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Real-time optical and electronic sensing with a β-amino enone linked, triazine-containing 2D covalent organic framework

Author

Listed:
  • Ranjit Kulkarni

    (Humboldt-Universität zu Berlin
    Institute of Organic Chemistry and Biochemistry of the CAS)

  • Yu Noda

    (Humboldt-Universität zu Berlin
    Institute of Organic Chemistry and Biochemistry of the CAS)

  • Deepak Kumar Barange

    (Institute of Organic Chemistry and Biochemistry of the CAS)

  • Yaroslav S. Kochergin

    (Humboldt-Universität zu Berlin
    Institute of Organic Chemistry and Biochemistry of the CAS
    Charles University in Prague)

  • Pengbo Lyu

    (Charles University in Prague)

  • Barbora Balcarova

    (Institute of Organic Chemistry and Biochemistry of the CAS)

  • Petr Nachtigall

    (Charles University in Prague)

  • Michael J. Bojdys

    (Humboldt-Universität zu Berlin
    Institute of Organic Chemistry and Biochemistry of the CAS)

Abstract

Fully-aromatic, two-dimensional covalent organic frameworks (2D COFs) are hailed as candidates for electronic and optical devices, yet to-date few applications emerged that make genuine use of their rational, predictive design principles and permanent pore structure. Here, we present a 2D COF made up of chemoresistant β-amino enone bridges and Lewis-basic triazine moieties that exhibits a dramatic real-time response in the visible spectrum and an increase in bulk conductivity by two orders of magnitude to a chemical trigger - corrosive HCl vapours. The optical and electronic response is fully reversible using a chemical switch (NH3 vapours) or physical triggers (temperature or vacuum). These findings demonstrate a useful application of fully-aromatic 2D COFs as real-time responsive chemosensors and switches.

Suggested Citation

  • Ranjit Kulkarni & Yu Noda & Deepak Kumar Barange & Yaroslav S. Kochergin & Pengbo Lyu & Barbora Balcarova & Petr Nachtigall & Michael J. Bojdys, 2019. "Real-time optical and electronic sensing with a β-amino enone linked, triazine-containing 2D covalent organic framework," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:10:y:2019:i:1:d:10.1038_s41467-019-11264-z
    DOI: 10.1038/s41467-019-11264-z
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    Cited by:

    1. Song Wang & Yangyang Han & Vaishnavi Amarr Reddy & Mervin Chun-Yi Ang & Gabriel Sánchez-Velázquez & Jolly Madathiparambil Saju & Yunteng Cao & Duc Thinh Khong & Praveen Kumar Jayapal & Raju Cheerlavan, 2024. "Chromatic covalent organic frameworks enabling in-vivo chemical tomography," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Jie Zhang & Linshan Liu & Chaofeng Zheng & Wang Li & Chunru Wang & Taishan Wang, 2023. "Embedded nano spin sensor for in situ probing of gas adsorption inside porous organic frameworks," Nature Communications, Nature, vol. 14(1), pages 1-10, December.

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