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Modulation of triplet quantum coherence by guest-induced structural changes in a flexible metal-organic framework

Author

Listed:
  • Akio Yamauchi

    (Kyushu University)

  • Saiya Fujiwara

    (Kyushu University)

  • Nobuo Kimizuka

    (Kyushu University
    Kyushu University)

  • Mizue Asada

    (Institute for Molecular Science)

  • Motoyasu Fujiwara

    (Institute for Molecular Science)

  • Toshikazu Nakamura

    (Institute for Molecular Science)

  • Jenny Pirillo

    (Nagoya University)

  • Yuh Hijikata

    (Nagoya university)

  • Nobuhiro Yanai

    (Kyushu University
    Kyushu University
    JST
    The University of Tokyo)

Abstract

Quantum sensing has the potential to improve the sensitivity of chemical sensing by exploiting the characteristics of qubits, which are sensitive to the external environment. Modulation of quantum coherence by target analytes can be a useful tool for quantum sensing. Using molecular qubits is expected to provide excellent sensitivity due to the proximity of the sensor to the target analyte. However, many molecular qubits are used at cryogenic temperatures, and how to make molecular qubits respond to specific analytes remains unclear. Here, we propose a material design in which the coherence time changes in response to a variety of analytes at room temperature. We used the photoexcited triplet, which can be initialized at room temperature, as qubits and introduce them to a metal–organic framework that can flexibly change its pore structure in response to guest adsorption. By changing the local molecular density around the triplet qubits by adsorption of a specific analyte, the mobility of the triplet qubit can be changed, and the coherence time can be made responsive.

Suggested Citation

  • Akio Yamauchi & Saiya Fujiwara & Nobuo Kimizuka & Mizue Asada & Motoyasu Fujiwara & Toshikazu Nakamura & Jenny Pirillo & Yuh Hijikata & Nobuhiro Yanai, 2024. "Modulation of triplet quantum coherence by guest-induced structural changes in a flexible metal-organic framework," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51715-w
    DOI: 10.1038/s41467-024-51715-w
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    References listed on IDEAS

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