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SiO-induced thermal instability and interplay between graphite and SiO in graphite/SiO composite anode

Author

Listed:
  • Ban Seok Lee

    (Korea University)

  • Sang-Hwan Oh

    (Korea University)

  • Yoon Jeong Choi

    (Korea University)

  • Min-Jeong Yi

    (Korea University)

  • So Hee Kim

    (Korea Institute of Science and Technology (KIST))

  • Shin-Yeong Kim

    (Seoul National University
    Institute for Basic Science (IBS))

  • Yung-Eun Sung

    (Seoul National University
    Institute for Basic Science (IBS))

  • Sun Young Shin

    (LG Energy Solution, Research Park)

  • Yongju Lee

    (LG Energy Solution, Research Park)

  • Seung-Ho Yu

    (Korea University)

Abstract

Silicon monoxide (SiO), which exhibits better cyclability compared to silicon while delivering higher capacity than that of graphite, is an adequate material for the development of lithium-ion batteries (LIBs) having higher energy densities. However, incorporating silicon-based materials including SiO into stable graphite anode inevitably degrades not only cycle life but also calendar life of LIBs, while little is known about their aging mechanisms. Here, SiO-induced thermal instability of the graphite/SiO composite anode is investigated. We reveal that under thermal exposure, SiO accelerates the loss of lithium inventory and concomitantly facilitates the lithium de-intercalation from graphite. This self-discharge phenomenon, which is weakly observed in the graphite anode without SiO, is the result of preferential parasitic reaction on the SiO interface and spontaneous electron and lithium-ion migration to equilibrate the electron energy imbalance between graphite and SiO. Understanding this underlying electron-level interplay between graphite and SiO in the composite anode will contribute toward improving shelf life of SiO-containing LIBs in actual operating conditions.

Suggested Citation

  • Ban Seok Lee & Sang-Hwan Oh & Yoon Jeong Choi & Min-Jeong Yi & So Hee Kim & Shin-Yeong Kim & Yung-Eun Sung & Sun Young Shin & Yongju Lee & Seung-Ho Yu, 2023. "SiO-induced thermal instability and interplay between graphite and SiO in graphite/SiO composite anode," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-022-35769-2
    DOI: 10.1038/s41467-022-35769-2
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    References listed on IDEAS

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