titanate porous scaffold for efficient Li metal cycling in anode-free cells," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    2. Zhi Chang & Huijun Yang & Xingyu Zhu & Ping He & Haoshen Zhou, 2022. "A stable quasi-solid electrolyte improves the safe operation of highly efficient lithium-metal pouch cells in harsh environments," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    3. Zhi Chang & Huijun Yang & Anqiang Pan & Ping He & Haoshen Zhou, 2022. "An improved 9 micron thick separator for a 350 Wh/kg lithium metal rechargeable pouch cell," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    4. Xiaozhe Zhang & Pan Xu & Jianing Duan & Xiaodong Lin & Juanjuan Sun & Wenjie Shi & Hewei Xu & Wenjie Dou & Qingyi Zheng & Ruming Yuan & Jiande Wang & Yan Zhang & Shanshan Yu & Zehan Chen & Mingsen Zhe, 2024. "A dicarbonate solvent electrolyte for high performance 5 V-Class Lithium-based batteries," Nature Communications, Nature, vol. 15(1), pages 1-18, December.
    5. Zhixin Xu & Xiyue Zhang & Jun Yang & Xuzixu Cui & Yanna Nuli & Jiulin Wang, 2024. "High-voltage and intrinsically safe electrolytes for Li metal batteries," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    6. Yan Zhao & Tianhong Zhou & Timur Ashirov & Mario El Kazzi & Claudia Cancellieri & Lars P. H. Jeurgens & Jang Wook Choi & Ali Coskun, 2022. "Fluorinated ether electrolyte with controlled solvation structure for high voltage lithium metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    7. Yan Zhao & Tianhong Zhou & Mounir Mensi & Jang Wook Choi & Ali Coskun, 2023. "Electrolyte engineering via ether solvent fluorination for developing stable non-aqueous lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    8. Solomon T. Oyakhire & Wenbo Zhang & Andrew Shin & Rong Xu & David T. Boyle & Zhiao Yu & Yusheng Ye & Yufei Yang & James A. Raiford & William Huang & Joel R. Schneider & Yi Cui & Stacey F. Bent, 2022. "Electrical resistance of the current collector controls lithium morphology," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    9. Mohammadmahdi Ghiji & Vasily Novozhilov & Khalid Moinuddin & Paul Joseph & Ian Burch & Brigitta Suendermann & Grant Gamble, 2020. "A Review of Lithium-Ion Battery Fire Suppression," Energies, MDPI, vol. 13(19), pages 1-30, October.
    10. Chen, Dongfang & Pan, Lyuming & Pei, Pucheng & Huang, Shangwei & Ren, Peng & Song, Xin, 2021. "Carbon-coated oxygen vacancies-rich Co3O4 nanoarrays grow on nickel foam as efficient bifunctional electrocatalysts for rechargeable zinc-air batteries," Energy, Elsevier, vol. 224(C).
    11. Ziheng Zhang & Maxim Avdeev & Huaican Chen & Wen Yin & Wang Hay Kan & Guang He, 2022. "Lithiated Prussian blue analogues as positive electrode active materials for stable non-aqueous lithium-ion batteries," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    12. Hyeokjin Kwon & Hyun-Ji Choi & Jung-kyu Jang & Jinhong Lee & Jinkwan Jung & Wonjun Lee & Youngil Roh & Jaewon Baek & Dong Jae Shin & Ju-Hyuk Lee & Nam-Soon Choi & Ying Shirley Meng & Hee-Tak Kim, 2023. "Weakly coordinated Li ion in single-ion-conductor-based composite enabling low electrolyte content Li-metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    13. Jack E. N. Swallow & Michael W. Fraser & Nis-Julian H. Kneusels & Jodie F. Charlton & Christopher G. Sole & Conor M. E. Phelan & Erik Björklund & Peter Bencok & Carlos Escudero & Virginia Pérez-Dieste, 2022. "Revealing solid electrolyte interphase formation through interface-sensitive Operando X-ray absorption spectroscopy," Nature Communications, Nature, vol. 13(1), pages 1-14, December.
    14. Lili Zhang & Ning Zhang & Huishan Shang & Zhiyi Sun & Zihao Wei & Jingtao Wang & Yuanting Lei & Xiaochen Wang & Dan Wang & Yafei Zhao & Zhongti Sun & Fang Zhang & Xu Xiang & Bing Zhang & Wenxing Chen, 2024. "High-density asymmetric iron dual-atom sites for efficient and stable electrochemical water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    15. Sewon Kim & Ju-Sik Kim & Lincoln Miara & Yan Wang & Sung-Kyun Jung & Seong Yong Park & Zhen Song & Hyungsub Kim & Michael Badding & JaeMyung Chang & Victor Roev & Gabin Yoon & Ryounghee Kim & Jung-Hwa, 2022. "High-energy and durable lithium metal batteries using garnet-type solid electrolytes with tailored lithium-metal compatibility," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    16. Mengyao Tang & Shuai Dong & Jiawei Wang & Liwei Cheng & Qiaonan Zhu & Yanmei Li & Xiuyi Yang & Lin Guo & Hua Wang, 2023. "Low-temperature anode-free potassium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    17. Du, Peng & Cao, Liang & Zhang, Bao & Wang, Chunhui & Xiao, Zhiming & Zhang, Jiafeng & Wang, Dong & Ou, Xing, 2021. "Recent progress on heterostructure materials for next-generation sodium/potassium ion batteries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    18. Shaozhen Huang & Zhibin Wu & Bernt Johannessen & Kecheng Long & Piao Qing & Pan He & Xiaobo Ji & Weifeng Wei & Yuejiao Chen & Libao Chen, 2023. "Interfacial friction enabling ≤ 20 μm thin free-standing lithium strips for lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    19. Troy, Stefanie & Schreiber, Andrea & Reppert, Thorsten & Gehrke, Hans-Gregor & Finsterbusch, Martin & Uhlenbruck, Sven & Stenzel, Peter, 2016. "Life Cycle Assessment and resource analysis of all-solid-state batteries," Applied Energy, Elsevier, vol. 169(C), pages 757-767.
    20. Weili Zhang & Yang Lu & Lei Wan & Pan Zhou & Yingchun Xia & Shuaishuai Yan & Xiaoxia Chen & Hangyu Zhou & Hao Dong & Kai Liu, 2022. "Engineering a passivating electric double layer for high performance lithium metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-12, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36934-x. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.