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Quantum barriers engineering toward radiative and stable perovskite photovoltaic devices

Author

Listed:
  • Kyung Mun Yeom

    (Korea University)

  • Changsoon Cho

    (University of Cambridge
    Pohang University of Science and Technology (POSTECH)
    Yonsei University)

  • Eui Hyuk Jung

    (Korea Institute of Energy Technology (KENTECH))

  • Geunjin Kim

    (Korea Research Institute of Chemical Technology (KRICT))

  • Chan Su Moon

    (Korea University
    Korea Research Institute of Chemical Technology (KRICT))

  • So Yeon Park

    (Korea University
    National Renewable Energy Laboratory)

  • Su Hyun Kim

    (Korea University)

  • Mun Young Woo

    (Korea University)

  • Mohammed Nabaz Taher Khayyat

    (Korea University)

  • Wanhee Lee

    (Pohang University of Science and Technology (POSTECH))

  • Nam Joong Jeon

    (Korea Research Institute of Chemical Technology (KRICT))

  • Miguel Anaya

    (University of Cambridge)

  • Samuel D. Stranks

    (University of Cambridge
    University of Cambridge)

  • Richard H. Friend

    (University of Cambridge)

  • Neil C. Greenham

    (University of Cambridge)

  • Jun Hong Noh

    (Korea University
    Korea University
    Korea University)

Abstract

Efficient photovoltaic devices must be efficient light emitters to reach the thermodynamic efficiency limit. Here, we present a promising prospect of perovskite photovoltaics as bright emitters by harnessing the significant benefits of photon recycling, which can be practically achieved by suppressing interfacial quenching. We have achieved radiative and stable perovskite photovoltaic devices by the design of a multiple quantum well structure with long (∼3 nm) organic spacers with oleylammonium molecules at perovskite top interfaces. Our L-site exchange process (L: barrier molecule cation) enables the formation of stable interfacial structures with moderate conductivity despite the thick barriers. Compared to popular short (∼1 nm) Ls, our approach results in enhanced radiation efficiency through the recursive process of photon recycling. This leads to the realization of radiative perovskite photovoltaics with both high photovoltaic efficiency (in-lab 26.0%, certified to 25.2%) and electroluminescence quantum efficiency (19.7 % at peak, 17.8% at 1-sun equivalent condition). Furthermore, the stable crystallinity of oleylammonium-based quantum wells enables our devices to maintain high efficiencies for over 1000 h of operation and >2 years of storage.

Suggested Citation

  • Kyung Mun Yeom & Changsoon Cho & Eui Hyuk Jung & Geunjin Kim & Chan Su Moon & So Yeon Park & Su Hyun Kim & Mun Young Woo & Mohammed Nabaz Taher Khayyat & Wanhee Lee & Nam Joong Jeon & Miguel Anaya & S, 2024. "Quantum barriers engineering toward radiative and stable perovskite photovoltaic devices," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-48887-w
    DOI: 10.1038/s41467-024-48887-w
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    1. Fengtao Pei & Yihua Chen & Qianqian Wang & Liang Li & Yue Ma & Huifen Liu & Ye Duan & Tinglu Song & Haipeng Xie & Guilin Liu & Ning Yang & Ying Zhang & Wentao Zhou & Jiaqian Kang & Xiuxiu Niu & Kailin, 2024. "A binary 2D perovskite passivation for efficient and stable perovskite/silicon tandem solar cells," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

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