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Spatially controllable and mechanically switchable isomorphous organoferroeleastic crystal optical waveguides and networks

Author

Listed:
  • Subham Ranjan

    (Kanazawa-ku)

  • Avulu Vinod Kumar

    (University of Hyderabad)

  • Rajadurai Chandrasekar

    (University of Hyderabad)

  • Satoshi Takamizawa

    (Kanazawa-ku)

Abstract

The precise, reversible, and diffusionless shape-switching ability of organic ferroelastic crystals, while maintaining their structural integrity, positions them as promising materials for next-generation hybrid photonic devices. Herein, we present versatile bi-directional ferroelasticity and optical waveguide properties of three isomorphous, halogen-based, Schiff base organic crystals. These crystals exhibit sharp bending at multiple interfaces driven by molecular movement around the CH = N bond and subsequent 180° rotational twinning, offering controlled light path manipulation. The ferroelastic nature of these crystals allowed the construction of robust hybrid photonic structures, including Z-shaped configurations, closed-loop networks, and staircase-like hybrid optical waveguides. This study highlights the potential of shape-switchable organoferroelastic crystals as waveguides for applications in programmable photonic devices.

Suggested Citation

  • Subham Ranjan & Avulu Vinod Kumar & Rajadurai Chandrasekar & Satoshi Takamizawa, 2024. "Spatially controllable and mechanically switchable isomorphous organoferroeleastic crystal optical waveguides and networks," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51504-5
    DOI: 10.1038/s41467-024-51504-5
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    References listed on IDEAS

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    1. Xuesong Yang & Linfeng Lan & Liang Li & Xiaokong Liu & Panče Naumov & Hongyu Zhang, 2022. "Remote and precise control over morphology and motion of organic crystals by using magnetic field," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    2. Xuesong Yang & Linfeng Lan & Xiuhong Pan & Qi Di & Xiaokong Liu & Liang Li & Panče Naumov & Hongyu Zhang, 2023. "Bioinspired soft robots based on organic polymer-crystal hybrid materials with response to temperature and humidity," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    3. Ming-Peng Zhuo & Jun-Jie Wu & Xue-Dong Wang & Yi-Chen Tao & Yi Yuan & Liang-Sheng Liao, 2019. "Hierarchical self-assembly of organic heterostructure nanowires," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    4. Kiumars Aryana & John A. Tomko & Ran Gao & Eric R. Hoglund & Takanori Mimura & Sara Makarem & Alejandro Salanova & Md Shafkat Bin Hoque & Thomas W. Pfeifer & David H. Olson & Jeffrey L. Braun & Joyeet, 2022. "Observation of solid-state bidirectional thermal conductivity switching in antiferroelectric lead zirconate (PbZrO3)," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
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