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CO2 hydrate heat cycle using a carbon fiber supported catalyst for gas hydrate formation processes

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  • Kawasaki, Toshiyuki
  • Obara, Shin'ya

Abstract

In order to contribute to utilization expansion of unused energy and renewable energy, a heat cycle of the small difference in temperature which used unique dissociation expansion property of CO2 hydrate is proposed. However, the formation speed of CO2 hydrate needs to be accelerated drastic to realize the proposed heat cycle. Therefore, application of a powdery iron oxide catalyst for gas hydrate formation, 150% or more of CO2 hydrate formation speed has realized. On the other hand, the powdery catalyst jumped out of the reactor with high pressure dissociated gas, stability of the catalytic effect was important subject. In this study, the carbon fiber supported catalyst is developed and performance stabilization of CO2 hydrate heat cycle is tried. The effect of the carbon fiber supported catalyst developed newly is comparable as conventional powdery catalyst, and the effect stable in repeating operation of heat cycle is obtained. Moreover, when pressure conditions of the gas hydrate heat cycle were set highly, the generated amount of CO2 hydrate increased from the proposal catalyst system.

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  • Kawasaki, Toshiyuki & Obara, Shin'ya, 2020. "CO2 hydrate heat cycle using a carbon fiber supported catalyst for gas hydrate formation processes," Applied Energy, Elsevier, vol. 269(C).
    • Handle: RePEc:eee:appene:v:269:y:2020:i:c:s0306261920306371
    DOI: 10.1016/j.apenergy.2020.115125
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    References listed on IDEAS

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    Cited by:

    1. Obara, Shin'ya & Tanaka, Ryu, 2021. "Waste heat recovery system for nuclear power plants using the gas hydrate heat cycle," Applied Energy, Elsevier, vol. 292(C).
    2. Park, Joon Ho & Park, Jungjoon & Lee, Jae Won & Kang, Yong Tae, 2023. "Progress in CO2 hydrate formation and feasibility analysis for cold thermal energy harvesting application," Renewable and Sustainable Energy Reviews, Elsevier, vol. 187(C).
    3. Tongu, Daiki & Obara, Shin'ya, 2024. "Formation temperature range expansion and energy storage properties of CO2 hydrates," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    4. Lee, Jae Won & Kim, Seonggon & Torres Pineda, Israel & Kang, Yong Tae, 2021. "Review of nanoabsorbents for capture enhancement of CO2 and its industrial applications with design criteria," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).
    5. Qin, Jiyou & Chinen, Daigo & Obara, Shin'ya, 2022. "Storage and discharge efficiency of small-temperature-difference CO2 hydrate batteries with cyclopentane accelerators," Applied Energy, Elsevier, vol. 308(C).
    6. Kawai, Masahito & Obara, Shin'ya, 2021. "Study on a carbon dioxide hydrate power generation system employing an unstirred reactor with cyclopentane," Energy, Elsevier, vol. 230(C).
    7. Wang, Shuai & Sun, Huilian & Liu, Huiquan & Xi, Dezhi & Long, Jiayi & Zhang, Lunxiang & Zhao, Jiafei & Song, Yongchen & Shi, Changrui & Ling, Zheng, 2024. "Novel vermiculite/tannic acid composite aerogels with outstanding CO2 storage via enhanced gas hydrate formation," Energy, Elsevier, vol. 289(C).
    8. Uemura, Yuta & Kawasaki, Toshiyuki & Obara, Shin’ya, 2021. "Analysis of the performance of an electricity generation system using the CO2 hydrate formation and dissociation process for heat recover," Energy, Elsevier, vol. 218(C).
    9. Obara, Shin'ya, 2023. "Energy storage device based on a hybrid system of a CO2 heat pump cycle and a CO2 hydrate heat cycle," Renewable and Sustainable Energy Reviews, Elsevier, vol. 179(C).

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