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Characterization of Thermophysical Properties of Phase Change Materials Using Unconventional Experimental Technologies

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  • Arnold Martínez

    (Rational Use of Energy and Environment Preservation Research Group from Universidad del Norte, 081007 Barranquilla, Atlántico, Colombia
    Engineering, Science and Technology—I.C.T Research group from Universidad de Córdoba, 230002 Montería, Córdoba, Colombia)

  • Mauricio Carmona

    (Rational Use of Energy and Environment Preservation Research Group from Universidad del Norte, 081007 Barranquilla, Atlántico, Colombia)

  • Cristóbal Cortés

    (Department of Mechanical Engineering, University of Zaragoza, Campus Río Ebro. Building B. María de Luna s/n, 50018 Zaragoza, Spain)

  • Inmaculada Arauzo

    (Department of Mechanical Engineering, University of Zaragoza, Campus Río Ebro. Building B. María de Luna s/n, 50018 Zaragoza, Spain)

Abstract

The growing interest in developing applications for the storage of thermal energy (TES) is highly linked to the knowledge of the properties of the materials that will be used for that purpose. Likewise, the validity of representing processes through numerical simulations will depend on the accuracy of the thermal properties of the materials. The most relevant properties in the characterization of phase change materials (PCM) are the phase change enthalpy, thermal conductivity, heat capacity and density. Differential scanning calorimetry (DSC) is the most widely used technique for determining thermophysical properties. However, several unconventional methods have been proposed in the literature, mainly due to overcome the limitations of DSC, namely, the small sample required which is unsuitable for studying inhomogeneous materials. This paper presents the characterization of two commercial paraffins commonly used in TES applications, using methods such as T-history and T-melting, which were selected due to their simplicity, high reproducibility, and low cost of implementation. In order to evaluate the reliability of the methods, values calculated with the proposed alternative methods are compared with the results obtained by DSC measurements and with the manufacturer’s technical datasheet. Results obtained show that these non-conventional techniques can be used for the accurate estimation of selected thermal properties. A detailed discussion of the advantage and disadvantage of each method is given.

Suggested Citation

  • Arnold Martínez & Mauricio Carmona & Cristóbal Cortés & Inmaculada Arauzo, 2020. "Characterization of Thermophysical Properties of Phase Change Materials Using Unconventional Experimental Technologies," Energies, MDPI, vol. 13(18), pages 1-23, September.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:18:p:4687-:d:410812
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    References listed on IDEAS

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    1. Wang, Xiaolin & Dennis, Mike, 2016. "Characterisation of thermal properties and charging performance of semi-clathrate hydrates for cold storage applications," Applied Energy, Elsevier, vol. 167(C), pages 59-69.
    2. Cabeza, Luisa F. & Barreneche, Camila & Martorell, Ingrid & Miró, Laia & Sari-Bey, Sana & Fois, Magali & Paksoy, Halime O. & Sahan, Nurten & Weber, Robert & Constantinescu, Mariaella & Anghel, Elena M, 2015. "Unconventional experimental technologies available for phase change materials (PCM) characterization. Part 1. Thermophysical properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1399-1414.
    3. Kravvaritis, E.D. & Antonopoulos, K.A. & Tzivanidis, C., 2011. "Experimental determination of the effective thermal capacity function and other thermal properties for various phase change materials using the thermal delay method," Applied Energy, Elsevier, vol. 88(12), pages 4459-4469.
    4. Xu, Tianhao & Gunasekara, Saman Nimali & Chiu, Justin Ningwei & Palm, Björn & Sawalha, Samer, 2020. "Thermal behavior of a sodium acetate trihydrate-based PCM: T-history and full-scale tests," Applied Energy, Elsevier, vol. 261(C).
    5. Faraj, Khaireldin & Khaled, Mahmoud & Faraj, Jalal & Hachem, Farouk & Castelain, Cathy, 2020. "Phase change material thermal energy storage systems for cooling applications in buildings: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    6. Stanković, Stanislava B. & Kyriacou, Panayiotis A., 2013. "Improved measurement technique for the characterization of organic and inorganic phase change materials using the T-history method," Applied Energy, Elsevier, vol. 109(C), pages 433-440.
    7. Khan, Mohammed Mumtaz A. & Saidur, R. & Al-Sulaiman, Fahad A., 2017. "A review for phase change materials (PCMs) in solar absorption refrigeration systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 105-137.
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