IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-37155-y.html
   My bibliography  Save this article

Trifunctional nanoprecipitates ductilize and toughen a strong laminated metastable titanium alloy

Author

Listed:
  • Chongle Zhang

    (Xi’an Jiaotong University)

  • Shuaiyang Liu

    (Xi’an Jiaotong University)

  • Jinyu Zhang

    (Xi’an Jiaotong University)

  • Dongdong Zhang

    (Xi’an Jiaotong University)

  • Jie Kuang

    (Xi’an Jiaotong University)

  • Xiangyun Bao

    (Xi’an Jiaotong University)

  • Gang Liu

    (Xi’an Jiaotong University)

  • Jun Sun

    (Xi’an Jiaotong University)

Abstract

Metastability-engineering, e.g., transformation-induced plasticity (TRIP), can enhance the ductility of alloys, however it often comes at the expense of relatively low yield strength. Here, using a metastable Ti-1Al-8.5Mo-2.8Cr-2.7Zr (wt.%) alloy as a model material, we fabricate a heterogeneous laminated structure decorated by multiple-morphological α-nanoprecipitates. The hard α nanoprecipitate in our alloy acts not only as a strengthener to the material, but also as a local stress raiser to activate TRIP in the soft matrix for great uniform elongation and as a promoter to trigger interfacial delamination toughening for superior fracture resistance. By elaborately manipulating the activation sequence of lamellar-thickness-dependent deformation mechanisms in Ti-1Al-8.5Mo-2.8Cr-2.7Zr alloys, the yield strength of the present submicron-laminated alloy is twice that of equiaxed-coarse grained alloys with the same composition, yet without sacrificing the large uniform elongation. The desired mechanical properties enabled by this strategy combining the laminated metastable structure and trifunctional nanoprecipitates provide new insights into designing ultra-strong and ductile materials with great toughness.

