IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v167y2016icp59-69.html
   My bibliography  Save this article

Characterisation of thermal properties and charging performance of semi-clathrate hydrates for cold storage applications

Author

Listed:
  • Wang, Xiaolin
  • Dennis, Mike

Abstract

Thermal storage for air conditioning applications has potential to flatten peak load on electricity grids and improve energy savings of cooling systems. Phase change materials (PCMs) for thermal storage have much greater energy storage density than sensible thermal storage materials. It is proven that semi-clathrate hydrates of tetra-n-butylammonium fluoride (TBAF) can offer appropriate phase change temperatures and rapid formation rates, thus they are considered favourable for cold storage. To demonstrate the feasibility of TBAF hydrate as a cold storage medium, its thermal properties are determined. TBAF aqueous solutions are tested at a mass fraction range of 15–40wt% in the presence or absence of another two quaternary ammonium/phosphonium salts – tetra-n-butylammonium bromide (TBAB) and tetra-n-butylphosphonium bromide (TBPB). The T-history method is employed to determine the enthalpy and heat capacity of the material while the heat diffusion equation is used to obtain the material’s thermal conductivity. The material with the highest formation enthalpy was selected for further analysis. For this material, a model of hydrate formation in a cold storage tube is established using the enthalpy method. By this means, the accumulated cooling capacity and charging rate of the tube is predicted, and the influencing factors on the charging performance are studied. The results indicate that careful selection of the heat transfer fluid (HTF) temperature, tube diameter, thermal conductivity and thickness of the tube wall can all potentially shorten the required charging time of the cold storage tube.

