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Hierarchical bifunctional catalysts with tailored catalytic activity for high-energy rechargeable Zn-air batteries

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  • Xu, Nengneng
  • Zhang, Yanxing
  • Wang, Yudong
  • Wang, Min
  • Su, Tianshun
  • Coco, Cameron A.
  • Qiao, Jinli
  • Zhou, Xiao-Dong

Abstract

For Zn-air batteries, much research is still needed to obtain low-cost, high-efficient, and strong durability bifunctional catalysts to promote various electrochemical reactions. In this article, MnO2/carbon-nanotubes (CNTs) hybrid catalysts anchored with a metal oxide (M−MnO2/CNTs) are developed via a facile hydrothermal process toward an efficient oxygen catalytic (evolution and reduction) reactions. M−MnO2/CNTs displays better catalytic activity than MnO2/CNTs. The overpotential of Co-MnO2/CNTs is lowered to 0.803 V, very close to that of Pt/C + IrO2 (0.801 V). Moreover, Co-MnO2/CNTs exhibits faster kinetics for oxygen evolution reaction with low Tafel slope (62 mV dec−1) than Pt/C + IrO2. The improved performance and stability originated from (i) the novel hierarchal structure improving the mass transport, (ii) the redistribution of electrons activating the Mn catalytic sites, (iii) the coupling effect between the metal oxide and MnO2/CNTs, and (iv) an excellent conductivity building a fast electron transfer high-way. The density functional theory results reveal that the anchored metal oxide cluster directly activates neighbor Mn sites on the surface of the hybrid catalyst, and enhances the oxygen catalytic activity by decreasing the bonding with OH and OOH. Accordingly, the maximum power density of the Co-MnO2/CNTs-based Zn-air battery reaches 342.7 mW cm−2. The Zn-air battery also exhibits good charge–discharge stability with a low voltage gap of 0.72 V for 128 h. This work provides an effective method to achieve MnO2/CNTs materials with tailored catalytic activity by anchoring different metal oxides and demonstrates great potential in the field of high specific energy batteries for electrical vehicles, portable electronics, and wearable devices.

Suggested Citation

  • Xu, Nengneng & Zhang, Yanxing & Wang, Yudong & Wang, Min & Su, Tianshun & Coco, Cameron A. & Qiao, Jinli & Zhou, Xiao-Dong, 2020. "Hierarchical bifunctional catalysts with tailored catalytic activity for high-energy rechargeable Zn-air batteries," Applied Energy, Elsevier, vol. 279(C).
    • Handle: RePEc:eee:appene:v:279:y:2020:i:c:s0306261920313477
    DOI: 10.1016/j.apenergy.2020.115876
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    1. Jinyue Yan & Ying Yang & Pietro Elia Campana & Jijiang He, 2019. "City-level analysis of subsidy-free solar photovoltaic electricity price, profits and grid parity in China," Nature Energy, Nature, vol. 4(8), pages 709-717, August.
    2. Wang, Keliang & Pei, Pucheng & Wang, Yichun & Liao, Cheng & Wang, Wei & Huang, Shangwei, 2018. "Advanced rechargeable zinc-air battery with parameter optimization," Applied Energy, Elsevier, vol. 225(C), pages 848-856.
    3. Pei, Pucheng & Huang, Shangwei & Chen, Dongfang & Li, Yuehua & Wu, Ziyao & Ren, Peng & Wang, Keliang & Jia, Xiaoning, 2019. "A high-energy-density and long-stable-performance zinc-air fuel cell system," Applied Energy, Elsevier, vol. 241(C), pages 124-129.
    4. Yuesheng Wang & Jue Liu & Byungju Lee & Ruimin Qiao & Zhenzhong Yang & Shuyin Xu & Xiqian Yu & Lin Gu & Yong-Sheng Hu & Wanli Yang & Kisuk Kang & Hong Li & Xiao-Qing Yang & Liquan Chen & Xuejie Huang, 2015. "Ti-substituted tunnel-type Na0.44MnO2 oxide as a negative electrode for aqueous sodium-ion batteries," Nature Communications, Nature, vol. 6(1), pages 1-10, May.
    5. Yifei Yuan & Chun Zhan & Kun He & Hungru Chen & Wentao Yao & Soroosh Sharifi-Asl & Boao Song & Zhenzhen Yang & Anmin Nie & Xiangyi Luo & Hao Wang & Stephen M. Wood & Khalil Amine & M. Saiful Islam & J, 2016. "The influence of large cations on the electrochemical properties of tunnel-structured metal oxides," Nature Communications, Nature, vol. 7(1), pages 1-9, December.
    6. Tan, P. & Jiang, H.R. & Zhu, X.B. & An, L. & Jung, C.Y. & Wu, M.C. & Shi, L. & Shyy, W. & Zhao, T.S., 2017. "Advances and challenges in lithium-air batteries," Applied Energy, Elsevier, vol. 204(C), pages 780-806.
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    Cited by:

    1. Mechili, Maria & Vaitsis, Christos & Argirusis, Nikolaos & Pandis, Pavlos K. & Sourkouni, Georgia & Argirusis, Christos, 2022. "Research progress in transition metal oxide based bifunctional electrocatalysts for aqueous electrically rechargeable zinc-air batteries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 156(C).
    2. Shang, Wenxu & Yu, Wentao & Xiao, Xu & Ma, Yanyi & Chen, Ziqi & Ni, Meng & Tan, Peng, 2022. "Optimizing the charging protocol to address the self-discharge issues in rechargeable alkaline Zn-Co batteries," Applied Energy, Elsevier, vol. 308(C).
    3. Wei, Manhui & Wang, Keliang & Pei, Pucheng & Zhong, Liping & Züttel, Andreas & Pham, Thi Ha My & Shang, Nuo & Zuo, Yayu & Wang, Hengwei & Zhao, Siyuan, 2023. "Zinc carboxylate optimization strategy for extending Al-air battery system's lifetime," Applied Energy, Elsevier, vol. 350(C).
    4. Pan, Lyuming & Chen, Dongfang & Pei, Pucheng & Huang, Shangwei & Ren, Peng & Song, Xin, 2021. "A novel structural design of air cathodes expanding three-phase reaction interfaces for zinc-air batteries," Applied Energy, Elsevier, vol. 290(C).
    5. Wei, Manhui & Wang, Keliang & Pei, Pucheng & Zuo, Yayu & Zhong, Liping & Shang, Nuo & Wang, Hengwei & Chen, Junfeng & Zhang, Pengfei & Chen, Zhuo, 2022. "An enhanced-performance Al-air battery optimizing the alkaline electrolyte with a strong Lewis acid ZnCl2," Applied Energy, Elsevier, vol. 324(C).

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