IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-37406-y.html
   My bibliography  Save this article

Atomic-thick metastable phase RhMo nanosheets for hydrogen oxidation catalysis

Author

Listed:
  • Juntao Zhang

    (Xiamen University)

  • Xiaozhi Liu

    (Institute of Physics, Chinese Academy of Sciences)

  • Yujin Ji

    (Soochow University)

  • Xuerui Liu

    (Beijing University of Chemical Technology)

  • Dong Su

    (Institute of Physics, Chinese Academy of Sciences)

  • Zhongbin Zhuang

    (Beijing University of Chemical Technology)

  • Yu-Chung Chang

    (National Synchrotron Radiation Research Center)

  • Chih-Wen Pao

    (National Synchrotron Radiation Research Center)

  • Qi Shao

    (Soochow University)

  • Zhiwei Hu

    (Max Planck Institute for Chemical Physics of Solids)

  • Xiaoqing Huang

    (Xiamen University)

Abstract

Metastable phase two-dimensional catalysts provide great flexibility for modifying their chemical, physical, and electronic properties. However, the synthesis of ultrathin metastable phase two-dimensional metallic nanomaterials is highly challenging, mainly due to the anisotropic nature of metallic materials and their thermodynamically unstable ground-state. Here, we report free-standing RhMo nanosheets with atomic thickness and a unique core/shell (metastable phase/stable phase) structure. The polymorphic interface between the core region and shell region stabilizes and activates metastable phase catalysts; the RhMo Nanosheets/C shows excellent hydrogen oxidation activity and stability. Specifically, the mass activities of RhMo Nanosheets/C is 6.96 A mgRh−1; this is 21.09 times higher than that of commercial Pt/C (0.33 A mgPt−1). Density functional theory calculations suggest that the interface aids in the dissociation of H2 and the H species can then spillover to weak H binding sites for desorption, providing excellent hydrogen oxidation activity for RhMo nanosheets. This work advances the highly controlled synthesis of two-dimensional metastable phase noble metals and provides great directions for the design of high-performance catalysts for fuel cells and beyond.

