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Bifunctional hole-shuttle molecule for improved interfacial energy level alignment and defect passivation in perovskite solar cells

Author

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  • Shuai You

    (Huazhong University of Science and Technology
    École Polytechnique Fédérale de Lausanne (EPFL))

  • Felix T. Eickemeyer

    (École Polytechnique Fédérale de Lausanne (EPFL))

  • Jing Gao

    (École Polytechnique Fédérale de Lausanne (EPFL))

  • Jun-Ho Yum

    (École Polytechnique Fédérale de Lausanne (EPFL))

  • Xin Zheng

    (Huazhong University of Science and Technology)

  • Dan Ren

    (École Polytechnique Fédérale de Lausanne (EPFL))

  • Meng Xia

    (École Polytechnique Fédérale de Lausanne (EPFL))

  • Rui Guo

    (Huazhong University of Science and Technology)

  • Yaoguang Rong

    (Huazhong University of Science and Technology)

  • Shaik M. Zakeeruddin

    (École Polytechnique Fédérale de Lausanne (EPFL))

  • Kevin Sivula

    (École Polytechnique Fédérale de Lausanne (EPFL))

  • Jiang Tang

    (Huazhong University of Science and Technology)

  • Zhongjin Shen

    (École Polytechnique Fédérale de Lausanne (EPFL))

  • Xiong Li

    (Huazhong University of Science and Technology)

  • Michael Grätzel

    (École Polytechnique Fédérale de Lausanne (EPFL))

Abstract

Perovskite solar cells have reached a power conversion efficiency over 25%, and the engineering of the interface between the perovskite and hole transport layer (HTL) has been crucial to achieve high performance. Here we design a bifunctional molecule CBz-PAI with carbazole-triphenylamine and phenylammonium iodide units to passivate defects at the perovskite/HTL interface. Owing to a favourable energy level alignment with the perovskite, the CBz-PAI acts as a hole shuttle between the perovskite layer and the HTL. This minimizes the difference between the quasi-Fermi level splitting of the perovskite, or ‘internal’ Voc, and the external device Voc, thus reducing voltage losses. As a result, solar cells incorporating CBz-PAI reach a stabilized power conversion efficiency of 24.7% and maintain 92.3% of the initial efficiency after 1,000 h under damp heat test (85 °C and 85% relative humidity) and 94.6% after 1,100 h under maximum power point-tracking conditions.

Suggested Citation

  • Shuai You & Felix T. Eickemeyer & Jing Gao & Jun-Ho Yum & Xin Zheng & Dan Ren & Meng Xia & Rui Guo & Yaoguang Rong & Shaik M. Zakeeruddin & Kevin Sivula & Jiang Tang & Zhongjin Shen & Xiong Li & Micha, 2023. "Bifunctional hole-shuttle molecule for improved interfacial energy level alignment and defect passivation in perovskite solar cells," Nature Energy, Nature, vol. 8(5), pages 515-525, May.
    • Handle: RePEc:nat:natene:v:8:y:2023:i:5:d:10.1038_s41560-023-01249-0
    DOI: 10.1038/s41560-023-01249-0
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    2. Zihan Qu & Yang Zhao & Fei Ma & Le Mei & Xian-Kai Chen & Haitao Zhou & Xinbo Chu & Yingguo Yang & Qi Jiang & Xingwang Zhang & Jingbi You, 2024. "Enhanced charge carrier transport and defects mitigation of passivation layer for efficient perovskite solar cells," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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