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Characterisation of thermal properties and charging performance of semi-clathrate hydrates for cold storage applications

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  • Wang, Xiaolin
  • Dennis, Mike

Abstract

Thermal storage for air conditioning applications has potential to flatten peak load on electricity grids and improve energy savings of cooling systems. Phase change materials (PCMs) for thermal storage have much greater energy storage density than sensible thermal storage materials. It is proven that semi-clathrate hydrates of tetra-n-butylammonium fluoride (TBAF) can offer appropriate phase change temperatures and rapid formation rates, thus they are considered favourable for cold storage. To demonstrate the feasibility of TBAF hydrate as a cold storage medium, its thermal properties are determined. TBAF aqueous solutions are tested at a mass fraction range of 15–40wt% in the presence or absence of another two quaternary ammonium/phosphonium salts – tetra-n-butylammonium bromide (TBAB) and tetra-n-butylphosphonium bromide (TBPB). The T-history method is employed to determine the enthalpy and heat capacity of the material while the heat diffusion equation is used to obtain the material’s thermal conductivity. The material with the highest formation enthalpy was selected for further analysis. For this material, a model of hydrate formation in a cold storage tube is established using the enthalpy method. By this means, the accumulated cooling capacity and charging rate of the tube is predicted, and the influencing factors on the charging performance are studied. The results indicate that careful selection of the heat transfer fluid (HTF) temperature, tube diameter, thermal conductivity and thickness of the tube wall can all potentially shorten the required charging time of the cold storage tube.

