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Nanoemulsion-directed growth of MOFs with versatile architectures for the heterogeneous regeneration of coenzymes

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  • Ke Li

    (East China University of Science and Technology)

  • Yucheng Zhao

    (East China University of Science and Technology)

  • Jian Yang

    (East China University of Science and Technology)

  • Jinlou Gu

    (East China University of Science and Technology)

Abstract

As one of the most appealing strategies for the synthesis of nanomaterials with various architectures, emulsion-directed methods have been rarely used to control the structure of metal-organic frameworks (MOFs). Herein, we report a versatile salt-assisted nanoemulsion-guided assembly to achieve continuous architecture transition of hierarchical Zr-based MOFs. The morphology of nanoemulsion can be facilely regulated by tuning the feed ratio of a dual-surfactant and the introduced amount of compatible hydrophobic compounds, which directs the assembly of MOFs with various architectures such as bowl-like mesoporous particle, dendritic nanospheres, walnut-shaped particles, crumpled nanosheets and nanodisks. The developed dendritic nanospheres with highly open and large mesochannels is successfully used as matrix for the co-immobilization of coenzymes and corresponding enzymes to realize the in situ heterogeneous regeneration of NAD+. This strategy is expected to pave a way for exploring sophisticated hierarchical MOFs which can be competent for practical applications with bulk molecules involved.

Suggested Citation

  • Ke Li & Yucheng Zhao & Jian Yang & Jinlou Gu, 2022. "Nanoemulsion-directed growth of MOFs with versatile architectures for the heterogeneous regeneration of coenzymes," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29535-7
    DOI: 10.1038/s41467-022-29535-7
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    Cited by:

    1. Haidong Xu & Ji Han & Bin Zhao & Ruigang Sun & Guiyuan Zhong & Guangrui Chen & Yusuke Yamauchi & Buyuan Guan, 2023. "A facile dual-template-directed successive assembly approach to hollow multi-shell mesoporous metal–organic framework particles," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    2. Qiang Chen & Ge Qu & Xu Li & Mingjian Feng & Fan Yang & Yanjie Li & Jincheng Li & Feifei Tong & Shiyi Song & Yujun Wang & Zhoutong Sun & Guangsheng Luo, 2023. "Active and stable alcohol dehydrogenase-assembled hydrogels via synergistic bridging of triazoles and metal ions," Nature Communications, Nature, vol. 14(1), pages 1-12, December.

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