IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-45262-7.html
   My bibliography  Save this article

Visualizing the interfacial-layer-based epitaxial growth process toward organic core-shell architectures

Author

Listed:
  • Ming-Peng Zhuo

    (Soochow University
    Technical Institute of Physics and Chemistry Chinese Academy of Sciences
    Soochow University)

  • Xiao Wei

    (Technical Institute of Physics and Chemistry Chinese Academy of Sciences)

  • Yuan-Yuan Li

    (Soochow University
    Soochow University)

  • Ying-Li Shi

    (Soochow University)

  • Guang-Peng He

    (Soochow University)

  • Huixue Su

    (Technical Institute of Physics and Chemistry Chinese Academy of Sciences)

  • Ke-Qin Zhang

    (Soochow University)

  • Jin-Ping Guan

    (Soochow University)

  • Xue-Dong Wang

    (Soochow University)

  • Yuchen Wu

    (Technical Institute of Physics and Chemistry Chinese Academy of Sciences)

  • Liang-Sheng Liao

    (Soochow University
    Macau University of Science and Technology)

Abstract

Organic heterostructures (OHTs) with the desired geometry organization on micro/nanoscale have undergone rapid progress in nanoscience and nanotechnology. However, it is a significant challenge to elucidate the epitaxial-growth process for various OHTs composed of organic units with a lattice mismatching ratio of > 3%, which is unimaginable for inorganic heterostructures. Herein, we have demonstrated a vivid visualization of the morphology evolution of epitaxial-growth based on a doped interfacial-layer, which facilitates the comprehensive understanding of the hierarchical self-assembly of core-shell OHT with precise spatial configuration. Significantly, the barcoded OHT with periodic shells obviously illustrate the shell epitaxial-growth from tips to center parts along the seeded rods for forming the core-shell OHT. Furthermore, the diameter, length, and number of periodic shells were modulated by finely tuning the stoichiometric ratio, crystalline time, and temperature, respectively. This epitaxial-growth process could be generalized to organic systems with facile chemical/structural compatibility for forming the desired OHTs.

