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Direct synthesis of controllable ultrathin heteroatoms-intercalated 2D layered materials

Author

Listed:
  • Qianqian He

    (Beihang University
    Beihang University)

  • Kunpeng Si

    (Beihang University
    Center for Micro-Nano Innovation of Beihang University)

  • Zian Xu

    (Beihang University)

  • Xingguo Wang

    (Beihang University)

  • Chunqiao Jin

    (Beihang University
    Tianmushan Laboratory Xixi Octagon City)

  • Yahan Yang

    (Beihang University
    Center for Micro-Nano Innovation of Beihang University)

  • Juntian Wei

    (Beihang University
    Center for Micro-Nano Innovation of Beihang University)

  • Lingjia Meng

    (Beijing University of Technology)

  • Pengbo Zhai

    (Beihang University
    Tianmushan Laboratory Xixi Octagon City)

  • Peng Zhang

    (Beihang University)

  • Peizhe Tang

    (Beihang University
    Max Planck Institute for the Structure and Dynamics of Matter)

  • Yongji Gong

    (Beihang University
    Center for Micro-Nano Innovation of Beihang University
    Tianmushan Laboratory Xixi Octagon City)

Abstract

Two-dimensional (2D) layered materials have been studied in depth during the past two decades due to their unique structure and properties. Transition metal (TM) intercalation of layered materials have been proven as an effective way to introduce new physical properties, such as tunable 2D magnetism, but the direct growth of atomically thin heteroatoms-intercalated layered materials remains untapped. Herein, we directly synthesize various ultrathin heteroatoms-intercalated 2D layered materials (UHI-2DMs) through flux-assisted growth (FAG) approach. Eight UHI-2DMs (V1/3NbS2, Cr1/3NbS2, Mn1/3NbS2, Fe1/3NbS2, Co1/3NbS2, Co1/3NbSe2, Fe1/3TaS2, Fe1/4TaS2) were successfully synthesized. Their thickness can be reduced to the thinnest limit (bilayer 2D material with monolayer intercalated TM), and magnetic ordering can be induced in the synthesized structures. Interestingly, due to the possible anisotropy-stabilized long-range ferromagnetism in Fe1/3TaS2 with weak interlayer coupling, the layer-independent magnetic ordering temperature of Fe1/3TaS2 was revealed by magneto-transport properties. This work establishes a general method for direct synthesis of heteroatom-intercalated ultrathin 2D materials with tunable chemical and physical properties.

Suggested Citation

  • Qianqian He & Kunpeng Si & Zian Xu & Xingguo Wang & Chunqiao Jin & Yahan Yang & Juntian Wei & Lingjia Meng & Pengbo Zhai & Peng Zhang & Peizhe Tang & Yongji Gong, 2024. "Direct synthesis of controllable ultrathin heteroatoms-intercalated 2D layered materials," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-50694-2
    DOI: 10.1038/s41467-024-50694-2
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