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Dynamic study of methanol adsorption on activated carbon ACM-35.4 for enhancing the specific cooling power of adsorptive chillers

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  • Gordeeva, Larisa
  • Aristov, Yuri

Abstract

Lower specific cooling power (SCP) as compared to absorption and compression chillers slows down a broader application of adsorption cooling (AC) technology. In this paper, we endeavor to find out the factors dominating ad/desorption dynamics in adsorptive chillers and to make practical recommendations on optimizing the SCP. The working pair studied is “activated carbon ACM-35.4 – methanol”. This carbon is the modern analog of a well-known carbon AC-35 that has been widely tested for AC units. We have experimentally examined the dynamics under a simple, but realistic configuration of a thin adsorbent bed composed of loose grains located on a flat metal plate. The effects of the adsorbent grain size (0.8–4.0mm), bed thickness (0.8–5.6mm), and ad/desorption temperatures are explored under conditions of isobaric stages of AC cycle. The adsorption rate appears to be mainly controlled by the heat transfer between the adsorbent bed and the heat transfer fluid. The ratio (S/mad) of the heat transfer area S to the adsorbent mass mad can be used to assess the degree of dynamic perfection of real adsorber – heat exchanger units. On the base of the main findings obtained the practical recommendations on enhancing the SCP of AC units are made.

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  • Gordeeva, Larisa & Aristov, Yuri, 2014. "Dynamic study of methanol adsorption on activated carbon ACM-35.4 for enhancing the specific cooling power of adsorptive chillers," Applied Energy, Elsevier, vol. 117(C), pages 127-133.
    • Handle: RePEc:eee:appene:v:117:y:2014:i:c:p:127-133
    DOI: 10.1016/j.apenergy.2013.11.073
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    7. Gordeeva, Larisa & Frazzica, Andrea & Sapienza, Alessio & Aristov, Yuri & Freni, Angelo, 2014. "Adsorption cooling utilizing the “LiBr/silica – ethanol” working pair: Dynamic optimization of the adsorber/heat exchanger unit," Energy, Elsevier, vol. 75(C), pages 390-399.
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    9. Strelova, S.V. & Aristov, Yu. I. & Gordeeva, L.G., 2023. "Dynamics of water vapour sorption on composite LiCl/(silica gel): An innovative configuration of the adsorbent bed," Energy, Elsevier, vol. 283(C).
    10. Małgorzata Sieradzka & Agata Mlonka-Mędrala & Izabela Kalemba-Rec & Markus Reinmöller & Felix Küster & Wojciech Kalawa & Aneta Magdziarz, 2022. "Evaluation of Physical and Chemical Properties of Residue from Gasification of Biomass Wastes," Energies, MDPI, vol. 15(10), pages 1-19, May.
    11. Girnik, Ilya S. & Aristov, Yuri I., 2016. "Dynamic optimization of adsorptive chillers: The “AQSOA™-FAM-Z02 – Water” working pair," Energy, Elsevier, vol. 106(C), pages 13-22.
    12. Korhammer, Kathrin & Neumann, Karsten & Opel, Oliver & Ruck, Wolfgang K.L., 2018. "Thermodynamic and kinetic study of CaCl2-CH3OH adducts for solid sorption refrigeration by TGA/DSC," Applied Energy, Elsevier, vol. 230(C), pages 1255-1278.
    13. Qadir, Najam ul & Said, S.A.M. & Mansour, R.B. & Imran, Hussain & Khan, Mushtaq, 2020. "Performance comparison of a two-bed solar-driven adsorption chiller with optimal fixed and adaptive cycle times using a silica gel/water working pair," Renewable Energy, Elsevier, vol. 149(C), pages 1000-1017.
    14. N'Tsoukpoe, Kokouvi Edem & Restuccia, Giovanni & Schmidt, Thomas & Py, Xavier, 2014. "The size of sorbents in low pressure sorption or thermochemical energy storage processes," Energy, Elsevier, vol. 77(C), pages 983-998.
    15. Gordeeva, L.G. & Aristov, Yu.I., 2019. "Adsorptive heat storage and amplification: New cycles and adsorbents," Energy, Elsevier, vol. 167(C), pages 440-453.

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