Suggested Citation

  • Wang, Xiaolin & Dennis, Mike, 2016. "Characterisation of thermal properties and charging performance of semi-clathrate hydrates for cold storage applications," Applied Energy, Elsevier, vol. 167(C), pages 59-69.
    • Handle: RePEc:eee:appene:v:167:y:2016:i:c:p:59-69
    DOI: 10.1016/j.apenergy.2016.01.032
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    1. Bi, Yuehong & Guo, Tingwei & Zhang, Liang & Chen, Lingen & Sun, Fengrui, 2010. "Entropy generation minimization for charging and discharging processes in a gas-hydrate cool storage system," Applied Energy, Elsevier, vol. 87(4), pages 1149-1157, April.
    2. Rossi, Federico & Filipponi, Mirko & Castellani, Beatrice, 2012. "Investigation on a novel reactor for gas hydrate production," Applied Energy, Elsevier, vol. 99(C), pages 167-172.
    3. Solé, Aran & Miró, Laia & Barreneche, Camila & Martorell, Ingrid & Cabeza, Luisa F., 2013. "Review of the T-history method to determine thermophysical properties of phase change materials (PCM)," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 425-436.
    4. Kim, Soyoung & Baek, Il-Hyun & You, Jong-Kyun & Seo, Yongwon, 2015. "Guest gas enclathration in tetra-n-butyl ammonium chloride (TBAC) semiclathrates: Potential application to natural gas storage and CO2 capture," Applied Energy, Elsevier, vol. 140(C), pages 107-112.
    5. Wang, Xiaolin & Dennis, Mike & Hou, Liangzhuo, 2014. "Clathrate hydrate technology for cold storage in air conditioning systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 36(C), pages 34-51.
    6. Li, Xiao-Sen & Xu, Chun-Gang & Chen, Zhao-Yang & Wu, Hui-Jie, 2011. "Hydrate-based pre-combustion carbon dioxide capture process in the system with tetra-n-butyl ammonium bromide solution in the presence of cyclopentane," Energy, Elsevier, vol. 36(3), pages 1394-1403.
    7. Bi, Yuehong & Guo, Tingwei & Zhu, Tingying & Fan, Shuanshi & Liang, Deqing & Zhang, Liang, 2004. "Influence of volumetric-flow rate in the crystallizer on the gas-hydrate cool-storage process in a new gas-hydrate cool-storage system," Applied Energy, Elsevier, vol. 78(1), pages 111-121, May.
    8. Shi, X.J. & Zhang, P., 2013. "A comparative study of different methods for the generation of tetra-n-butyl ammonium bromide clathrate hydrate slurry in a cold storage air-conditioning system," Applied Energy, Elsevier, vol. 112(C), pages 1393-1402.
    9. Zhou, H. & de Sera, I.E.E. & Infante Ferreira, C.A., 2015. "Modelling and experimental validation of a fluidized bed based CO2 hydrate cold storage system," Applied Energy, Elsevier, vol. 158(C), pages 433-445.
    10. Chiu, Justin N.W. & Martin, Viktoria, 2012. "Submerged finned heat exchanger latent heat storage design and its experimental verification," Applied Energy, Elsevier, vol. 93(C), pages 507-516.
    11. Kim, Soyoung & Seo, Yongwon, 2015. "Semiclathrate-based CO2 capture from flue gas mixtures: An experimental approach with thermodynamic and Raman spectroscopic analyses," Applied Energy, Elsevier, vol. 154(C), pages 987-994.
    12. Babu, Ponnivalavan & Linga, Praveen & Kumar, Rajnish & Englezos, Peter, 2015. "A review of the hydrate based gas separation (HBGS) process for carbon dioxide pre-combustion capture," Energy, Elsevier, vol. 85(C), pages 261-279.
    13. Veluswamy, Hari Prakash & Kumar, Rajnish & Linga, Praveen, 2014. "Hydrogen storage in clathrate hydrates: Current state of the art and future directions," Applied Energy, Elsevier, vol. 122(C), pages 112-132.
    14. Zhang, P. & Ma, Z.W. & Wang, R.Z., 2010. "An overview of phase change material slurries: MPCS and CHS," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 598-614, February.
    15. Xie, Yingming & Li, Gang & Liu, Daoping & Liu, Ni & Qi, Yingxia & Liang, Deqing & Guo, Kaihua & Fan, Shuanshi, 2010. "Experimental study on a small scale of gas hydrate cold storage apparatus," Applied Energy, Elsevier, vol. 87(11), pages 3340-3346, November.
    16. Xia, Zhi-Ming & Li, Xiao-Sen & Chen, Zhao-Yang & Li, Gang & Yan, Ke-Feng & Xu, Chun-Gang & Lv, Qiu-Nan & Cai, Jing, 2016. "Hydrate-based CO2 capture and CH4 purification from simulated biogas with synergic additives based on gas solvent," Applied Energy, Elsevier, vol. 162(C), pages 1153-1159.
    17. Zhang, P. & Ma, Z.W., 2012. "An overview of fundamental studies and applications of phase change material slurries to secondary loop refrigeration and air conditioning systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5021-5058.
    18. Li, Xiao-Sen & Xu, Chun-Gang & Chen, Zhao-Yang & Wu, Hui-Jie, 2010. "Tetra-n-butyl ammonium bromide semi-clathrate hydrate process for post-combustion capture of carbon dioxide in the presence of dodecyl trimethyl ammonium chloride," Energy, Elsevier, vol. 35(9), pages 3902-3908.
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    Cited by:

    1. Li, Zheng & Zhong, Dong-Liang & Lu, Yi-Yu & Yan, Jin & Zou, Zhen-Lin, 2017. "Preferential enclathration of CO2 into tetra-n-butyl phosphonium bromide semiclathrate hydrate in moderate operating conditions: Application for CO2 capture from shale gas," Applied Energy, Elsevier, vol. 199(C), pages 370-381.
    2. Arnold Martínez & Mauricio Carmona & Cristóbal Cortés & Inmaculada Arauzo, 2020. "Characterization of Thermophysical Properties of Phase Change Materials Using Unconventional Experimental Technologies," Energies, MDPI, vol. 13(18), pages 1-23, September.
    3. Xuan Vien Nguyen, 2021. "Fabrication and Performance Evaluation of Cold Thermal Energy Storage Tanks Operating in Water Chiller Air Conditioning System," Energies, MDPI, vol. 14(14), pages 1-16, July.

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