IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v92y2012icp415-420.html
   My bibliography  Save this article

The effect of SO2 on CO2 capture by CaO-based pellets prepared with a kaolin derived Al(OH)3 binder

Author

Listed:
  • Ridha, Firas N.
  • Manovic, Vasilije
  • Macchi, Arturo
  • Anthony, Edward J.

Abstract

High-temperature CO2 capture by Ca looping cycles was investigated in the presence of SO2. The sorbents tested included natural limestone (HV-P), pellets formed from powdered limestone with a binder (HV-AH) and pellets formed from powdered acetified limestone with a binder (HV10-AH). The binder used in pellet preparation was Al(OH)3 obtained from acid leaching of kaolin. Simulated flue gas with a composition of 15% CO2, 3% O2, 0.45% SO2, and N2 balance was used during the CO2 capture step. Two calcination conditions were employed for sorbent regeneration: pure CO2 at 920°C and pure N2 at 850°C. By five reaction cycles, the well-developed porous texture of HV10-AH acetified by 10vol.% acetic acid did not offer better CO2 capture than that for natural limestone at 650°C for calcination in CO2; instead it promoted a higher SO2 retention than that for the limestone. Unfortunately, the CO2 capture capacity for all sorbents calcined in CO2 in the presence of SO2 was effectively eliminated after 2–3 cycles. Calcination in N2 did not significantly enhance CO2 sorbent capture capacity; but instead it improved the SO2 retention ability of HV10-AH, for which the sulphation level was over twice that of the natural limestone. Increasing the carbonation temperature to 700°C enhanced sulphation rather than carbonation with HV10-AH, but produced the opposite effect with natural limestone. In general, it appears that SO2 impedes CO2 capture, leading to a negligible CO2 capture capacity after only few cycles regardless of how the sorbent morphology is modified, which suggests any method designed to improve sorbent performance for CO2 capture will not be proof against significant SO2 concentrations in flue gas. These results suggest that despite the fact that sorbent performance can be influenced to some extent by altering carbonation and calcination conditions; the presence of SO2 must be avoided if the objective is CO2 capture from flue gas.