Suggested Citation

  • Chongle Zhang & Shuaiyang Liu & Jinyu Zhang & Dongdong Zhang & Jie Kuang & Xiangyun Bao & Gang Liu & Jun Sun, 2023. "Trifunctional nanoprecipitates ductilize and toughen a strong laminated metastable titanium alloy," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37155-y
    DOI: 10.1038/s41467-023-37155-y
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-37155-y
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-023-37155-y?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Sijing Chen & Hyun Seok Oh & Bernd Gludovatz & Sang Jun Kim & Eun Soo Park & Ze Zhang & Robert O. Ritchie & Qian Yu, 2020. "Real-time observations of TRIP-induced ultrahigh strain hardening in a dual-phase CrMnFeCoNi high-entropy alloy," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    2. Jaafar A. El-Awady, 2015. "Unravelling the physics of size-dependent dislocation-mediated plasticity," Nature Communications, Nature, vol. 6(1), pages 1-9, May.
    3. L. Choisez & L. Ding & M. Marteleur & H. Idrissi & T. Pardoen & P. J. Jacques, 2020. "High temperature rise dominated cracking mechanisms in ultra-ductile and tough titanium alloy," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    4. Peijian Shi & Weili Ren & Tianxiang Zheng & Zhongming Ren & Xueling Hou & Jianchao Peng & Pengfei Hu & Yanfei Gao & Yunbo Zhong & Peter K. Liaw, 2019. "Enhanced strength–ductility synergy in ultrafine-grained eutectic high-entropy alloys by inheriting microstructural lamellae," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    5. Ying Yang & Tianyi Chen & Lizhen Tan & Jonathan D. Poplawsky & Ke An & Yanli Wang & German D. Samolyuk & Ken Littrell & Andrew R. Lupini & Albina Borisevich & Easo P. George, 2021. "Bifunctional nanoprecipitates strengthen and ductilize a medium-entropy alloy," Nature, Nature, vol. 595(7866), pages 245-249, July.
    6. Qian Yu & Zhi-Wei Shan & Ju Li & Xiaoxu Huang & Lin Xiao & Jun Sun & Evan Ma, 2010. "Strong crystal size effect on deformation twinning," Nature, Nature, vol. 463(7279), pages 335-338, January.
    7. Zhiming Li & Konda Gokuldoss Pradeep & Yun Deng & Dierk Raabe & Cemal Cem Tasan, 2016. "Metastable high-entropy dual-phase alloys overcome the strength–ductility trade-off," Nature, Nature, vol. 534(7606), pages 227-230, June.
    8. Arun Devaraj & Vineet V. Joshi & Ankit Srivastava & Sandeep Manandhar & Vladimir Moxson & Volodymyr A. Duz & Curt Lavender, 2016. "A low-cost hierarchical nanostructured beta-titanium alloy with high strength," Nature Communications, Nature, vol. 7(1), pages 1-8, September.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Tielong Han & Chao Hou & Zhi Zhao & Zengbao Jiao & Yurong Li & Shuang Jiang & Hao Lu & Haibin Wang & Xuemei Liu & Zuoren Nie & Xiaoyan Song, 2024. "Simultaneous enhancement of strength and conductivity via self-assembled lamellar architecture," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Hyun Chung & Won Seok Choi & Hosun Jun & Hyeon-Seok Do & Byeong-Joo Lee & Pyuck-Pa Choi & Heung Nam Han & Won-Seok Ko & Seok Su Sohn, 2023. "Doubled strength and ductility via maraging effect and dynamic precipitate transformation in ultrastrong medium-entropy alloy," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    2. Chongle Zhang & Xiangyun Bao & Mengyuan Hao & Wei Chen & Dongdong Zhang & Dong Wang & Jinyu Zhang & Gang Liu & Jun Sun, 2022. "Hierarchical nano-martensite-engineered a low-cost ultra-strong and ductile titanium alloy," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    3. Tong Li & Tianwei Liu & Shiteng Zhao & Yan Chen & Junhua Luan & Zengbao Jiao & Robert O. Ritchie & Lanhong Dai, 2023. "Ultra-strong tungsten refractory high-entropy alloy via stepwise controllable coherent nanoprecipitations," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    4. Xizheng Wang & Yunhao Zhao & Gang Chen & Xinpeng Zhao & Chuan Liu & Soumya Sridar & Luis Fernando Ladinos Pizano & Shuke Li & Alexandra H. Brozena & Miao Guo & Hanlei Zhang & Yuankang Wang & Wei Xiong, 2022. "Ultrahigh-temperature melt printing of multi-principal element alloys," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    5. Zongrui Pei & Shiteng Zhao & Martin Detrois & Paul D. Jablonski & Jeffrey A. Hawk & David E. Alman & Mark Asta & Andrew M. Minor & Michael C. Gao, 2023. "Theory-guided design of high-entropy alloys with enhanced strength-ductility synergy," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    6. Li Zhong & Yin Zhang & Xiang Wang & Ting Zhu & Scott