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Photovoltaic and photocatalytic performance study of SOLWAT system for the degradation of Methylene Blue, Acid Red 26 and 4-Chlorophenol

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  • Wang, Zhen
  • Wang, Yiping
  • Vivar, Marta
  • Fuentes, Manuel
  • Zhu, Li
  • Qin, Lianwei

Abstract

The SOLWAT system is a combined system for solar water purification and renewable electricity generation. Its photovoltaic and photocatalytic performance, along with the photovoltaic (PV) electricity production was studied under the degradation of three different pollutants: Methylene Blue, Acid Red 26 and 4-Chlorophenol in present paper. The spectrum loss of the system was analyzed theoretically. Spectral transmittance experiments with different medium were conducted and compared with the results of outdoor experiments. The photovoltaic performance of the SOLWAT system was studied comparatively by measuring the Pm and Isc under actual climatic conditions with a reference PV system. To investigate the photocatalytic performance of the SOLWAT system, the degradation of sample pollutants were detected by analyzing the UV absorption and the TOC. In the presence of the additional wastewater layer, PV cells in the SOLWAT system could work under lower temperature. Depending on the spectral absorption of pollutants, if it is within the spectral response of the PV cell, the electricity output is affected by the pollutant degradation (Methylene Blue, Acid Red 26). When the spectral absorption of pollutant is out of the spectral response of the cell, the PV output is not affected by the contaminant degradation (4-Chlorophenol). The output power of SOLWAT system, though decreased due to the light absorption, was sufficient to drive the whole system. The degradation of sample pollutants was detected by analyzing the UV absorption and the TOC to investigate the photocatalytic performance of the SOLWAT system. For the wastewater with different initial concentrations, the decolorization rate ran up above 99% and the mineralization rate was above 80%.

Suggested Citation

  • Wang, Zhen & Wang, Yiping & Vivar, Marta & Fuentes, Manuel & Zhu, Li & Qin, Lianwei, 2014. "Photovoltaic and photocatalytic performance study of SOLWAT system for the degradation of Methylene Blue, Acid Red 26 and 4-Chlorophenol," Applied Energy, Elsevier, vol. 120(C), pages 1-10.
    • Handle: RePEc:eee:appene:v:120:y:2014:i:c:p:1-10
    DOI: 10.1016/j.apenergy.2014.01.039
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    1. Suganthi, K.S. & Leela Vinodhan, V. & Rajan, K.S., 2014. "Heat transfer performance and transport properties of ZnO–ethylene glycol and ZnO–ethylene glycol–water nanofluid coolants," Applied Energy, Elsevier, vol. 135(C), pages 548-559.
    2. Zhang, Wei & Chen, Miao & Zhang, Shaofeng & Wang, Yiping, 2020. "Designation of a solar falling-film photochemical hybrid system for the decolorization of azo dyes," Energy, Elsevier, vol. 197(C).
    3. Qin, Lianwei & Wang, Yiping & Vivar, Marta & Huang, Qunwu & Zhu, Li & Fuentes, Manuel & Wang, Zhen, 2015. "Comparison of photovoltaic and photocatalytic performance of non-concentrating and V-trough SOLWAT (solar water purification and renewable electricity generation) systems for water purification," Energy, Elsevier, vol. 85(C), pages 251-260.
    4. Wang, Yiping & Jin, Yanchao & Huang, Qunwu & Zhu, Li & Vivar, Marta & Qin, Lianwei & Sun, Yong & Cui, Yong & Cui, Lingyun, 2016. "Photovoltaic and disinfection performance study of a hybrid photovoltaic-solar water disinfection system," Energy, Elsevier, vol. 106(C), pages 757-764.
    5. Yu, Bendong & Hou, Jingxin & He, Wei & Liu, Shanshan & Hu, Zhongting & Ji, Jie & Chen, Hongbing & Xu, Gang, 2018. "Study on a high-performance photocatalytic-Trombe wall system for space heating and air purification," Applied Energy, Elsevier, vol. 226(C), pages 365-380.
    6. Xia, Xiaokang & Gu, Tao & Fan, Miaomiao & Chen, Haifei & Yu, Bendong, 2022. "A novel solar PV/T driven photocatalytic multifunctional system: Concept proposal and performance investigation," Renewable Energy, Elsevier, vol. 196(C), pages 1127-1141.
    7. Yu, Bendong & Yang, Jichun & He, Wei & Qin, Minghui & Zhao, Xudong & Chen, Hongbing, 2019. "The performance analysis of a novel hybrid solar gradient utilization photocatalytic-thermal-catalytic-Trombe wall system," Energy, Elsevier, vol. 174(C), pages 420-435.
    8. Yu, Bendong & Jiang, Qingyang & He, Wei & Liu, Shanshan & Zhou, Fan & Ji, Jie & Xu, Gang & Chen, Hongbing, 2018. "Performance study on a novel hybrid solar gradient utilization system for combined photocatalytic oxidation technology and photovoltaic/thermal technology," Applied Energy, Elsevier, vol. 215(C), pages 699-716.
    9. Pichel, N. & Vivar, M. & Fuentes, M., 2016. "Performance analysis of a solar photovoltaic hybrid system for electricity generation and simultaneous water disinfection of wild bacteria strains," Applied Energy, Elsevier, vol. 171(C), pages 103-112.
    10. Cui, Lingyun & Zhu, Li & Huang, Qunwu & Wang, Yiping & Jin, Yanchao & Sun, Yong & Cui, Yong & Chen, Miao & Fan, Jiangyang, 2017. "Performance analysis of a solar photochemical photovoltaic hybrid system for decolorization of Acid Red 26 (AR 26)," Energy, Elsevier, vol. 127(C), pages 209-217.
    11. Rajput, Usman Jamil & Alhadrami, Hani & Al-Hazmi, Faten & Guo, Quiquan & Yang, Jun, 2017. "Initial investigations of a combined photo-assisted water cleaner and thermal collector," Renewable Energy, Elsevier, vol. 113(C), pages 235-247.
    12. Pichel, N. & Vivar, M. & Fuentes, M., 2021. "Comparative analysis of the SolWat photovoltaic performance regarding different PV technologies and hydraulic retention times," Applied Energy, Elsevier, vol. 292(C).

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