Suggested Citation

  • Ridha, Firas N. & Manovic, Vasilije & Macchi, Arturo & Anthony, Edward J., 2012. "The effect of SO2 on CO2 capture by CaO-based pellets prepared with a kaolin derived Al(OH)3 binder," Applied Energy, Elsevier, vol. 92(C), pages 415-420.
    • Handle: RePEc:eee:appene:v:92:y:2012:i:c:p:415-420
    DOI: 10.1016/j.apenergy.2011.11.036
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261911007331
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2011.11.036?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Hetland, Jens & Kvamsdal, Hanne Marie & Haugen, Geir & Major, Fredrik & Kårstad, Vemund & Tjellander, Göran, 2009. "Integrating a full carbon capture scheme onto a 450Â MWe NGCC electric power generation hub for offshore operations: Presenting the Sevan GTW concept," Applied Energy, Elsevier, vol. 86(11), pages 2298-2307, November.
    2. Wu, Yinghai & Wang, Chunbo & Tan, Yewen & Jia, Lufei & Anthony, Edward J., 2011. "Characterization of ashes from a 100kWth pilot-scale circulating fluidized bed with oxy-fuel combustion," Applied Energy, Elsevier, vol. 88(9), pages 2940-2948.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wang, Wenjing & Li, Yingjie & Xie, Xin & Sun, Rongyue, 2014. "Effect of the presence of HCl on cyclic CO2 capture of calcium-based sorbent in calcium looping process," Applied Energy, Elsevier, vol. 125(C), pages 246-253.
    2. Erans, María & Jeremias, Michal & Zheng, Liya & Yao, Joseph G. & Blamey, John & Manovic, Vasilije & Fennell, Paul S. & Anthony, Edward J., 2018. "Pilot testing of enhanced sorbents for calcium looping with cement production," Applied Energy, Elsevier, vol. 225(C), pages 392-401.
    3. Tritippayanon, Rattapong & Piemjaiswang, Ratchanon & Piumsomboon, Pornpote & Chalermsinsuwan, Benjapon, 2019. "Computational fluid dynamics of sulfur dioxide and carbon dioxide capture using mixed feeding of calcium carbonate/calcium oxide in an industrial scale circulating fluidized bed boiler," Applied Energy, Elsevier, vol. 250(C), pages 493-502.
    4. Yan Shao & Donglin He & Changlei Qin & Jingyu Ran & Li Zhang, 2017. "SO 2 removal characteristics using waste CaO from calcium looping CO 2 capture process," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 7(4), pages 637-648, August.
    5. Qin, Changlei & Yin, Junjun & Feng, Bo & Ran, Jingyu & Zhang, Li & Manovic, Vasilije, 2016. "Modelling of the calcination behaviour of a uniformly-distributed CuO/CaCO3 particle in Ca–Cu chemical looping," Applied Energy, Elsevier, vol. 164(C), pages 400-410.
    6. Wang, Weilong & Xiao, Jing & Wei, Xiaolan & Ding, Jing & Wang, Xiaoxing & Song, Chunshan, 2014. "Development of a new clay supported polyethylenimine composite for CO2 capture," Applied Energy, Elsevier, vol. 113(C), pages 334-341.
    7. Xiao, Jing & Wu, Luoming & Wu, Ying & Liu, Bing & Dai, Lu & Li, Zhong & Xia, Qibin & Xi, Hongxia, 2014. "Effect of gasoline composition on oxidative desulfurization using a phosphotungstic acid/activated carbon catalyst with hydrogen peroxide," Applied Energy, Elsevier, vol. 113(C), pages 78-85.
    8. Antzaras, Andy N. & Lemonidou, Angeliki A., 2022. "Recent advances on materials and processes for intensified production of blue hydrogen," Renewable and Sustainable Energy Reviews, Elsevier, vol. 155(C).
    9. Erans, María & Manovic, Vasilije & Anthony, Edward J., 2016. "Calcium looping sorbents for CO2 capture," Applied Energy, Elsevier, vol. 180(C), pages 722-742.
    10. Li, Bingyun & Duan, Yuhua & Luebke, David & Morreale, Bryan, 2013. "Advances in CO2 capture technology: A patent review," Applied Energy, Elsevier, vol. 102(C), pages 1439-1447.
    11. Li, Yingjie & Su, Mengying & Xie, Xin & Wu, Shuimu & Liu, Changtian, 2015. "CO2 capture performance of synthetic sorbent prepared from carbide slag and aluminum nitrate hydrate by combustion synthesis," Applied Energy, Elsevier, vol. 145(C), pages 60-68.
    12. Xiaotong Ma & Yingjie Li & Yi Qian & Zeyan Wang, 2019. "A Carbide Slag-Based, Ca 12 Al 14 O 33 -Stabilized Sorbent Prepared by the Hydrothermal Template Method Enabling Efficient CO 2 Capture," Energies, MDPI, vol. 12(13), pages 1-17, July.
    13. Itskos, Grigorios & Grammelis, Panagiotis & Scala, Fabrizio & Pawlak-Kruczek, Halina & Coppola, Antonio & Salatino, Piero & Kakaras, Emmanuel, 2013. "A comparative characterization study of Ca-looping natural sorbents," Applied Energy, Elsevier, vol. 108(C), pages 373-382.
    14. Peng Yang & Zhao Sun & Lunbo Duan & Hongjian Tang, 2020. "Mechanism of steam‐declined sulfation and steam‐enhanced carbonation by DFT calculations," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 10(2), pages 472-483, April.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Oboirien, B.O. & Thulari, V. & North, B.C., 2014. "Major and trace elements in coal bottom ash at different oxy coal combustion conditions," Applied Energy, Elsevier, vol. 129(C), pages 207-216.