Suggested Citation

  • Wang, Xiaolin & Dennis, Mike, 2016. "Characterisation of thermal properties and charging performance of semi-clathrate hydrates for cold storage applications," Applied Energy, Elsevier, vol. 167(C), pages 59-69.
    • Handle: RePEc:eee:appene:v:167:y:2016:i:c:p:59-69
    DOI: 10.1016/j.apenergy.2016.01.032
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261916300125
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2016.01.032?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Bi, Yuehong & Guo, Tingwei & Zhang, Liang & Chen, Lingen & Sun, Fengrui, 2010. "Entropy generation minimization for charging and discharging processes in a gas-hydrate cool storage system," Applied Energy, Elsevier, vol. 87(4), pages 1149-1157, April.
    2. Rossi, Federico & Filipponi, Mirko & Castellani, Beatrice, 2012. "Investigation on a novel reactor for gas hydrate production," Applied Energy, Elsevier, vol. 99(C), pages 167-172.
    3. Kim, Soyoung & Baek, Il-Hyun & You, Jong-Kyun & Seo, Yongwon, 2015. "Guest gas enclathration in tetra-n-butyl ammonium chloride (TBAC) semiclathrates: Potential application to natural gas storage and CO2 capture," Applied Energy, Elsevier, vol. 140(C), pages 107-112.
    4. Wang, Xiaolin & Dennis, Mike & Hou, Liangzhuo, 2014. "Clathrate hydrate technology for cold storage in air conditioning systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 36(C), pages 34-51.
    5. Bi, Yuehong & Guo, Tingwei & Zhu, Tingying & Fan, Shuanshi & Liang, Deqing & Zhang, Liang, 2004. "Influence of volumetric-flow rate in the crystallizer on the gas-hydrate cool-storage process in a new gas-hydrate cool-storage system," Applied Energy, Elsevier, vol. 78(1), pages 111-121, May.
    6. Zhou, H. & de Sera, I.E.E. & Infante Ferreira, C.A., 2015. "Modelling and experimental validation of a fluidized bed based CO2 hydrate cold storage system," Applied Energy, Elsevier, vol. 158(C), pages 433-445.
    7. Babu, Ponnivalavan & Linga, Praveen & Kumar, Rajnish & Englezos, Peter, 2015. "A review of the hydrate based gas separation (HBGS) process for carbon dioxide pre-combustion capture," Energy, Elsevier, vol. 85(C), pages 261-279.
    8. Veluswamy, Hari Prakash & Kumar, Rajnish & Linga, Praveen, 2014. "Hydrogen storage in clathrate hydrates: Current state of the art and future directions," Applied Energy, Elsevier, vol. 122(C), pages 112-132.
    9. Xie, Yingming & Li, Gang & Liu, Daoping & Liu, Ni & Qi, Yingxia & Liang, Deqing & Guo, Kaihua & Fan, Shuanshi, 2010. "Experimental study on a small scale of gas hydrate cold storage apparatus," Applied Energy, Elsevier, vol. 87(11), pages 3340-3346, November.
    10. Li, Xiao-Sen & Xu, Chun-Gang & Chen, Zhao-Yang & Wu, Hui-Jie, 2010. "Tetra-n-butyl ammonium bromide semi-clathrate hydrate process for post-combustion capture of carbon dioxide in the presence of dodecyl trimethyl ammonium chloride," Energy, Elsevier, vol. 35(9), pages 3902-3908.
    11. Solé, Aran & Miró, Laia & Barreneche, Camila & Martorell, Ingrid & Cabeza, Luisa F., 2013. "Review of the T-history method to determine thermophysical properties of phase change materials (PCM)," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 425-436.
    12. Li, Xiao-Sen & Xu, Chun-Gang & Chen, Zhao-Yang & Wu, Hui-Jie, 2011. "Hydrate-based pre-combustion carbon dioxide capture process in the system with tetra-n-butyl ammonium bromide solution in the presence of cyclopentane," Energy, Elsevier, vol. 36(3), pages 1394-1403.
    13. Shi, X.J. & Zhang, P., 2013. "A comparative study of different methods for the generation of tetra-n-butyl ammonium bromide clathrate hydrate slurry in a cold storage air-conditioning system," Applied Energy, Elsevier, vol. 112(C), pages 1393-1402.
    14. Chiu, Justin N.W. & Martin, Viktoria, 2012. "Submerged finned heat exchanger latent heat storage design and its experimental verification," Applied Energy, Elsevier, vol. 93(C), pages 507-516.
    15. Kim, Soyoung & Seo, Yongwon, 2015. "Semiclathrate-based CO2 capture from flue gas mixtures: An experimental approach with thermodynamic and Raman spectroscopic analyses," Applied Energy, Elsevier, vol. 154(C), pages 987-994.
    16. Zhang, P. & Ma, Z.W. & Wang, R.Z., 2010. "An overview of phase change material slurries: MPCS and CHS," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 598-614, February.
    17. Xia, Zhi-Ming & Li, Xiao-Sen & Chen, Zhao-Yang & Li, Gang & Yan, Ke-Feng & Xu, Chun-Gang & Lv, Qiu-Nan & Cai, Jing, 2016. "Hydrate-based CO2 capture and CH4 purification from simulated biogas with synergic additives based on gas solvent," Applied Energy, Elsevier, vol. 162(C), pages 1153-1159.
    18. Zhang, P. & Ma, Z.W., 2012. "An overview of fundamental studies and applications of phase change material slurries to secondary loop refrigeration and air conditioning systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5021-5058.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Li, Zheng & Zhong, Dong-Liang & Lu, Yi-Yu & Yan, Jin & Zou, Zhen-Lin, 2017. "Preferential enclathration of CO2 into tetra-n-butyl phosphonium bromide semiclathrate hydrate in moderate operating conditions: Application for CO2 capture from shale gas," Applied Energy, Elsevier, vol. 199(C), pages 370-381.
    2. Xuan Vien Nguyen, 2021. "Fabrication and Performance Evaluation of Cold Thermal Energy Storage Tanks Operating in Water Chiller Air Conditioning System," Energies, MDPI, vol. 14(14), pages 1-16, July.
