IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-38111-6.html
   My bibliography  Save this article

Theory-guided design of high-entropy alloys with enhanced strength-ductility synergy

Author

Listed:
  • Zongrui Pei

    (National Energy Technology Laboratory
    ORISE)

  • Shiteng Zhao

    (University of California
    Lawrence Berkeley National Laboratory
    Beihang University
    Tianmushan Laboratory)

  • Martin Detrois

    (National Energy Technology Laboratory)

  • Paul D. Jablonski

    (National Energy Technology Laboratory)

  • Jeffrey A. Hawk

    (National Energy Technology Laboratory)

  • David E. Alman

    (National Energy Technology Laboratory)

  • Mark Asta

    (University of California
    Lawrence Berkeley National Laboratory)

  • Andrew M. Minor

    (University of California
    Lawrence Berkeley National Laboratory)

  • Michael C. Gao

    (National Energy Technology Laboratory)

Abstract

Metallic alloys have played essential roles in human civilization due to their balanced strength and ductility. Metastable phases and twins have been introduced to overcome the strength-ductility tradeoff in face-centered cubic (FCC) high-entropy alloys (HEAs). However, there is still a lack of quantifiable mechanisms to predict good combinations of the two mechanical properties. Here we propose a possible mechanism based on the parameter κ, the ratio of short-ranged interactions between closed-pack planes. It promotes the formation of various nanoscale stacking sequences and enhances the work-hardening ability of the alloys. Guided by the theory, we successfully designed HEAs with enhanced strength and ductility compared with other extensively studied CoCrNi-based systems. Our results not only offer a physical picture of the strengthening effects but can also be used as a practical design principle to enhance the strength-ductility synergy in HEAs.

