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Efficient n-i-p Monolithic Perovskite/Silicon Tandem Solar Cells with Tin Oxide via a Chemical Bath Deposition Method

Author

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  • Jiyeon Hyun

    (Department of Materials Science and Engineering, Korea University, 145, Anam-ro, Seongbuk-gu, Seoul 02841, Korea)

  • Kyung Mun Yeom

    (School of Civil, Environmental and Architectural Engineering, Korea University, 145, Anam-ro, Seongbuk-gu, Seoul 02841, Korea)

  • Ha Eun Lee

    (Department of Materials Science and Engineering, Korea University, 145, Anam-ro, Seongbuk-gu, Seoul 02841, Korea)

  • Donghwan Kim

    (Department of Materials Science and Engineering, Korea University, 145, Anam-ro, Seongbuk-gu, Seoul 02841, Korea)

  • Hae-Seok Lee

    (KU-KIST Green School Graduate School of Energy and Environment, Korea University, 145, Anam-ro, Seongbuk-gu, Seoul 02841, Korea)

  • Jun Hong Noh

    (School of Civil, Environmental and Architectural Engineering, Korea University, 145, Anam-ro, Seongbuk-gu, Seoul 02841, Korea)

  • Yoonmook Kang

    (KU-KIST Green School Graduate School of Energy and Environment, Korea University, 145, Anam-ro, Seongbuk-gu, Seoul 02841, Korea)

Abstract

Tandem solar cells, based on perovskite and crystalline silicon absorbers, are promising candidates for commercial applications. Tin oxide (SnO 2 ), applied via the spin-coating method, has been among the most used electron transfer layers in normal (n-i-p) perovskite/silicon tandem cells. SnO 2 synthesized by chemical bath deposition (CBD) has not yet been applied in tandem devices. This method shows improved efficiency in perovskite single cells and allows for deposition over a larger area. Our study is the first to apply low-temperature processed SnO 2 via CBD to a homojunction silicon solar cell without additional deposition of a recombination layer. By controlling the reaction time, a tandem efficiency of 16.9% was achieved. This study shows that tandem implementation is possible through the CBD method, and demonstrates the potential of this method in commercial application to textured silicon surfaces with large areas.

Suggested Citation

  • Jiyeon Hyun & Kyung Mun Yeom & Ha Eun Lee & Donghwan Kim & Hae-Seok Lee & Jun Hong Noh & Yoonmook Kang, 2021. "Efficient n-i-p Monolithic Perovskite/Silicon Tandem Solar Cells with Tin Oxide via a Chemical Bath Deposition Method," Energies, MDPI, vol. 14(22), pages 1-10, November.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:22:p:7614-:d:679268
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    References listed on IDEAS

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    Cited by:

    1. Jianqin Li & Feng Wen & Shenghao Wang, 2023. "Perovskite Tandem Solar Cell Technologies," Energies, MDPI, vol. 16(4), pages 1-3, February.

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