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Embedded nano spin sensor for in situ probing of gas adsorption inside porous organic frameworks

Author

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  • Jie Zhang

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Linshan Liu

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences)

  • Chaofeng Zheng

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Wang Li

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences)

  • Chunru Wang

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences)

  • Taishan Wang

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences)

Abstract

Spin-based sensors have attracted considerable attention owing to their high sensitivities. Herein, we developed a metallofullerene-based nano spin sensor to probe gas adsorption within porous organic frameworks. For this, spin-active metallofullerene, Sc3C2@C80, was selected and embedded into a nanopore of a pyrene-based covalent organic framework (Py-COF). Electron paramagnetic resonance (EPR) spectroscopy recorded the EPR signals of Sc3C2@C80 within Py-COF after adsorbing N2, CO, CH4, CO2, C3H6, and C3H8. Results indicated that the regularly changing EPR signals of embedded Sc3C2@C80 were associated with the gas adsorption performance of Py-COF. In contrast to traditional adsorption isotherm measurements, this implantable nano spin sensor could probe gas adsorption and desorption with in situ, real-time monitoring. The proposed nano spin sensor was also employed to probe the gas adsorption performance of a metal–organic framework (MOF-177), demonstrating its versatility. The nano spin sensor is thus applicable for quantum sensing and precision measurements.

Suggested Citation

  • Jie Zhang & Linshan Liu & Chaofeng Zheng & Wang Li & Chunru Wang & Taishan Wang, 2023. "Embedded nano spin sensor for in situ probing of gas adsorption inside porous organic frameworks," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-40683-2
    DOI: 10.1038/s41467-023-40683-2
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    2. Laigang Hu & Wenhao Wu & Min Hu & Ling Jiang & Daohui Lin & Jian Wu & Kun Yang, 2024. "Double-walled Al-based MOF with large microporous specific surface area for trace benzene adsorption," Nature Communications, Nature, vol. 15(1), pages 1-8, December.

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