X. Mao, 2024. "Atomic-scale observation of nucleation- and growth-controlled deformation twinning in body-centered cubic nanocrystals," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    7. Bo Xiao & Junhua Luan & Shijun Zhao & Lijun Zhang & Shiyao Chen & Yilu Zhao & Lianyong Xu & C. T. Liu & Ji-Jung Kai & Tao Yang, 2022. "Achieving thermally stable nanoparticles in chemically complex alloys via controllable sluggish lattice diffusion," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    8. Yang Yang & Sheng Yin & Qin Yu & Yingxin Zhu & Jun Ding & Ruopeng Zhang & Colin Ophus & Mark Asta & Robert O. Ritchie & Andrew M. Minor, 2024. "Rejuvenation as the origin of planar defects in the CrCoNi medium entropy alloy," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    9. Sheng Xu & Takumi Odaira & Shunsuke Sato & Xiao Xu & Toshihiro Omori & Stefanus Harjo & Takuro Kawasaki & Hanuš Seiner & Kristýna Zoubková & Yasukazu Murakami & Ryosuke Kainuma, 2022. "Non-Hookean large elastic deformation in bulk crystalline metals," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    10. Bin Ouyang & Yan Zeng, 2024. "The rise of high-entropy battery materials," Nature Communications, Nature, vol. 15(1), pages 1-5, December.
    11. Benjamin P. MacLeod & Fraser G. L. Parlane & Connor C. Rupnow & Kevan E. Dettelbach & Michael S. Elliott & Thomas D. Morrissey & Ted H. Haley & Oleksii Proskurin & Michael B. Rooney & Nina Taherimakhs, 2022. "A self-driving laboratory advances the Pareto front for material properties," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    12. Lin Jiang & Mingyu Gong & Jian Wang & Zhiliang Pan & Xin Wang & Dalong Zhang & Y. Morris Wang & Jim Ciston & Andrew M. Minor & Mingjie Xu & Xiaoqing Pan & Timothy J. Rupert & Subhash Mahajan & Enrique, 2022. "Visualization and validation of twin nucleation and early-stage growth in magnesium," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    13. Daniel Utt & Subin Lee & Yaolong Xing & Hyejin Jeong & Alexander Stukowski & Sang Ho Oh & Gerhard Dehm & Karsten Albe, 2022. "The origin of jerky dislocation motion in high-entropy alloys," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    14. Jiaojiao Hu & Qiankun Yang & Shuya Zhu & Yong Zhang & Dingshun Yan & Kefu Gan & Zhiming Li, 2023. "Superhard bulk high-entropy carbides with enhanced toughness via metastable in-situ particles," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    15. Jingqi Zhang & Yingang Liu & Gang Sha & Shenbao Jin & Ziyong Hou & Mohamad Bayat & Nan Yang & Qiyang Tan & Yu Yin & Shiyang Liu & Jesper Henri Hattel & Matthew Dargusch & Xiaoxu Huang & Ming-Xing Zhan, 2022. "Designing against phase and property heterogeneities in additively manufactured titanium alloys," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    16. Bin Xing & Timothy J. Rupert & Xiaoqing Pan & Penghui Cao, 2024. "Neural network kinetics for exploring diffusion multiplicity and chemical ordering in compositionally complex materials," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    17. Zan Li & Yin Zhang & Zhibo Zhang & Yi-Tao Cui & Qiang Guo & Pan Liu & Shenbao Jin & Gang Sha & Kunqing Ding & Zhiqiang Li & Tongxiang Fan & Herbert M. Urbassek & Qian Yu & Ting Zhu & Di Zhang & Y. Mor, 2022. "A nanodispersion-in-nanograins strategy for ultra-strong, ductile and stable metal nanocomposites," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    18. Jianan Yin & Yang Yan & Mulin Miao & Jiayin Tang & Jiali Jiang & Hui Liu & Yuhan Chen & Yinxian Chen & Fucong Lyu & Zhengyi Mao & Yunhu He & Lei Wan & Binbin Zhou & Jian Lu, 2024. "Diamond with Sp2-Sp3 composite phase for thermometry at Millikelvin temperatures," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    19. Xingjia He & Yu Zhang & Xinlei Gu & Jiangwei Wang & Jinlei Qi & Jun Hao & Longpeng Wang & Hao Huang & Mao Wen & Kan Zhang & Weitao Zheng, 2023. "Pt-induced atomic-level tailoring towards paracrystalline high-entropy alloy," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    20. Binglu Zhang & Qisi Zhu & Chi Xu & Changtai Li & Yuan Ma & Zhaoxiang Ma & Sinuo Liu & Ruiwen Shao & Yuting Xu & Baolong Jiang & Lei Gao & Xiaolu Pang & Yang He & Guang Chen & Lijie Qiao, 2022. "Atomic-scale insights on hydrogen trapping and exclusion at incoherent interfaces of nanoprecipitates in martensitic steels," Nature Communications, Nature, vol. 13(1), pages 1-11, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37155-y. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.