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Defect passivation in hybrid perovskite solar cells using quaternary ammonium halide anions and cations

Author

Listed:
  • Xiaopeng Zheng

    (University of Nebraska-Lincoln)

  • Bo Chen

    (University of Nebraska-Lincoln)

  • Jun Dai

    (University of Nebraska-Lincoln)

  • Yanjun Fang

    (University of Nebraska-Lincoln)

  • Yang Bai

    (University of Nebraska-Lincoln)

  • Yuze Lin

    (University of Nebraska-Lincoln)

  • Haotong Wei

    (University of Nebraska-Lincoln)

  • Xiao Cheng Zeng

    (University of Nebraska-Lincoln)

  • Jinsong Huang

    (University of Nebraska-Lincoln
    University of North Carolina)

Abstract

The ionic defects at the surfaces and grain boundaries of organic–inorganic halide perovskite films are detrimental to both the efficiency and stability of perovskite solar cells. Here, we show that quaternary ammonium halides can effectively passivate ionic defects in several different types of hybrid perovskite with their negative- and positive-charged components. The efficient defect passivation reduces the charge trap density and elongates the carrier recombination lifetime, which is supported by density-function-theory calculation. The defect passivation reduces the open-circuit-voltage deficit of the p–i–n-structured device to 0.39 V, and boosts the efficiency to a certified value of 20.59 ± 0.45%. Moreover, the defect healing also significantly enhances the stability of films in ambient conditions. Our findings provide an avenue for defect passivation to further improve both the efficiency and stability of solar cells.

Suggested Citation

  • Xiaopeng Zheng & Bo Chen & Jun Dai & Yanjun Fang & Yang Bai & Yuze Lin & Haotong Wei & Xiao Cheng Zeng & Jinsong Huang, 2017. "Defect passivation in hybrid perovskite solar cells using quaternary ammonium halide anions and cations," Nature Energy, Nature, vol. 2(7), pages 1-9, July.
    • Handle: RePEc:nat:natene:v:2:y:2017:i:7:d:10.1038_nenergy.2017.102
    DOI: 10.1038/nenergy.2017.102
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    Cited by:

