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The effect of SO2 on CO2 capture by CaO-based pellets prepared with a kaolin derived Al(OH)3 binder

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  • Ridha, Firas N.
  • Manovic, Vasilije
  • Macchi, Arturo
  • Anthony, Edward J.

Abstract

High-temperature CO2 capture by Ca looping cycles was investigated in the presence of SO2. The sorbents tested included natural limestone (HV-P), pellets formed from powdered limestone with a binder (HV-AH) and pellets formed from powdered acetified limestone with a binder (HV10-AH). The binder used in pellet preparation was Al(OH)3 obtained from acid leaching of kaolin. Simulated flue gas with a composition of 15% CO2, 3% O2, 0.45% SO2, and N2 balance was used during the CO2 capture step. Two calcination conditions were employed for sorbent regeneration: pure CO2 at 920°C and pure N2 at 850°C. By five reaction cycles, the well-developed porous texture of HV10-AH acetified by 10vol.% acetic acid did not offer better CO2 capture than that for natural limestone at 650°C for calcination in CO2; instead it promoted a higher SO2 retention than that for the limestone. Unfortunately, the CO2 capture capacity for all sorbents calcined in CO2 in the presence of SO2 was effectively eliminated after 2–3 cycles. Calcination in N2 did not significantly enhance CO2 sorbent capture capacity; but instead it improved the SO2 retention ability of HV10-AH, for which the sulphation level was over twice that of the natural limestone. Increasing the carbonation temperature to 700°C enhanced sulphation rather than carbonation with HV10-AH, but produced the opposite effect with natural limestone. In general, it appears that SO2 impedes CO2 capture, leading to a negligible CO2 capture capacity after only few cycles regardless of how the sorbent morphology is modified, which suggests any method designed to improve sorbent performance for CO2 capture will not be proof against significant SO2 concentrations in flue gas. These results suggest that despite the fact that sorbent performance can be influenced to some extent by altering carbonation and calcination conditions; the presence of SO2 must be avoided if the objective is CO2 capture from flue gas.

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  • Ridha, Firas N. & Manovic, Vasilije & Macchi, Arturo & Anthony, Edward J., 2012. "The effect of SO2 on CO2 capture by CaO-based pellets prepared with a kaolin derived Al(OH)3 binder," Applied Energy, Elsevier, vol. 92(C), pages 415-420.
    • Handle: RePEc:eee:appene:v:92:y:2012:i:c:p:415-420
    DOI: 10.1016/j.apenergy.2011.11.036
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    1. Hetland, Jens & Kvamsdal, Hanne Marie & Haugen, Geir & Major, Fredrik & Kårstad, Vemund & Tjellander, Göran, 2009. "Integrating a full carbon capture scheme onto a 450Â MWe NGCC electric power generation hub for offshore operations: Presenting the Sevan GTW concept," Applied Energy, Elsevier, vol. 86(11), pages 2298-2307, November.
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    1. Yan Shao & Donglin He & Changlei Qin & Jingyu Ran & Li Zhang, 2017. "SO 2 removal characteristics using waste CaO from calcium looping CO 2 capture process," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 7(4), pages 637-648, August.
    2. Qin, Changlei & Yin, Junjun & Feng, Bo & Ran, Jingyu & Zhang, Li & Manovic, Vasilije, 2016. "Modelling of the calcination behaviour of a uniformly-distributed CuO/CaCO3 particle in Ca–Cu chemical looping," Applied Energy, Elsevier, vol. 164(C), pages 400-410.
    3. Li, Bingyun & Duan, Yuhua & Luebke, David & Morreale, Bryan, 2013. "Advances in CO2 capture technology: A patent review," Applied Energy, Elsevier, vol. 102(C), pages 1439-1447.
    4. Li, Yingjie & Su, Mengying & Xie, Xin & Wu, Shuimu & Liu, Changtian, 2015. "CO2 capture performance of synthetic sorbent prepared from carbide slag and aluminum nitrate hydrate by combustion synthesis," Applied Energy, Elsevier, vol. 145(C), pages 60-68.
    5. Xiaotong Ma & Yingjie Li & Yi Qian & Zeyan Wang, 2019. "A Carbide Slag-Based, Ca 12 Al 14 O 33 -Stabilized Sorbent Prepared by the Hydrothermal Template Method Enabling Efficient CO 2 Capture," Energies, MDPI, vol. 12(13), pages 1-17, July.
    6. Itskos, Grigorios & Grammelis, Panagiotis & Scala, Fabrizio & Pawlak-Kruczek, Halina & Coppola, Antonio & Salatino, Piero & Kakaras, Emmanuel, 2013. "A comparative characterization study of Ca-looping natural sorbents," Applied Energy, Elsevier, vol. 108(C), pages 373-382.
    7. Wang, Wenjing & Li, Yingjie & Xie, Xin & Sun, Rongyue, 2014. "Effect of the presence of HCl on cyclic CO2 capture of calcium-based sorbent in calcium looping process," Applied Energy, Elsevier, vol. 125(C), pages 246-253.
    8. Erans, María & Jeremias, Michal & Zheng, Liya & Yao, Joseph G. & Blamey, John & Manovic, Vasilije & Fennell, Paul S. & Anthony, Edward J., 2018. "Pilot testing of enhanced sorbents for calcium looping with cement production," Applied Energy, Elsevier, vol. 225(C), pages 392-401.
    9. Tritippayanon, Rattapong & Piemjaiswang, Ratchanon & Piumsomboon, Pornpote & Chalermsinsuwan, Benjapon, 2019. "Computational fluid dynamics of sulfur dioxide and carbon dioxide capture using mixed feeding of calcium carbonate/calcium oxide in an industrial scale circulating fluidized bed boiler," Applied Energy, Elsevier, vol. 250(C), pages 493-502.
    10. Wang, Weilong & Xiao, Jing & Wei, Xiaolan & Ding, Jing & Wang, Xiaoxing & Song, Chunshan, 2014. "Development of a new clay supported polyethylenimine composite for CO2 capture," Applied Energy, Elsevier, vol. 113(C), pages 334-341.
    11. Xiao, Jing & Wu, Luoming & Wu, Ying & Liu, Bing & Dai, Lu & Li, Zhong & Xia, Qibin & Xi, Hongxia, 2014. "Effect of gasoline composition on oxidative desulfurization using a phosphotungstic acid/activated carbon catalyst with hydrogen peroxide," Applied Energy, Elsevier, vol. 113(C), pages 78-85.
    12. Antzaras, Andy N. & Lemonidou, Angeliki A., 2022. "Recent advances on materials and processes for intensified production of blue hydrogen," Renewable and Sustainable Energy Reviews, Elsevier, vol. 155(C).
    13. Erans, María & Manovic, Vasilije & Anthony, Edward J., 2016. "Calcium looping sorbents for CO2 capture," Applied Energy, Elsevier, vol. 180(C), pages 722-742.
    14. Peng Yang & Zhao Sun & Lunbo Duan & Hongjian Tang, 2020. "Mechanism of steam‐declined sulfation and steam‐enhanced carbonation by DFT calculations," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 10(2), pages 472-483, April.

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    More about this item

    Keywords

    CO2 capture; Limestone; Ca-looping; Ca-based sorbent; SO2;
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