Suggested Citation

  • Juntao Zhang & Xiaozhi Liu & Yujin Ji & Xuerui Liu & Dong Su & Zhongbin Zhuang & Yu-Chung Chang & Chih-Wen Pao & Qi Shao & Zhiwei Hu & Xiaoqing Huang, 2023. "Atomic-thick metastable phase RhMo nanosheets for hydrogen oxidation catalysis," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37406-y
    DOI: 10.1038/s41467-023-37406-y
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-37406-y
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-023-37406-y?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Yanrong Xue & Lin Shi & Xuerui Liu & Jinjie Fang & Xingdong Wang & Brian P. Setzler & Wei Zhu & Yushan Yan & Zhongbin Zhuang, 2020. "A highly-active, stable and low-cost platinum-free anode catalyst based on RuNi for hydroxide exchange membrane fuel cells," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    2. Jaeyoung Hong & Jee-Hwan Bae & Hyesung Jo & Hee-Young Park & Sehyun Lee & Sung Jun Hong & Hoje Chun & Min Kyung Cho & Juyoung Kim & Joodeok Kim & Yongju Son & Haneul Jin & Jin-Yoo Suh & Sung-Chul Kim , 2022. "Metastable hexagonal close-packed palladium hydride in liquid cell TEM," Nature, Nature, vol. 603(7902), pages 631-636, March.
    3. Ziliang Ye & Ting Cao & Kevin O’Brien & Hanyu Zhu & Xiaobo Yin & Yuan Wang & Steven G. Louie & Xiang Zhang, 2014. "Probing excitonic dark states in single-layer tungsten disulphide," Nature, Nature, vol. 513(7517), pages 214-218, September.
    4. Haohong Duan & Ning Yan & Rong Yu & Chun-Ran Chang & Gang Zhou & Han-Shi Hu & Hongpan Rong & Zhiqiang Niu & Junjie Mao & Hiroyuki Asakura & Tsunehiro Tanaka & Paul Joseph Dyson & Jun Li & Yadong Li, 2014. "Ultrathin rhodium nanosheets," Nature Communications, Nature, vol. 5(1), pages 1-8, May.
    5. K. S. Novoselov & A. K. Geim & S. V. Morozov & D. Jiang & M. I. Katsnelson & I. V. Grigorieva & S. V. Dubonos & A. A. Firsov, 2005. "Two-dimensional gas of massless Dirac fermions in graphene," Nature, Nature, vol. 438(7065), pages 197-200, November.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Yanyan Fang & Cong Wei & Zenan Bian & Xuanwei Yin & Bo Liu & Zhaohui Liu & Peng Chi & Junxin Xiao & Wanjie Song & Shuwen Niu & Chongyang Tang & Jun Liu & Xiaolin Ge & Tongwen Xu & Gongming Wang, 2024. "Unveiling the nature of Pt-induced anti-deactivation of Ru for alkaline hydrogen oxidation reaction," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Qiqi Mao & Xu Mu & Wenxin Wang & Kai Deng & Hongjie Yu & Ziqiang Wang & You Xu & Liang Wang & Hongjing Wang, 2023. "Atomically dispersed Cu coordinated Rh metallene arrays for simultaneously electrochemical aniline synthesis and biomass upgrading," Nature Communications, Nature, vol. 14(1), pages 1-12, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Anh-Luan Phan & Dai-Nam Le, 2021. "Electronic transport in two-dimensional strained Dirac materials under multi-step Fermi velocity barrier: transfer matrix method for supersymmetric systems," The European Physical Journal B: Condensed Matter and Complex Systems, Springer;EDP Sciences, vol. 94(8), pages 1-16, August.
    2. Di Molfetta, Giuseppe & Brachet, Marc & Debbasch, Fabrice, 2014. "Quantum walks in artificial electric and gravitational fields," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 397(C), pages 157-168.
    3. Dasari, Bhagya Lakshmi & Nouri, Jamshid M. & Brabazon, Dermot & Naher, Sumsun, 2017. "Graphene and derivatives – Synthesis techniques, properties and their energy applications," Energy, Elsevier, vol. 140(P1), pages 766-778.
    4. Zhongzhe Wei & Zijiang Zhao & Chenglong Qiu & Songtao Huang & Zihao Yao & Mingxuan Wang & Yi Chen & Yue Lin & Xing Zhong & Xiaonian Li & Jianguo Wang, 2023. "Tripodal Pd metallenes mediated by Nb2C MXenes for boosting alkynes semihydrogenation," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    5. M. T. Greenaway & P. Kumaravadivel & J. Wengraf & L. A. Ponomarenko & A. I. Berdyugin & J. Li & J. H. Edgar & R. Krishna Kumar & A. K. Geim & L. Eaves, 2021. "Graphene’s non-equilibrium fermions reveal Doppler-shifted magnetophonon resonances accompanied by Mach supersonic and Landau velocity effects," Nature Communications, Nature, vol. 12(1), pages 1-6, December.
    6. Maria Karaulova & Abdullah Gök & Oliver Shackleton & Philip Shapira, 2016. "Science system path-dependencies and their influences: nanotechnology research in Russia," Scientometrics, Springer;Akadémiai Kiadó, vol. 107(2), pages 645-670, May.