Suggested Citation

  • Ming-Peng Zhuo & Xiao Wei & Yuan-Yuan Li & Ying-Li Shi & Guang-Peng He & Huixue Su & Ke-Qin Zhang & Jin-Ping Guan & Xue-Dong Wang & Yuchen Wu & Liang-Sheng Liao, 2024. "Visualizing the interfacial-layer-based epitaxial growth process toward organic core-shell architectures," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-45262-7
    DOI: 10.1038/s41467-024-45262-7
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-45262-7
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-45262-7?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Ming-Peng Zhuo & Jun-Jie Wu & Xue-Dong Wang & Yi-Chen Tao & Yi Yuan & Liang-Sheng Liao, 2019. "Hierarchical self-assembly of organic heterostructure nanowires," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    2. Lincoln J. Lauhon & Mark S. Gudiksen & Deli Wang & Charles M. Lieber, 2002. "Epitaxial core–shell and core–multishell nanowire heterostructures," Nature, Nature, vol. 420(6911), pages 57-61, November.
    3. Bozhi Tian & Xiaolin Zheng & Thomas J. Kempa & Ying Fang & Nanfang Yu & Guihua Yu & Jinlin Huang & Charles M. Lieber, 2007. "Coaxial silicon nanowires as solar cells and nanoelectronic power sources," Nature, Nature, vol. 449(7164), pages 885-889, October.
    4. Ming-Peng Zhuo & Guang-Peng He & Xue-Dong Wang & Liang-Sheng Liao, 2021. "Organic superstructure microwires with hierarchical spatial organisation," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    5. Thangavel Kanagasekaran & Hidekazu Shimotani & Ryota Shimizu & Taro Hitosugi & Katsumi Tanigaki, 2017. "A new electrode design for ambipolar injection in organic semiconductors," Nature Communications, Nature, vol. 8(1), pages 1-7, December.
    6. Dario M. Bassani, 2011. "Molecular wires get connected," Nature, Nature, vol. 480(7377), pages 326-327, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ying-Xin Ma & Xue-Dong Wang, 2024. "Directional self-assembly of organic vertically superposed nanowires," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wenqing Xu & Guanheng Huang & Zhan Yang & Ziqi Deng & Chen Zhou & Jian-An Li & Ming-De Li & Tao Hu & Ben Zhong Tang & David Lee Phillips, 2024. "Nucleic-acid-base photofunctional cocrystal for information security and antimicrobial applications," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    2. Li Zhai & Sara T. Gebre & Bo Chen & Dan Xu & Junze Chen & Zijian Li & Yawei Liu & Hua Yang & Chongyi Ling & Yiyao Ge & Wei Zhai & Changsheng Chen & Lu Ma & Qinghua Zhang & Xuefei Li & Yujie Yan & Xiny, 2023. "Epitaxial growth of highly symmetrical branched noble metal-semiconductor heterostructures with efficient plasmon-induced hot-electron transfer," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Ying-Xin Ma & Xue-Dong Wang, 2024. "Directional self-assembly of organic vertically superposed nanowires," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    4. Yinan Huang & Kunjie Wu & Yajing Sun & Yongxu Hu & Zhongwu Wang & Liqian Yuan & Shuguang Wang & Deyang Ji & Xiaotao Zhang & Huanli Dong & Zhongmiao Gong & Zhiyun Li & Xuefei Weng & Rong Huang & Yi Cui, 2024. "Unraveling the crucial role of trace oxygen in organic semiconductors," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    5. Sharifi, Farrokh & Ghobadian, Sasan & Cavalcanti, Flavia R. & Hashemi, Nastaran, 2015. "Paper-based devices for energy applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 1453-1472.
    6. Subham Ranjan & Avulu Vinod Kumar & Rajadurai Chandrasekar & Satoshi Takamizawa, 2024. "Spatially controllable and mechanically switchable isomorphous organoferroeleastic crystal optical waveguides and networks," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    7. Hsin-Cheng Lee & Shich-Chuan Wu & Tien-Chung Yang & Ta-Jen Yen, 2010. "Efficiently Harvesting Sun Light for Silicon Solar Cells through Advanced Optical Couplers and A Radial p-n Junction Structure," Energies, MDPI, vol. 3(4), pages 1-19, April.
    8. Fengjing Liu & Xinming Zhuang & Mingxu Wang & Dongqing Qi & Shengpan Dong & SenPo Yip & Yanxue Yin & Jie Zhang & Zixu Sa & Kepeng Song & Longbing He & Yang Tan & You Meng & Johnny C. Ho & Lei Liao & F, 2023. "Lattice-mismatch-free construction of III-V/chalcogenide core-shell heterostructure nanowires," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    9. Xiaohua Liu & Yongjing Lin & Sa Zhou & Stafford Sheehan & Dunwei Wang, 2010. "Complex Nanostructures: Synthesis and Energetic Applications," Energies, MDPI, vol. 3(3), pages 1-16, February.
    10. Qiang Lv & Xue-Dong Wang & Yue Yu & Ming-Peng Zhuo & Min Zheng & Liang-Sheng Liao, 2022. "Lattice-mismatch-free growth of organic heterostructure nanowires from cocrystals to alloys," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    11. Sen Gao & Sanghyun Hong & Soohyung Park & Hyun Young Jung & Wentao Liang & Yonghee Lee & Chi Won Ahn & Ji Young Byun & Juyeon Seo & Myung Gwan Hahm & Hyehee Kim & Kiwoong Kim & Yeonjin Yi & Hailong Wa, 2022. "Catalyst-free synthesis of sub-5 nm silicon nanowire arrays with massive lattice contraction and wide bandgap," Nature Communications, Nature, vol. 13(1), pages 1-9, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-45262-7. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.