    2. Nasvi, M.C.M. & Ranjith, P.G. & Sanjayan, J., 2014. "Effect of different mix compositions on apparent carbon dioxide (CO2) permeability of geopolymer: Suitability as well cement for CO2 sequestration wells," Applied Energy, Elsevier, vol. 114(C), pages 939-948.
    3. Lupiáñez, Carlos & Carmen Mayoral, M. & Díez, Luis I. & Pueyo, Eloy & Espatolero, Sergio & Manuel Andrés, J., 2016. "The role of limestone during fluidized bed oxy-combustion of coal and biomass," Applied Energy, Elsevier, vol. 184(C), pages 670-680.
    4. Duan, Lunbo & Liu, Daoyin & Chen, Xiaoping & Zhao, Changsui, 2012. "Fly ash recirculation by bottom feeding on a circulating fluidized bed boiler co-burning coal sludge and coal," Applied Energy, Elsevier, vol. 95(C), pages 295-299.
    5. Giorgetti, S. & Bricteux, L. & Parente, A. & Blondeau, J. & Contino, F. & De Paepe, W., 2017. "Carbon capture on micro gas turbine cycles: Assessment of the performance on dry and wet operations," Applied Energy, Elsevier, vol. 207(C), pages 243-253.
    6. Orlandini, Valentina & Pierobon, Leonardo & Schløer, Signe & De Pascale, Andrea & Haglind, Fredrik, 2016. "Dynamic performance of a novel offshore power system integrated with a wind farm," Energy, Elsevier, vol. 109(C), pages 236-247.
    7. Xu, Mingxin & Li, Shiyuan & Wu, Yinghai & Jia, Lufei & Lu, Qinggang, 2017. "The characteristics of recycled NO reduction over char during oxy-fuel fluidized bed combustion," Applied Energy, Elsevier, vol. 190(C), pages 553-562.
    8. Rodrigues, A.C.C., 2022. "Decreasing natural gas flaring in Brazilian oil and gas industry," Resources Policy, Elsevier, vol. 77(C).
    9. Guo, Zhihang & Wang, Qinhui & Fang, Mengxiang & Luo, Zhongyang & Cen, Kefa, 2014. "Thermodynamic and economic analysis of polygeneration system integrating atmospheric pressure coal pyrolysis technology with circulating fluidized bed power plant," Applied Energy, Elsevier, vol. 113(C), pages 1301-1314.
    10. Xu, Gang & Yang, Yong-ping & Ding, Jie & Li, Shoucheng & Liu, Wenyi & Zhang, Kai, 2013. "Analysis and optimization of CO2 capture in an existing coal-fired power plant in China," Energy, Elsevier, vol. 58(C), pages 117-127.
    11. Lee, Jaehee & Han, Sang-Jun & Wee, Jung-Ho, 2014. "Synthesis of dry sorbents for carbon dioxide capture using coal fly ash and its performance," Applied Energy, Elsevier, vol. 131(C), pages 40-47.
    12. Seddighi, Sadegh & Clough, Peter T. & Anthony, Edward J. & Hughes, Robin W. & Lu, Ping, 2018. "Scale-up challenges and opportunities for carbon capture by oxy-fuel circulating fluidized beds," Applied Energy, Elsevier, vol. 232(C), pages 527-542.
    13. Jiang, Xi, 2011. "A review of physical modelling and numerical simulation of long-term geological storage of CO2," Applied Energy, Elsevier, vol. 88(11), pages 3557-3566.
    14. Roussanaly, S. & Aasen, A. & Anantharaman, R. & Danielsen, B. & Jakobsen, J. & Heme-De-Lacotte, L. & Neji, G. & Sødal, A. & Wahl, P.E. & Vrana, T.K. & Dreux, R., 2019. "Offshore power generation with carbon capture and storage to decarbonise mainland electricity and offshore oil and gas installations: A techno-economic analysis," Applied Energy, Elsevier, vol. 233, pages 478-494.
    15. Wang, Chang’an & Zhang, Xiaoming & Liu, Yinhe & Che, Defu, 2012. "Pyrolysis and combustion characteristics of coals in oxyfuel combustion," Applied Energy, Elsevier, vol. 97(C), pages 264-273.
    16. Yang, Zhiwei & Khatri, Dishant & Verma, Piyush & Li, Tianxiang & Adeosun, Adewale & Kumfer, Benjamin M. & Axelbaum, Richard L., 2021. "Experimental study and demonstration of pilot-scale, dry feed, oxy-coal combustion under pressure," Applied Energy, Elsevier, vol. 285(C).
    17. Cruz, Matheus de Andrade & Brigagão, George Victor & de Medeiros, José Luiz & Musse, Ana Paula Santana & Kami, Eduardo & Freire, Ronaldo Lucas Alkmin & Araújo, Ofélia de Queiroz Fernandes, 2023. "Decarbonization of energy supply to offshore oil & gas production with post-combustion capture: A simulation-based techno-economic analysis," Energy, Elsevier, vol. 274(C).
    18. Tan, Y. & Jia, L. & Wu, Y. & Anthony, E.J., 2012. "Experiences and results on a 0.8MWth oxy-fuel operation pilot-scale circulating fluidized bed," Applied Energy, Elsevier, vol. 92(C), pages 343-347.
    19. Campanari, Stefano & Manzolini, Giampaolo & Chiesa, Paolo, 2013. "Using MCFC for high efficiency CO2 capture from natural gas combined cycles: Comparison of internal and external reforming," Applied Energy, Elsevier, vol. 112(C), pages 772-783.
    20. Vidoza, Jorge A. & Andreasen, Jesper Graa & Haglind, Fredrik & dos Reis, Max M.L. & Gallo, Waldyr, 2019. "Design and optimization of power hubs for Brazilian off-shore oil production units," Energy, Elsevier, vol. 176(C), pages 656-666.

    More about this item

    Keywords

    CO2 capture; Limestone; Ca-looping; Ca-based sorbent; SO2;
    All these keywords.

    JEL classification:

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:92:y:2012:i:c:p:415-420. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.