IDEAS home Printed from https://ideas.repec.org/a/nat/natene/v7y2022i1d10.1038_s41560-021-00952-0.html
   My bibliography  Save this article

High areal capacity, long cycle life 4 V ceramic all-solid-state Li-ion batteries enabled by chloride solid electrolytes

Author

Listed:
  • Laidong Zhou

    (University of Waterloo
    Argonne National Laboratory)

  • Tong-Tong Zuo

    (Justus Liebig University)

  • Chun Yuen Kwok

    (University of Waterloo)

  • Se Young Kim

    (University of Waterloo)

  • Abdeljalil Assoud

    (University of Waterloo)

  • Qiang Zhang

    (Oak Ridge National Laboratory)

  • Jürgen Janek

    (Justus Liebig University)

  • Linda F. Nazar

    (University of Waterloo
    Argonne National Laboratory)

Abstract

All-solid-state Li batteries (ASSBs) employing inorganic solid electrolytes offer improved safety and are exciting candidates for next-generation energy storage. Herein, we report a family of lithium mixed-metal chlorospinels, Li2InxSc0.666−xCl4 (0 ≤ x ≤ 0.666), with high ionic conductivity (up to 2.0 mS cm−1) owing to a highly disordered Li-ion distribution, and low electronic conductivity (4.7 × 10−10 S cm−1), which are implemented for high-performance ASSBs. Owing to the excellent interfacial stability of the SE against uncoated high-voltage cathode materials, ASSBs utilizing LiCoO2 or LiNi0.85Co0.1Mn0.05O2 exhibit superior rate capability and long-term cycling (up to 4.8 V versus Li+/Li) compared to state-of-the-art ASSBs. In particular, the ASSB with LiNi0.85Co0.1Mn0.05O2 exhibits a long life of >3,000 cycles with 80% capacity retention at room temperature. High cathode loadings are also demonstrated in ASSBs with stable capacity retention of >4 mAh cm−2 (~190 mAh g−1).

Suggested Citation

  • Laidong Zhou & Tong-Tong Zuo & Chun Yuen Kwok & Se Young Kim & Abdeljalil Assoud & Qiang Zhang & Jürgen Janek & Linda F. Nazar, 2022. "High areal capacity, long cycle life 4 V ceramic all-solid-state Li-ion batteries enabled by chloride solid electrolytes," Nature Energy, Nature, vol. 7(1), pages 83-93, January.
    • Handle: RePEc:nat:natene:v:7:y:2022:i:1:d:10.1038_s41560-021-00952-0
    DOI: 10.1038/s41560-021-00952-0
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41560-021-00952-0
    File Function: Abstract
    Download Restriction: Access to the full text of the articles in this series is restricted.
    File URL: https://libkey.io/10.1038/s41560-021-00952-0?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Chanho Kim & Gyutae Nam & Yoojin Ahn & Xueyu Hu & Meilin Liu, 2024. "Nb1.60Ti0.32W0.08O5−δ as negative electrode active material for durable and fast-charging all-solid-state Li-ion batteries," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    2. Guanjun Ji & Junxiong Wang & Zheng Liang & Kai Jia & Jun Ma & Zhaofeng Zhuang & Guangmin Zhou & Hui-Ming Cheng, 2023. "Direct regeneration of degraded lithium-ion battery cathodes with a multifunctional organic lithium salt," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    3. Lv Hu & Jinzhu Wang & Kai Wang & Zhenqi Gu & Zhiwei Xi & Hui Li & Fang Chen & Youxi Wang & Zhenyu Li & Cheng Ma, 2023. "A cost-effective, ionically conductive and compressible oxychloride solid-state electrolyte for stable all-solid-state lithium-based batteries," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    4. Xiaona Li & Jung Tae Kim & Jing Luo & Changtai Zhao & Yang Xu & Tao Mei & Ruying Li & Jianwen Liang & Xueliang Sun, 2024. "Structural regulation of halide superionic conductors for all-solid-state lithium batteries," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    5. Shumin Zhang & Feipeng Zhao & Jiatang Chen & Jiamin Fu & Jing Luo & Sandamini H. Alahakoon & Lo-Yueh Chang & Renfei Feng & Mohsen Shakouri & Jianwen Liang & Yang Zhao & Xiaona Li & Le He & Yining Huan, 2023. "A family of oxychloride amorphous solid electrolytes for long-cycling all-solid-state lithium batteries," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    6. Pushun Lu & Yu Xia & Guochen Sun & Dengxu Wu & Siyuan Wu & Wenlin Yan & Xiang Zhu & Jiaze Lu & Quanhai Niu & Shaochen Shi & Zhengju Sha & Liquan Chen & Hong Li & Fan Wu, 2023. "Realizing long-cycling all-solid-state Li-In||TiS2 batteries using Li6+xMxAs1-xS5I (M=Si, Sn) sulfide solid electrolytes," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    7. Qidi Wang & Yunan Zhou & Xuelong Wang & Hao Guo & Shuiping Gong & Zhenpeng Yao & Fangting Wu & Jianlin Wang & Swapna Ganapathy & Xuedong Bai & Baohua Li & Chenglong Zhao & Jürgen Janek & Marnix Wagema, 2024. "Designing lithium halide solid electrolytes," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    8. Zhenyou Song & Tengrui Wang & Hua Yang & Wang Hay Kan & Yuwei Chen & Qian Yu & Likuo Wang & Yini Zhang & Yiming Dai & Huaican Chen & Wen Yin & Takashi Honda & Maxim Avdeev & Henghui Xu & Jiwei Ma & Yu, 2024. "Promoting high-voltage stability through local lattice distortion of halide solid electrolytes," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    9. Hiram Kwak & Jae-Seung Kim & Daseul Han & Jong Seok Kim & Juhyoun Park & Gihan Kwon & Seong-Min Bak & Unseon Heo & Changhyun Park & Hyun-Wook Lee & Kyung-Wan Nam & Dong-Hwa Seo & Yoon Seok Jung, 2023. "Boosting the interfacial superionic conduction of halide solid electrolytes for all-solid-state batteries," Nature Communications, Nature, vol. 14(1), pages 1-14, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natene:v:7:y:2022:i:1:d:10.1038_s41560-021-00952-0. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.