Suggested Citation

  • Zongrui Pei & Shiteng Zhao & Martin Detrois & Paul D. Jablonski & Jeffrey A. Hawk & David E. Alman & Mark Asta & Andrew M. Minor & Michael C. Gao, 2023. "Theory-guided design of high-entropy alloys with enhanced strength-ductility synergy," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38111-6
    DOI: 10.1038/s41467-023-38111-6
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-38111-6
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-38111-6?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. ZiJiao Zhang & M. M. Mao & Jiangwei Wang & Bernd Gludovatz & Ze Zhang & Scott X. Mao & Easo P. George & Qian Yu & Robert O. Ritchie, 2015. "Nanoscale origins of the damage tolerance of the high-entropy alloy CrMnFeCoNi," Nature Communications, Nature, vol. 6(1), pages 1-6, December.
    2. Zhaoxuan Wu & W. A. Curtin, 2015. "The origins of high hardening and low ductility in magnesium," Nature, Nature, vol. 526(7571), pages 62-67, October.
    3. Fei Zhang & Yuan Wu & Hongbo Lou & Zhidan Zeng & Vitali B. Prakapenka & Eran Greenberg & Yang Ren & Jinyuan Yan & John S. Okasinski & Xiongjun Liu & Yong Liu & Qiaoshi Zeng & Zhaoping Lu, 2017. "Polymorphism in a high-entropy alloy," Nature Communications, Nature, vol. 8(1), pages 1-7, August.
    4. Ruopeng Zhang & Shiteng Zhao & Jun Ding & Yan Chong & Tao Jia & Colin Ophus & Mark Asta & Robert O. Ritchie & Andrew M. Minor, 2020. "Short-range order and its impact on the CrCoNi medium-entropy alloy," Nature, Nature, vol. 581(7808), pages 283-287, May.
    5. Cameron L. Tracy & Sulgiye Park & Dylan R. Rittman & Steven J. Zinkle & Hongbin Bei & Maik Lang & Rodney C. Ewing & Wendy L. Mao, 2017. "High pressure synthesis of a hexagonal close-packed phase of the high-entropy alloy CrMnFeCoNi," Nature Communications, Nature, vol. 8(1), pages 1-6, August.
    6. Zijiao Zhang & Hongwei Sheng & Zhangjie Wang & Bernd Gludovatz & Ze Zhang & Easo P. George & Qian Yu & Scott X. Mao & Robert O. Ritchie, 2017. "Dislocation mechanisms and 3D twin architectures generate exceptional strength-ductility-toughness combination in CrCoNi medium-entropy alloy," Nature Communications, Nature, vol. 8(1), pages 1-8, April.
    7. Changning Niu & Carlyn R. LaRosa & Jiashi Miao & Michael J. Mills & Maryam Ghazisaeidi, 2018. "Magnetically-driven phase transformation strengthening in high entropy alloys," Nature Communications, Nature, vol. 9(1), pages 1-9, December.
    8. Zhiming Li & Konda Gokuldoss Pradeep & Yun Deng & Dierk Raabe & Cemal Cem Tasan, 2016. "Metastable high-entropy dual-phase alloys overcome the strength–ductility trade-off," Nature, Nature, vol. 534(7606), pages 227-230, June.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Xizheng Wang & Yunhao Zhao & Gang Chen & Xinpeng Zhao & Chuan Liu & Soumya Sridar & Luis Fernando Ladinos Pizano & Shuke Li & Alexandra H. Brozena & Miao Guo & Hanlei Zhang & Yuankang Wang & Wei Xiong, 2022. "Ultrahigh-temperature melt printing of multi-principal element alloys," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    2. Wei Chen & Antoine Hilhorst & Georgios Bokas & Stéphane Gorsse & Pascal J. Jacques & Geoffroy Hautier, 2023. "A map of single-phase high-entropy alloys," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Yang Yang & Sheng Yin & Qin Yu & Yingxin Zhu & Jun Ding & Ruopeng Zhang & Colin Ophus & Mark Asta & Robert O. Ritchie & Andrew M. Minor, 2024. "Rejuvenation as the origin of planar defects in the CrCoNi medium entropy alloy," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    4. Jing Wang & Ping Jiang & Fuping Yuan & Xiaolei Wu, 2022. "Chemical medium-range order in a medium-entropy alloy," Nature Communications, Nature, vol. 13(1), pages 1-6, December.
    5. Tong Li & Tianwei Liu & Shiteng Zhao & Yan Chen & Junhua Luan & Zengbao Jiao & Robert O. Ritchie & Lanhong Dai, 2023. "Ultra-strong tungsten refractory high-entropy alloy via stepwise controllable coherent nanoprecipitations," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    6. Daniel Utt & Subin Lee & Yaolong Xing & Hyejin Jeong & Alexander Stukowski & Sang Ho Oh & Gerhard Dehm & Karsten Albe, 2022. "The origin of jerky dislocation motion in high-entropy alloys," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    7. Jae Bok Seol & Won-Seok Ko & Seok Su Sohn & Min Young Na & Hye Jung Chang & Yoon-Uk Heo & Jung Gi Kim & Hyokyung Sung & Zhiming Li & Elena Pereloma & Hyoung Seop Kim, 2022. "Mechanically derived short-range order and its impact on the multi-principal-element alloys," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    8. Linze Li & Bin Ouyang & Zhengyan Lun & Haoyan Huo & Dongchang Chen & Yuan Yue & Colin Ophus & Wei Tong & Guoying Chen & Gerbrand Ceder & Chongmin Wang, 2023. "Atomic-scale probing of short-range order and its impact on electrochemical properties in cation-disordered oxide cathodes," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    9. Ying Han & Hangman Chen & Yongwen Sun & Jian Liu & Shaolou Wei & Bijun Xie & Zhiyu Zhang & Yingxin Zhu & Meng Li & Judith Yang & Wen Chen & Penghui Cao & Yang Yang, 2024. "Ubiquitous short-range order in multi-principal element alloys," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    10. Mingliang Han & Yuan Wu & Xiaobin Zong & Yaozu Shen & Fei Zhang & Hongbo Lou & Xiao Dong & Zhidan Zeng & Xiangyang Peng & Shuo Hou & Guangyao Lu & Lianghua Xiong & Bingmin Yan & Huiyang Gou & Yanping , 2024. "Lightweight single-phase Al-based complex concentrated alloy with high specific strength," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    11. Yannick Naunheim & Christopher A. Schuh, 2024. "Multicomponent alloys designed to sinter," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    12. Li Zhong & Yin Zhang & Xiang Wang & Ting Zhu & Scott X. Mao, 2024. "Atomic-scale observation of nucleation- and growth-controlled deformation twinning in body-centered cubic nanocrystals," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    13. Bo Xiao & Junhua Luan & Shijun Zhao & Lijun Zhang & Shiyao Chen & Yilu Zhao & Lianyong Xu & C. T. Liu & Ji-Jung Kai & Tao Yang, 2022. "Achieving thermally stable nanoparticles in chemically complex alloys via controllable sluggish lattice diffusion," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    14. Wuyang Ren & Wenhua Xue & Shuping Guo & Ran He & Liangzi Deng & Shaowei Song & Andrei Sotnikov & Kornelius Nielsch & Jeroen Brink & Guanhui Gao & Shuo Chen & Yimo Han & Jiang Wu & Ching-Wu Chu & Zhimi, 2023. "Vacancy-mediated anomalous phononic and electronic transport in defective half-Heusler ZrNiBi," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    15. Sung-Kyun Jung & Hyeokjo Gwon & Hyungsub Kim & Gabin Yoon & Dongki Shin & Jihyun Hong & Changhoon Jung & Ju-Sik Kim, 2022. "Unlocking the hidden chemical space in cubic-phase garnet solid electrolyte for efficient quasi-all-solid-state lithium batteries," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    16. Sheng Xu & Takumi Odaira & Shunsuke Sato & Xiao Xu & Toshihiro Omori & Stefanus Harjo & Takuro Kawasaki & Hanuš Seiner & Kristýna Zoubková & Yasukazu Murakami & Ryosuke Kainuma, 2022. "Non-Hookean large elastic deformation in bulk crystalline metals," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    17. Bin Ouyang & Yan Zeng, 2024. "The rise of high-entropy battery materials," Nature Communications, Nature, vol. 15(1), pages 1-5, December.
    18. Hyun Chung & Won Seok Choi & Hosun Jun & Hyeon-Seok Do & Byeong-Joo Lee & Pyuck-Pa Choi & Heung Nam Han & Won-Seok Ko & Seok Su Sohn, 2023. "Doubled strength and ductility via maraging effect and dynamic precipitate transformation in ultrastrong medium-entropy alloy," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    19. David Redka & Saleem Ayaz Khan & Edoardo Martino & Xavier Mettan & Luka Ciric & Davor Tolj & Trpimir Ivšić & Andreas Held & Marco Caputo & Eduardo Bonini Guedes & Vladimir N. Strocov & Igor Marco & Hu, 2024. "Interplay between disorder and electronic correlations in compositionally complex alloys," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    20. Benjamin P. MacLeod & Fraser G. L. Parlane & Connor C. Rupnow & Kevan E. Dettelbach & Michael S. Elliott & Thomas D. Morrissey & Ted H. Haley & Oleksii Proskurin & Michael B. Rooney & Nina Taherimakhs, 2022. "A self-driving laboratory advances the Pareto front for material properties," Nature Communications, Nature, vol. 13(1), pages 1-10, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38111-6. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.