    3. Arnold Martínez & Mauricio Carmona & Cristóbal Cortés & Inmaculada Arauzo, 2020. "Characterization of Thermophysical Properties of Phase Change Materials Using Unconventional Experimental Technologies," Energies, MDPI, vol. 13(18), pages 1-23, September.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Veluswamy, Hari Prakash & Kumar, Asheesh & Premasinghe, Kulesha & Linga, Praveen, 2017. "Effect of guest gas on the mixed tetrahydrofuran hydrate kinetics in a quiescent system," Applied Energy, Elsevier, vol. 207(C), pages 573-583.
    2. Wang, Xiaolin & Dennis, Mike & Hou, Liangzhuo, 2014. "Clathrate hydrate technology for cold storage in air conditioning systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 36(C), pages 34-51.
    3. Babu, Ponnivalavan & Linga, Praveen & Kumar, Rajnish & Englezos, Peter, 2015. "A review of the hydrate based gas separation (HBGS) process for carbon dioxide pre-combustion capture," Energy, Elsevier, vol. 85(C), pages 261-279.
    4. Kim, Soyoung & Choi, Sung-Deuk & Seo, Yongwon, 2017. "CO2 capture from flue gas using clathrate formation in the presence of thermodynamic promoters," Energy, Elsevier, vol. 118(C), pages 950-956.
    5. Park, Joon Ho & Park, Jungjoon & Lee, Jae Won & Kang, Yong Tae, 2023. "Progress in CO2 hydrate formation and feasibility analysis for cold thermal energy harvesting application," Renewable and Sustainable Energy Reviews, Elsevier, vol. 187(C).
    6. Zheng, Junjie & Bhatnagar, Krittika & Khurana, Maninder & Zhang, Peng & Zhang, Bao-Yong & Linga, Praveen, 2018. "Semiclathrate based CO2 capture from fuel gas mixture at ambient temperature: Effect of concentrations of tetra-n-butylammonium fluoride (TBAF) and kinetic additives," Applied Energy, Elsevier, vol. 217(C), pages 377-389.
    7. Babu, Ponnivalavan & Datta, Stuti & Kumar, Rajnish & Linga, Praveen, 2014. "Impact of experimental pressure and temperature on semiclathrate hydrate formation for pre-combustion capture of CO2 using tetra-n-butyl ammonium nitrate," Energy, Elsevier, vol. 78(C), pages 458-464.
    8. Yang, Mingjun & Jing, Wen & Zhao, Jiafei & Ling, Zheng & Song, Yongchen, 2016. "Promotion of hydrate-based CO2 capture from flue gas by additive mixtures (THF (tetrahydrofuran) + TBAB (tetra-n-butyl ammonium bromide))," Energy, Elsevier, vol. 106(C), pages 546-553.
    9. Wang, Yiwei & Deng, Ye & Guo, Xuqiang & Sun, Qiang & Liu, Aixian & Zhang, Guangqing & Yue, Gang & Yang, Lanying, 2018. "Experimental and modeling investigation on separation of methane from coal seam gas (CSG) using hydrate formation," Energy, Elsevier, vol. 150(C), pages 377-395.
    10. Veluswamy, Hari Prakash & Kumar, Asheesh & Seo, Yutaek & Lee, Ju Dong & Linga, Praveen, 2018. "A review of solidified natural gas (SNG) technology for gas storage via clathrate hydrates," Applied Energy, Elsevier, vol. 216(C), pages 262-285.
    11. Li, Zheng & Zhong, Dong-Liang & Lu, Yi-Yu & Yan, Jin & Zou, Zhen-Lin, 2017. "Preferential enclathration of CO2 into tetra-n-butyl phosphonium bromide semiclathrate hydrate in moderate operating conditions: Application for CO2 capture from shale gas," Applied Energy, Elsevier, vol. 199(C), pages 370-381.
    12. Dong, Hongsheng & Wang, Jiaqi & Xie, Zhuoxue & Wang, Bin & Zhang, Lunxiang & Shi, Quan, 2021. "Potential applications based on the formation and dissociation of gas hydrates," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    13. Bi, Yuehong & Chen, Jie & Miao, Zhen, 2016. "Thermodynamic optimization for dissociation process of gas hydrates," Energy, Elsevier, vol. 106(C), pages 270-276.
    14. Babu, Ponnivalavan & Ong, Hong Wen Nelson & Linga, Praveen, 2016. "A systematic kinetic study to evaluate the effect of tetrahydrofuran on the clathrate process for pre-combustion capture of carbon dioxide," Energy, Elsevier, vol. 94(C), pages 431-442.
    15. Zheng, Junjie & Zhang, Peng & Linga, Praveen, 2017. "Semiclathrate hydrate process for pre-combustion capture of CO2 at near ambient temperatures," Applied Energy, Elsevier, vol. 194(C), pages 267-278.
    16. Lee, Yohan & Lee, Dongyoung & Lee, Jong-Won & Seo, Yongwon, 2016. "Enclathration of CO2 as a co-guest of structure H hydrates and its implications for CO2 capture and sequestration," Applied Energy, Elsevier, vol. 163(C), pages 51-59.
    17. Ma, Fei & Zhang, Peng, 2019. "A review of thermo-fluidic performance and application of shellless phase change slurry: Part 1 – Preparations, properties and applications," Energy, Elsevier, vol. 189(C).
    18. Yang, Mingjun & Song, Yongchen & Jiang, Lanlan & Liu, Weiguo & Dou, Binlin & Jing, Wen, 2014. "Effects of operating mode and pressure on hydrate-based desalination and CO2 capture in porous media," Applied Energy, Elsevier, vol. 135(C), pages 504-511.
    19. Yan, Jin & Lu, Yi-Yu & Zhong, Dong-Liang & Zou, Zhen-Lin & Li, Jian-Bo, 2019. "Enhanced methane recovery from low-concentration coalbed methane by gas hydrate formation in graphite nanofluids," Energy, Elsevier, vol. 180(C), pages 728-736.
    20. Li, Ze-Yu & Xia, Zhi-Ming & Chen, Zhao-Yang & Li, Xiao-Sen & Xu, Chun-Gang & Yan, Ran, 2019. "The plateau effects and crystal transition study in Tetrahydrofuran (THF)/CO2/H2 hydrate formation processes," Applied Energy, Elsevier, vol. 238(C), pages 195-201.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:167:y:2016:i:c:p:59-69. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.