    1. Yehui Wen & Tianchi Zhang & Xingtao Wang & Tiantian Liu & Yu Wang & Rui Zhang & Miao Kan & Li Wan & Weihua Ning & Yong Wang & Deren Yang, 2024. "Amorphous (lysine)2PbI2 layer enhanced perovskite photovoltaics," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    2. Paolo Mariani & Miguel Ángel Molina-García & Jessica Barichello & Marilena Isabella Zappia & Erica Magliano & Luigi Angelo Castriotta & Luca Gabatel & Sanjay Balkrishna Thorat & Antonio Esaú Rio Casti, 2024. "Low-temperature strain-free encapsulation for perovskite solar cells and modules passing multifaceted accelerated ageing tests," Nature Communications, Nature, vol. 15(1), pages 1-15, December.
    3. Stefania Cacovich & Guillaume Vidon & Matteo Degani & Marie Legrand & Laxman Gouda & Jean-Baptiste Puel & Yana Vaynzof & Jean-François Guillemoles & Daniel Ory & Giulia Grancini, 2022. "Imaging and quantifying non-radiative losses at 23% efficient inverted perovskite solar cells interfaces," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    4. Guus J. W. Aalbers & Tom P. A. Pol & Kunal Datta & Willemijn H. M. Remmerswaal & Martijn M. Wienk & René A. J. Janssen, 2024. "Effect of sub-bandgap defects on radiative and non-radiative open-circuit voltage losses in perovskite solar cells," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    5. Peng Jin & Yingjie Tang & Dingwei Li & Yan Wang & Peng Ran & Chuanyu Zhou & Ye Yuan & Wenjuan Zhu & Tianyu Liu & Kun Liang & Cuifang Kuang & Xu Liu & Bowen Zhu & Yang (Michael) Yang, 2023. "Realizing nearly-zero dark current and ultrahigh signal-to-noise ratio perovskite X-ray detector and image array by dark-current-shunting strategy," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    6. Dhruba B. Khadka & Yasuhiro Shirai & Masatoshi Yanagida & Hitoshi Ota & Andrey Lyalin & Tetsuya Taketsugu & Kenjiro Miyano, 2024. "Defect passivation in methylammonium/bromine free inverted perovskite solar cells using charge-modulated molecular bonding," Nature Communications, Nature, vol. 15(1), pages 1-16, December.
    7. Chenxu Zhao & Zhiwen Zhou & Masaud Almalki & Michael A. Hope & Jiashang Zhao & Thibaut Gallet & Anurag Krishna & Aditya Mishra & Felix T. Eickemeyer & Jia Xu & Yingguo Yang & Shaik M. Zakeeruddin & Al, 2024. "Stabilization of highly efficient perovskite solar cells with a tailored supramolecular interface," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    8. Rashmi Mehrotra & Dongrak Oh & Ji-Wook Jang, 2021. "Unassisted selective solar hydrogen peroxide production by an oxidised buckypaper-integrated perovskite photocathode," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    9. Chee, A. Kuan-Way, 2023. "On current technology for light absorber materials used in highly efficient industrial solar cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 173(C).
    10. Marwa. S. Salem & Ahmed Shaker & Abdelhalim Zekry & Mohamed Abouelatta & Adwan Alanazi & Mohammad T. Alshammari & Christian Gontand, 2021. "Analysis of Hybrid Hetero-Homo Junction Lead-Free Perovskite Solar Cells by SCAPS Simulator," Energies, MDPI, vol. 14(18), pages 1-22, September.
    11. M. Mottakin & K. Sobayel & Dilip Sarkar & Hend Alkhammash & Sami Alharthi & Kuaanan Techato & Md. Shahiduzzaman & Nowshad Amin & Kamaruzzaman Sopian & Md. Akhtaruzzaman, 2021. "Design and Modelling of Eco-Friendly CH 3 NH 3 SnI 3 -Based Perovskite Solar Cells with Suitable Transport Layers," Energies, MDPI, vol. 14(21), pages 1-16, November.
    12. Omar M. Saif & Yasmine Elogail & Tarek M. Abdolkader & Ahmed Shaker & Abdelhalim Zekry & Mohamed Abouelatta & Marwa S. Salem & Mostafa Fedawy, 2023. "Comprehensive Review on Thin Film Homojunction Solar Cells: Technologies, Progress and Challenges," Energies, MDPI, vol. 16(11), pages 1-23, May.
    13. Shuai You & Felix T. Eickemeyer & Jing Gao & Jun-Ho Yum & Xin Zheng & Dan Ren & Meng Xia & Rui Guo & Yaoguang Rong & Shaik M. Zakeeruddin & Kevin Sivula & Jiang Tang & Zhongjin Shen & Xiong Li & Micha, 2023. "Bifunctional hole-shuttle molecule for improved interfacial energy level alignment and defect passivation in perovskite solar cells," Nature Energy, Nature, vol. 8(5), pages 515-525, May.
    14. Md Aslam Uddin & Prem Jyoti Singh Rana & Zhenyi Ni & Guang Yang & Mingze Li & Mengru Wang & Hangyu Gu & Hengkai Zhang & Benjia Dak Dou & Jinsong Huang, 2024. "Iodide manipulation using zinc additives for efficient perovskite solar minimodules," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    15. Tinghuan Yang & Lili Gao & Jing Lu & Chuang Ma & Yachao Du & Peijun Wang & Zicheng Ding & Shiqiang Wang & Peng Xu & Dongle Liu & Haojin Li & Xiaoming Chang & Junjie Fang & Wenming Tian & Yingguo Yang , 2023. "One-stone-for-two-birds strategy to attain beyond 25% perovskite solar cells," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    16. Hobeom Kim & So-Min Yoo & Bin Ding & Hiroyuki Kanda & Naoyuki Shibayama & Maria A. Syzgantseva & Farzaneh Fadaei Tirani & Pascal Schouwink & Hyung Joong Yun & Byoungchul Son & Yong Ding & Beom-Soo Kim, 2024. "Shallow-level defect passivation by 6H perovskite polytype for highly efficient and stable perovskite solar cells," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    17. Zihan Qu & Yang Zhao & Fei Ma & Le Mei & Xian-Kai Chen & Haitao Zhou & Xinbo Chu & Yingguo Yang & Qi Jiang & Xingwang Zhang & Jingbi You, 2024. "Enhanced charge carrier transport and defects mitigation of passivation layer for efficient perovskite solar cells," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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