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Intact 2D/3D halide junction perovskite solar cells via solid-phase in-plane growth

Author

Listed:
  • Yeoun-Woo Jang

    (Seoul National University
    Seoul National University)

  • Seungmin Lee

    (Korea University)

  • Kyung Mun Yeom

    (Korea University)

  • Kiwan Jeong

    (Seoul National University)

  • Kwang Choi

    (Korea University)

  • Mansoo Choi

    (Seoul National University
    Seoul National University)

  • Jun Hong Noh

    (Korea University
    Korea University)

Abstract

The solution process has been employed to obtain Ruddlesden–Popper two-dimensional/three-dimensional (2D/3D) halide perovskite bilayers in perovskite solar cells for improving the efficiency and chemical stability; however, the solution process has limitations in achieving thermal stability and designing a proper local electric field for efficient carrier collection due to the formation of a metastable quasi-2D perovskite. Here we grow a stable and highly crystalline 2D (C4H9NH3)2PbI4 film on top of a 3D film using a solvent-free solid-phase in-plane growth, which could result in an intact 2D/3D heterojunction. An enhanced built-in potential is achieved at the 2D/3D heterojunction with a thick 2D film, resulting in high photovoltage in the device. The intact 2D/3D heterojunction endow the devices with an open-circuit voltage of 1.185 V and a certified steady-state efficiency of 24.35%. The encapsulated device retained 94% of its initial efficiency after 1,056 h under the damp heat test (85 °C/85% relative humidity) and 98% after 1,620 h under full-sun illumination.

Suggested Citation

  • Yeoun-Woo Jang & Seungmin Lee & Kyung Mun Yeom & Kiwan Jeong & Kwang Choi & Mansoo Choi & Jun Hong Noh, 2021. "Intact 2D/3D halide junction perovskite solar cells via solid-phase in-plane growth," Nature Energy, Nature, vol. 6(1), pages 63-71, January.
    • Handle: RePEc:nat:natene:v:6:y:2021:i:1:d:10.1038_s41560-020-00749-7
    DOI: 10.1038/s41560-020-00749-7
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    1. Jiangang Feng & Xi Wang & Jia Li & Haoming Liang & Wen Wen & Ezra Alvianto & Cheng-Wei Qiu & Rui Su & Yi Hou, 2023. "Resonant perovskite solar cells with extended band edge," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    2. Giovanni Pica & Lorenzo Pancini & Christopher E. Petoukhoff & Badri Vishal & Francesco Toniolo & Changzeng Ding & Young-Kwang Jung & Mirko Prato & Nada Mrkyvkova & Peter Siffalovic & Stefaan De Wolf &, 2024. "Photo-ferroelectric perovskite interfaces for boosting VOC in efficient perovskite solar cells," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. Zhuang Zhang & Huanhuan Wang & T. Jesper Jacobsson & Jingshan Luo, 2022. "Big data driven perovskite solar cell stability analysis," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    4. Jiajia Suo & Bowen Yang & Edoardo Mosconi & Dmitry Bogachuk & Tiarnan A. S. Doherty & Kyle Frohna & Dominik J. Kubicki & Fan Fu & YeonJu Kim & Oussama Er-Raji & Tiankai Zhang & Lorenzo Baldinelli & Lu, 2024. "Multifunctional sulfonium-based treatment for perovskite solar cells with less than 1% efficiency loss over 4,500-h operational stability tests," Nature Energy, Nature, vol. 9(2), pages 172-183, February.
    5. Fengtao Pei & Yihua Chen & Qianqian Wang & Liang Li & Yue Ma & Huifen Liu & Ye Duan & Tinglu Song & Haipeng Xie & Guilin Liu & Ning Yang & Ying Zhang & Wentao Zhou & Jiaqian Kang & Xiuxiu Niu & Kailin, 2024. "A binary 2D perovskite passivation for efficient and stable perovskite/silicon tandem solar cells," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    6. Shuai You & Felix T. Eickemeyer & Jing Gao & Jun-Ho Yum & Xin Zheng & Dan Ren & Meng Xia & Rui Guo & Yaoguang Rong & Shaik M. Zakeeruddin & Kevin Sivula & Jiang Tang & Zhongjin Shen & Xiong Li & Micha, 2023. "Bifunctional hole-shuttle molecule for improved interfacial energy level alignment and defect passivation in perovskite solar cells," Nature Energy, Nature, vol. 8(5), pages 515-525, May.
    7. Weichuan Zhang & Ziyuan Liu & Lizhi Zhang & Hui Wang & Chuanxiu Jiang & Xianxin Wu & Chuanyun Li & Shengli Yue & Rongsheng Yang & Hong Zhang & Jianqi Zhang & Xinfeng Liu & Yuan Zhang & Huiqiong Zhou, 2024. "Ultrastable and efficient slight-interlayer-displacement 2D Dion-Jacobson perovskite solar cells," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    8. Tinghuan Yang & Lili Gao & Jing Lu & Chuang Ma & Yachao Du & Peijun Wang & Zicheng Ding & Shiqiang Wang & Peng Xu & Dongle Liu & Haojin Li & Xiaoming Chang & Junjie Fang & Wenming Tian & Yingguo Yang , 2023. "One-stone-for-two-birds strategy to attain beyond 25% perovskite solar cells," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    9. Liangliang Min & Haoxuan Sun & Linqi Guo & Meng Wang & Fengren Cao & Jun Zhong & Liang Li, 2024. "Frequency-selective perovskite photodetector for anti-interference optical communications," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    10. Kyung Mun Yeom & Changsoon Cho & Eui Hyuk Jung & Geunjin Kim & Chan Su Moon & So Yeon Park & Su Hyun Kim & Mun Young Woo & Mohammed Nabaz Taher Khayyat & Wanhee Lee & Nam Joong Jeon & Miguel Anaya & S, 2024. "Quantum barriers engineering toward radiative and stable perovskite photovoltaic devices," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

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