    7. Zheyu Cheng & Yi-Jun Guan & Haoran Xue & Yong Ge & Ding Jia & Yang Long & Shou-Qi Yuan & Hong-Xiang Sun & Yidong Chong & Baile Zhang, 2024. "Three-dimensional flat Landau levels in an inhomogeneous acoustic crystal," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    8. Ying Zhou & Hongqian Mu & Tongbiao Wang & Tianbao Yu & Qinghua Liao, 2022. "Tunable broadband superradiance near a graphene/hyperbolic metamaterial/graphene sandwich structure," The European Physical Journal B: Condensed Matter and Complex Systems, Springer;EDP Sciences, vol. 95(11), pages 1-10, November.
    9. Xuefei Liu & Zhaocai Zhang & Bing Lv & Zhao Ding & Zijiang Luo, 2021. "Impact of the vertical strain on the Schottky barrier height for graphene/AlN heterojunction: a study by the first-principles method," The European Physical Journal B: Condensed Matter and Complex Systems, Springer;EDP Sciences, vol. 94(1), pages 1-7, January.
    10. Xingdong Wang & Xuerui Liu & Jinjie Fang & Houpeng Wang & Xianwei Liu & Haiyong Wang & Chengjin Chen & Yongsheng Wang & Xuejiang Zhang & Wei Zhu & Zhongbin Zhuang, 2024. "Tuning the apparent hydrogen binding energy to achieve high-performance Ni-based hydrogen oxidation reaction catalyst," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    11. Lijun Zhu & Xiaoqiang Liu & Lin Li & Xinyi Wan & Ran Tao & Zhongniu Xie & Ji Feng & Changgan Zeng, 2023. "Signature of quantum interference effect in inter-layer Coulomb drag in graphene-based electronic double-layer systems," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    12. Yonggang Zuo & Can Liu & Liping Ding & Ruixi Qiao & Jinpeng Tian & Chang Liu & Qinghe Wang & Guodong Xue & Yilong You & Quanlin Guo & Jinhuan Wang & Ying Fu & Kehai Liu & Xu Zhou & Hao Hong & Muhong W, 2022. "Robust growth of two-dimensional metal dichalcogenides and their alloys by active chalcogen monomer supply," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    13. Anna M. Seiler & Nils Jacobsen & Martin Statz & Noelia Fernandez & Francesca Falorsi & Kenji Watanabe & Takashi Taniguchi & Zhiyu Dong & Leonid S. Levitov & R. Thomas Weitz, 2024. "Probing the tunable multi-cone band structure in Bernal bilayer graphene," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    14. Wenjun Cui & Weixiao Lin & Weichao Lu & Chengshan Liu & Zhixiao Gao & Hao Ma & Wen Zhao & Gustaaf Tendeloo & Wenyu Zhao & Qingjie Zhang & Xiahan Sang, 2023. "Direct observation of cation diffusion driven surface reconstruction at van der Waals gaps," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    15. Xiaoling Sun & Kun Ding, 2018. "Identifying and tracking scientific and technological knowledge memes from citation networks of publications and patents," Scientometrics, Springer;Akadémiai Kiadó, vol. 116(3), pages 1735-1748, September.
    16. Andreas Sinner & Gregor Tkachov, 2022. "Diffusive transport in the lowest Landau level of disordered 2d semimetals: the mean-square-displacement approach," The European Physical Journal B: Condensed Matter and Complex Systems, Springer;EDP Sciences, vol. 95(6), pages 1-17, June.
    17. Nauman Javed, Rana Muhammad & Al-Othman, Amani & Tawalbeh, Muhammad & Olabi, Abdul Ghani, 2022. "Recent developments in graphene and graphene oxide materials for polymer electrolyte membrane fuel cells applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    18. Saroj B. Chand & John M. Woods & Jiamin Quan & Enrique Mejia & Takashi Taniguchi & Kenji Watanabe & Andrea Alù & Gabriele Grosso, 2023. "Interaction-driven transport of dark excitons in 2D semiconductors with phonon-mediated optical readout," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    19. Yiwen Zhang & Bo Xie & Yue Yang & Yueshen Wu & Xin Lu & Yuxiong Hu & Yifan Ding & Jiadian He & Peng Dong & Jinghui Wang & Xiang Zhou & Jianpeng Liu & Zhu-Jun Wang & Jun Li, 2024. "Extremely large magnetoresistance in twisted intertwined graphene spirals," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    20. Zihe Gao & Haoqi Zhao & Tianwei Wu & Xilin Feng & Zhifeng Zhang & Xingdu Qiao & Ching-Kai Chiu & Liang Feng, 2023. "Topological quadratic-node semimetal in a photonic microring lattice," Nature Communications, Nature, vol. 14(1), pages 1-8, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37406-y. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.