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A refractory selective solar absorber for high performance thermochemical steam reforming

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  • Jiang, Dongyue
  • Yang, Wenming
  • Tang, Aikun

Abstract

The production of H2 through steam reforming involves intensive energy consumption. Concentrated solar energy could be employed for the endothermic reaction in the steam reformer to produce H2. However, at high operating temperatures, the solar absorber has huge radiation heat loss to the ambient as the radiation energy is proportional to the fourth power of the surface temperature. In order to avoid the large radiation heat loss and obtain higher surface temperature, here we present a 2D photonic crystal (PhC) solar selective absorber. The selective absorber is made from titanium nitride (TiN) thin film. On top of the TiN thin film, nano cavity array structure and Al2O3 coating are deposited. The absorptivity of the selective absorber is measured at room temperature and the high operating temperature performance is predicted. The fabricated selective absorber is thermal annealed at 800°C for two hours and proves its thermal stability. By comparing the steam reformers with different absorbers (selective absorber and blackbody absorber), the selective absorber shows superior results including higher surface temperature, higher C3H8 conversion rate as well as higher H2 production rate. The experimental and simulation results in this study shows that the 2D PhC solar selective absorber is a good candidate in the steam reforming application for H2 production.

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  • Jiang, Dongyue & Yang, Wenming & Tang, Aikun, 2016. "A refractory selective solar absorber for high performance thermochemical steam reforming," Applied Energy, Elsevier, vol. 170(C), pages 286-292.
    • Handle: RePEc:eee:appene:v:170:y:2016:i:c:p:286-292
    DOI: 10.1016/j.apenergy.2016.02.121
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    5. Fuqiang, Wang & Lanxin, Ma & Ziming, Cheng & Jianyu, Tan & Xing, Huang & Linhua, Liu, 2017. "Radiative heat transfer in solar thermochemical particle reactor: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 935-949.
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